The linear molecular geometry describes the geometry around a central atom bonded to two other atoms (or ligands) placed at a bond angle of 180°. Linear organic molecules, such as acetylene (HC≡CH), are often described by invoking sp orbital hybridization for their carbon centers.
According to the VSEPR model (Valence Shell Electron Pair Repulsion model), linear geometry occurs at central atoms with two bonded atoms and zero or three lone pairs (AX2 or AX2E3) in the AXE notation. Neutral AX2 molecules with linear geometry include beryllium fluoride (F−Be−F) with two single bonds, carbon dioxide (O=C=O) with two double bonds, hydrogen cyanide (H−C≡N) with one single and one triple bond. The most important linear molecule with more than three atoms is acetylene (H−C≡C−H), in which each of its carbon atoms is considered to be a central atom with a single bond to one hydrogen and a triple bond to the other carbon atom. Linear anions include azide (N=N=N) and thiocyanate (S=C=N), and a linear cation is the nitronium ion (O=N=O).
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