Organic chemistry in the context of Physical organic chemistry


Organic chemistry in the context of Physical organic chemistry

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⭐ Core Definition: Organic chemistry

Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms. Study of structure determines their structural formula. Study of properties includes physical and chemical properties, and evaluation of chemical reactivity to understand their behavior. The study of organic reactions includes the chemical synthesis of natural products, drugs, and polymers, and study of individual organic molecules in the laboratory and via theoretical (in silico) study.

The range of chemicals studied in organic chemistry includes hydrocarbons (compounds containing only carbon and hydrogen) as well as compounds based on carbon, but also containing other elements, especially oxygen, nitrogen, sulfur, phosphorus (included in many biochemicals) and the halogens. Organometallic chemistry is the study of compounds containing carbon–metal bonds.

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Organic chemistry in the context of Molecule

A molecule is a group of two or more atoms that are held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.

A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.

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Organic chemistry in the context of Methane

Methane (US: /ˈmɛθn/ METH-ayn, UK: /ˈmθn/ MEE-thayn) is a chemical compound with the chemical formula CH4 (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is difficult because it is a gas at standard temperature and pressure. In the Earth's atmosphere methane is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Methane is an organic hydrocarbon, and among the simplest of organic compounds.

Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the atmosphere, it is known as atmospheric methane.

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Organic chemistry in the context of Salt (chemistry)

In chemistry, a salt or ionic compound is a chemical compound consisting of an assembly of positively charged ions (cations) and negatively charged ions (anions), which results in a compound with no net electric charge. The constituent ions are held together by electrostatic forces termed ionic bonds.

The component ions in a salt can be either inorganic, such as chloride (Cl), or organic, such as acetate (CH
3
COO
). Each ion can be either monatomic, such as sodium (Na) and chloride (Cl) in sodium chloride, or polyatomic, such as ammonium (NH
4
) and carbonate (CO
3
) ions in ammonium carbonate. Salts containing basic ions hydroxide (OH) or oxide (O) are classified as bases, such as sodium hydroxide and potassium oxide.

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Organic chemistry in the context of Hydrocarbon

In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic; their odor is usually faint, and may be similar to that of gasoline or lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene).

In the fossil fuel industries, hydrocarbon refers to naturally occurring petroleum, natural gas and coal, or their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are either carbon dioxide released by the burning of fossil fuels, or methane released from the handling of natural gas or from agriculture.

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Organic chemistry in the context of Bone

A bone is a rigid organ that constitutes part of the skeleton in most vertebrate animals. Bones protect the organs of the body, produce red and white blood cells, store minerals, help regulate acid-base homeostasis, provide structure and support for the body, and enable mobility and hearing. Bones come in a variety of shapes and sizes and have complex internal and external structures.

Bone tissue (also known as osseous tissue or bone in the uncountable) is a form of hard tissue, specialised connective tissue that is mineralized and has an intercellular honeycomb-like matrix, which helps to give the bone rigidity. Bone tissue is made up of different types of bone cells: osteoblasts and osteocytes (bone formation and mineralisation); osteoclasts (bone resorption); modified or flattened osteoblasts (lining cells that form a protective layer on the bone surface). The mineralised matrix of bone tissue has an organic component of mainly ossein, a form of collagen, and an inorganic component of bone mineral, made up of various salts. Bone tissue comprises cortical bone and cancellous bone, although bones may also contain other kinds of tissue including bone marrow, endosteum, periosteum, nerves, blood vessels, and cartilage.

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Organic chemistry in the context of Alexander Borodin

Alexander Porfiryevich Borodin (12 November 1833 – 27 February 1887) was a Russian Romantic composer and chemist of Georgian–Russian parentage. He was one of the prominent 19th-century composers known as "The Five", a group dedicated to producing a "uniquely Russian" kind of classical music. Borodin is known best for his symphonies, his two string quartets, the symphonic poem In the Steppes of Central Asia and his opera Prince Igor.

A doctor and chemist by profession and training, Borodin made important early contributions to organic chemistry. Although he is presently known better as a composer, he regarded medicine and science as his primary occupations, only practising music and composition in his spare time or when he was ill. As a chemist, Borodin is known best for his work concerning organic synthesis, including being among the first chemists to demonstrate nucleophilic substitution, as well as being the co-discoverer of the aldol reaction. Borodin was a promoter of education in Russia and founded the School of Medicine for Women in Saint Petersburg, where he taught until 1885.

