Primordial nuclide in the context of Mononuclidic elements

Uranium is a chemical element; it has symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactively decays, usually by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite.

Many contemporary uses of uranium exploit its unique nuclear properties. Uranium is used in nuclear power plants and nuclear weapons because it is the only naturally occurring element with a fissile isotope – uranium-235 – present in non-trace amounts. However, because of the low abundance of uranium-235 in natural uranium (which is overwhelmingly uranium-238), uranium needs to undergo enrichment so that enough uranium-235 is present. Uranium-238 is fissionable by fast neutrons and is fertile, meaning it can be transmuted to fissile plutonium-239 in a nuclear reactor. Another fissile isotope, uranium-233, can be produced from natural thorium and is studied for future industrial use in nuclear technology. Uranium-238 has a small probability for spontaneous fission or even induced fission with fast neutrons; uranium-235, and to a lesser degree uranium-233, have a much higher fission cross-section for slow neutrons. In sufficient concentration, these isotopes maintain a sustained nuclear chain reaction. This generates the heat in nuclear power reactors and produces the fissile material for nuclear weapons. The primary civilian use for uranium harnesses the heat energy to produce electricity. Depleted uranium (U) is used in kinetic energy penetrators and armor plating.

Helium-3 (He see also helion) is a light, stable isotope of helium with two protons and one neutron. (In contrast, the most common isotope, helium-4, has two protons and two neutrons.) Helium-3 and hydrogen-1 are the only stable nuclides with more protons than neutrons. It was discovered in 1939. Helium-3 atoms are fermionic and become a superfluid at the temperature of 2.491 mK.

Helium-3 occurs as a primordial nuclide, escaping from Earth's crust into its atmosphere and into outer space over millions of years. It is also thought to be a natural nucleogenic and cosmogenic nuclide, one produced when lithium is bombarded by natural neutrons, which can be released by spontaneous fission and by nuclear reactions with cosmic rays. Some found in the terrestrial atmosphere is a remnant of atmospheric and underwater nuclear weapons testing.

Aluminium-26 (Al, Al-26) is a radioactive isotope of the chemical element aluminium, decaying by either positron emission or electron capture to stable magnesium-26. The half-life of Al is 717,000 years. This is far too short for the isotope to survive as a primordial nuclide, but a small amount of it is produced by collisions of atoms with cosmic ray protons.

Decay of aluminium-26 also produces gamma rays and X-rays. The x-rays and Auger electrons are emitted by the excited atomic shell of the daughter Mg after the electron capture which typically leaves a hole in one of the lower sub-shells.

Enriched uranium is a type of uranium in which the percent composition of uranium-235 (written U) has been increased through the process of isotope separation. Naturally occurring uranium is composed of three major isotopes: uranium-238 (U with 99.2732–99.2752% natural abundance), uranium-235 (U, 0.7198–0.7210%), and uranium-234 (U, 0.0049–0.0059%). U is the only nuclide existing in nature (in any appreciable amount) that is fissile with thermal neutrons.

Enriched uranium is a critical component for both civil nuclear power generation and military nuclear weapons. Low-enriched uranium (below 20% U) is necessary to operate light water reactors, which make up almost 90% of nuclear electricity generation. Highly enriched uranium (above 20% U) is used for the cores of many nuclear weapons, as well as compact reactors for naval propulsion and research, as well as breeder reactors. There are about 2,000 tonnes of highly enriched uranium in the world.

Uranium-235 (
U or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exists in nature as a primordial nuclide.

Uranium-235 has a half-life of 704 million years. It was discovered in 1935 by Arthur Jeffrey Dempster. Its fission cross section for slow thermal neutrons is about 584.3±1 barns. For fast neutrons it is on the order of 1 barn.Most neutron absorptions induce fission, though a minority (about 15%) result in the formation of uranium-236.

Bismuth-209 (Bi) is an isotope of bismuth with the longest known half-life of any nuclide that undergoes α-decay (alpha decay); the decay product is thallium-205. It has 83 protons and a magic number of 126 neutrons, and naturally-occurring bismuth consists entirely of this isotope.

Thorium is a chemical element; it has symbol Th and atomic number 90. Thorium is a weakly radioactive light silver metal which tarnishes olive grey when it is exposed to air, forming thorium dioxide; it is moderately soft, malleable, and has a high melting point. Thorium is an electropositive actinide whose chemistry is dominated by the +4 oxidation state; it is quite reactive and can ignite in air when finely divided.

All known thorium isotopes are unstable. The most stable isotope, Th, has a half-life of 14.0 billion years, or about the age of the universe; it decays very slowly via alpha decay, starting a decay chain named the thorium series that ends at stable Pb. On Earth, thorium and uranium are the only elements with no stable or nearly-stable isotopes that still occur naturally in large quantities as primordial elements. Thorium is estimated to be over three times as abundant as uranium in the Earth's crust, and is chiefly refined from monazite sands as a by-product of extracting rare-earth elements.

Naturally occurring iodine (₅₃I) consists of one stable isotope, I, and is a mononuclidic element for atomic weight. Radioisotopes of iodine are known from I to I.

The longest-lived of those, I, has a half-life of 16.14 million years, which is too short for it to exist as a primordial nuclide. It is, however, found in nature as a trace isotope and universally distributed, produced naturally by cosmogenic sources in the atmosphere and by natural fission of the actinides. Today, however, most is artificial as fission product; like krypton-85 the contribution of past nuclear testing and of operating reactors are dwarfed by release from nuclear reprocessing.

