Mononuclidic elements in the context of Stable nuclide


Mononuclidic elements in the context of Stable nuclide

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⭐ Core Definition: Mononuclidic elements

A mononuclidic element or monotopic element is one of the 21 chemical elements that is found naturally on Earth essentially as a single nuclide (which may, or may not, be a stable nuclide). This single nuclide will have a characteristic atomic mass. Thus, the element's natural isotopic abundance is dominated by one isotope that is either stable or very long-lived. There are 19 elements in the first category (which are both monoisotopic and mononuclidic), and 2 (bismuth and protactinium) in the second category (mononuclidic but not monoisotopic, since they have zero, not one, stable nuclides). A list of the 21 mononuclidic elements is given at the end of this article.

Of the 26 monoisotopic elements that, by definition, have only one stable isotope, seven are not considered mononuclidic, due to the presence of a significant fraction of a very long-lived (primordial) radioisotope. These elements are vanadium, rubidium, indium, lanthanum, europium, lutetium, and rhenium.

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Mononuclidic elements in the context of Thorium-234

Thorium (90Th) has seven naturally occurring isotopes but none are stable. One isotope, Th, is relatively stable, with a half-life of 1.40×10 years, considerably longer than the age of the Earth, and even slightly longer than the generally accepted age of the universe. This isotope makes up nearly all natural thorium, so thorium was considered to be mononuclidic. However, in 2013, IUPAC reclassified thorium as binuclidic, due to large amounts of Th in deep seawater. Thorium has a characteristic terrestrial isotopic composition and thus a standard atomic weight can be given.

Thirty-one radioisotopes have been characterized, with the most stable being Th, Th with a half-life of 75,400 years, Th with a half-life of 7,916 years, and Th with a half-life of 1.91 years. All of the remaining radioactive isotopes have half-lives that are less than thirty days and the majority of these have half-lives that are less than ten minutes. One isotope, Th, has a nuclear isomer (or metastable state) with a remarkably low excitation energy, recently measured to be 8.355733554021(8) eV It has been proposed to perform laser spectroscopy of the Th nucleus and use the low-energy transition for the development of a nuclear clock of extremely high accuracy.

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