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Organic chemistry in the context of Gemstones

A gemstone (also called a fine gem, jewel, precious stone, semiprecious stone, or simply gem) is a piece of mineral crystal which, when cut or polished, is used to make jewelry or other adornments. Certain rocks (such as lapis lazuli, opal, and obsidian) and occasionally organic materials that are not minerals (such as amber, jet, and pearl) may also be used for jewelry and are therefore often considered to be gemstones as well. Most gemstones are hard, but some softer minerals such as brazilianite may be used in jewelry because of their color or luster or other physical properties that have aesthetic value. However, generally speaking, soft minerals are not typically used as gemstones by virtue of their brittleness and lack of durability.

Found all over the world, the industry of coloured gemstones (i.e. anything other than diamonds) is currently estimated at US$1.55 billion as of 2023 and is projected to steadily increase to a value of $4.46 billion by 2033.

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Organic chemistry in the context of Hydroxide

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical.The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group −OH of atoms is the hydroxy group.Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

Many inorganic substances which bear the word hydroxide in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups.

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Organic chemistry in the context of Organic compound

Organic compounds are a subclass of chemical compounds of carbon. Little consensus exists among chemists on the exact definition of organic compound; the only universally accepted definition is the quasi-tautological "organic compounds are the subject matter of organic chemistry".

Generally, any large chemical compound containing a carbon–hydrogen or carbon–carbon bond is accepted as an organic compound. Thus alkanes (e.g. ethane, CH3−CH3) and their derivatives are typically considered organic. For historical and disciplinary reasons, small molecules containing carbon are generally not accepted: cyanide ion (CN), hydrogen cyanide (HCN), chloroformic acid (ClCO2H), carbon dioxide (CO2), and carbonate ion (CO2−3) may all be excluded.

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Organic chemistry in the context of Organophosphate

In organic chemistry, organophosphates (also known as phosphate esters, or OPEs) are a class of organophosphorus compounds with the general structure O=P(OR)3, a central phosphate molecule with alkyl or aromatic substituents. They can be considered as esters of phosphoric acid. Organophosphates are best known for their use as pesticides.

Like most functional groups, organophosphates occur in a diverse range of forms, with important examples including key biomolecules such as DNA, RNA and ATP, as well as many insecticides, herbicides, nerve agents and flame retardants. OPEs have been widely used in various products as flame retardants, plasticizers, and performance additives to engine oil. The low cost of production and compatibility to diverse polymers made OPEs to be widely used in industry including textile, furniture, electronics as plasticizers and flame retardants. These compounds are added to the final product physically rather than by chemical bond. Due to this, OPEs leak into the environment more readily through volatilization, leaching, and abrasion. OPEs have been detected in diverse environmental compartments such as air, dust, water, sediment, soil and biota samples at higher frequency and concentration.

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Organic chemistry in the context of Alkane

In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula CnH2n+2. The alkanes range in complexity from the simplest case of methane (CH4), where n = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like hexacontane (C60H122) or 4-methyl-5-(1-methylethyl) octane, an isomer of dodecane (C12H26).

The International Union of Pure and Applied Chemistry (IUPAC) defines alkanes as "acyclic branched or unbranched hydrocarbons having the general formula CnH2n+2, and therefore consisting entirely of hydrogen atoms and saturated carbon atoms". However, some sources use the term to denote any saturated hydrocarbon, including those that are either monocyclic (i.e. the cycloalkanes) or polycyclic, despite them having a distinct general formula (e.g. cycloalkanes are CnH2n).

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Organic chemistry in the context of Cracking (chemistry)

In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon–carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of large hydrocarbons into smaller, more useful alkanes and alkenes. Simply put, hydrocarbon cracking is the process of breaking long-chain hydrocarbons into short ones. This process requires high temperatures.

More loosely, outside the field of petroleum chemistry, the term "cracking" is used to describe any type of splitting of molecules under the influence of heat, catalysts and solvents, such as in processes of destructive distillation or pyrolysis.

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Organic chemistry in the context of Chloracetophenone

Phenacyl chloride, also commonly known as chloroacetophenone, is a substituted acetophenone. It is a useful building block in organic chemistry. Apart from that, it has been historically used as a riot control agent, where it is designated CN. It should not be confused with cyanide, another agent used in chemical warfare, which has the chemical structure CN. Chloroacetophenone is thermally stable, and is the only tear agent that is distillable at ambient conditions.

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Organic chemistry in the context of Derivative (chemistry)

In chemistry, a derivative is a compound that is derived from a similar compound by a chemical reaction, or that can be imagined to arise from another compound, if one atom or group of atoms is replaced with another atom or group of atoms. The exact definition of "derivative" depends on the specific context.

The related term structural analogue is common in organic chemistry.

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