A mononuclidic element or monotopic element is one of the 21 chemical elements that is found naturally on Earth essentially as a single nuclide (which may, or may not, be a stable nuclide). This single nuclide will have a characteristic atomic mass. Thus, the element's natural isotopic abundance is dominated by one isotope that is either stable or very long-lived. There are 19 elements in the first category (which are both monoisotopic and mononuclidic), and 2 (bismuth and protactinium) in the second category (mononuclidic but not monoisotopic, since they have zero, not one, stable nuclides). A list of the 21 mononuclidic elements is given at the end of this article.

Of the 26 monoisotopic elements that, by definition, have only one stable isotope, seven are not considered mononuclidic, due to the presence of a significant fraction of a very long-lived (primordial) radioisotope. These elements are vanadium, rubidium, indium, lanthanum, europium, lutetium, and rhenium.

Lead (₈₂Pb) has four observationally stable isotopes: Pb, Pb, Pb, Pb. Lead-204 is entirely a primordial nuclide and is not a radiogenic nuclide. The three isotopes lead-206, lead-207, and lead-208 represent the ends of three decay chains: the uranium series (or radium series), the actinium series, and the thorium series, respectively; a fourth decay chain, the neptunium series, terminates with the thallium isotope Tl. The three series terminating in lead represent the decay chain products of long-lived primordial U, U, and Th. Each isotope also occurs, to some extent, as primordial isotopes that were made in supernovae, rather than radiogenically as daughter products. The fixed ratio of lead-204 to the primordial amounts of the other lead isotopes may be used as the baseline to estimate the extra amounts of radiogenic lead present in rocks as a result of decay from uranium and thorium. This is the basis for lead–lead dating and uranium–lead dating.

The longest-lived radioisotopes, both decaying by electron capture, are Pb with a half-life of 17.0 million years and Pb with a half-life of 52,500 years. A shorter-lived naturally occurring radioisotope, Pb with a half-life of 22.2 years, is useful for studying the sedimentation chronology of environmental samples on time scales shorter than 100 years.

The neutron–proton ratio (N/Z ratio or nuclear ratio) of an atomic nucleus is the ratio of its number of neutrons to its number of protons. Among stable nuclei and naturally occurring nuclei, this ratio generally increases with increasing atomic number. This is because electrical repulsive forces between protons scale with distance differently than strong nuclear force attractions. In particular, most pairs of protons in large nuclei are not far enough apart, such that electrical repulsion dominates over the strong nuclear force, and thus proton density in stable larger nuclei must be lower than in stable smaller nuclei where more pairs of protons have appreciable short-range nuclear force attractions.

For many elements with atomic number Z small enough to occupy only the first three nuclear shells, that is up to that of calcium (Z = 20), there exists a stable isotope with N/Z ratio of one. The exceptions are beryllium (N/Z = 1.25) and every element with odd atomic number between 9 and 19 inclusive (though in those cases N = Z + 1 always allows for stability). Hydrogen-1 (N/Z ratio = 0) and helium-3 (N/Z ratio = 0.5) are the only stable isotopes with neutron–proton ratio under one. Uranium-238 has the highest N/Z ratio of any primordial nuclide at 1.587, while mercury-204 has the highest N/Z ratio of any known stable isotope at 1.55. Radioactive decay generally proceeds so as to change the N/Z ratio to increase stability. If the N/Z ratio is greater than 1, alpha decay increases the N/Z ratio, and hence provides a common pathway towards stability for decays involving large nuclei with too few neutrons. Positron emission and electron capture also increase the ratio, while beta decay decreases the ratio.

Naturally occurring zirconium (₄₀Zr) is composed of four stable isotopes (one, Zr, may in the future be found radioactive), and one very long-lived radioisotope (Zr), a primordial nuclide that decays via double beta decay with an observed half-life of 2.34 × 10 years; it can also undergo single beta decay, which is not yet observed, but the theoretically predicted value of t_1/2 is 2.4 × 10 years. The second most stable radioisotope is Zr, which has a half-life of 1.61 million years. Thirty other radioisotopes have been observed from Zr to Zr; all have half-lives less than a day except for Zr (64.032 days), Zr (83.4 days), and Zr (78.36 hours). The most stable of the isomeric states is just 4.16 minutes for Zr.

Radioactive isotopes above the theoretically stable mass numbers 90-92 decay by electron emission resulting in niobium isotopes, whereas those below by positron emission or electron capture, resulting in yttrium isotopes.

A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy excited state levels (higher energy levels). "Metastable" describes nuclei whose excited states have half-lives of 10 seconds or longer, 100 to 1000 times longer than the half-lives of the excited nuclear states that decay with a "prompt" half-life (ordinarily on the order of 10 seconds). Some references recommend 5×10 seconds to distinguish the metastable half-life from the normal "prompt" gamma-emission half-life.

The half-lives of a number of isomers are far longer than this and may be minutes, hours, or years. For example, the
₇₃Ta nuclear isomer survives so long (at least 2.9×10 years) that it has never been observed to decay spontaneously, and occurs naturally as a primordial nuclide, though uncommonly at only 1/8000 of all tantalum. The second most stable isomer is
₈₃Bi, which does not occur naturally; its half-life is 3.04×10 years to alpha decay. The half-life of a nuclear isomer can exceed that of the ground state of the same nuclide, as with the two above, as well as, for example,
₇₅Re,
₇₇Ir,
₈₄Po,
₉₅Am and multiple holmium isomers.