Miscible in the context of Upper critical solution temperature


Miscible in the context of Upper critical solution temperature

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⭐ Core Definition: Miscible

Miscibility (/ˌmɪsɪˈbɪlɪti/) is the property of two substances to mix in all proportions (that is, to fully dissolve in each other at any concentration), forming a homogeneous mixture (a solution). Such substances are said to be miscible (etymologically equivalent to the common term "mixable"). The term is most often applied to liquids, but also applies to solids and gases. An example in liquids is the miscibility of water and ethanol as they mix in all proportions.

By contrast, substances are said to be immiscible if the mixture does not form a solution for certain proportions. For one example, oil is not soluble in water, so these two solvents are immiscible. As another example, butanone (methyl ethyl ketone) is immiscible in water: it is soluble in water up to about 275 grams per liter, but will separate into two phases beyond that.

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👉 Miscible in the context of Upper critical solution temperature

The upper critical solution temperature (UCST) or upper consolute temperature is the critical temperature above which the components of a mixture are miscible in all proportions. The word upper indicates that the UCST is an upper bound to a temperature range of partial miscibility, or miscibility for certain compositions only. For example, hexane-nitrobenzene mixtures have a UCST of 19 °C (66 °F), so that these two substances are miscible in all proportions above 19 °C (66 °F) but not at lower temperatures. Examples at higher temperatures are the aniline-water system at 168 °C (334 °F) (at pressures high enough for liquid water to exist at that temperature), and the lead-zinc system at 798 °C (1,468 °F) (a temperature where both metals are liquid).

A solid state example is the palladium-hydrogen system which has a solid solution phase (H2 in Pd) in equilibrium with a hydride phase (PdHn) below the UCST at 300 °C. Above this temperature there is a single solid solution phase.

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Miscible in the context of Wetting

Wetting is the ability of a liquid to maintain contact with a solid surface by displacing another substance or material - either a gas, or other liquid not miscible with the wetting liquid - due to the differential strength of intermolecular interactions with the surface.

The degree of wetting, or wettability, is dependent on the force balance between adhesive and cohesive forces, occurring when liquid and solid make contact in the presence of another physical phase. As such, wetting is of importance to bonding and adherence of substances in different phases.

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Miscible in the context of Glycerol

Glycerol (/ˈɡlɪsərɒl/) is an organic compound with chemical formula C3H5(OH)3. It has a three-carbon backbone and is a simple triol compound (an alcohol with three hydroxyl groups). It is a colorless, odorless, sweet-tasting, viscous liquid. Because of its three hydroxyl groups, glycerol is miscible with water and is hygroscopic in nature.

The glycerol backbone is found in lipids known as glycerides, where one or more of the hydroxyl groups are esterified with fatty acids. The most abundant of glycerides are triglycerides (found in animal fats and vegetable oils), it is where glycerol is most commonly found in nature. It is also widely used as a sweetener in the food industry and as a humectant in pharmaceutical formulations.

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Miscible in the context of DMSO

Dimethyl sulfoxide (DMSO) is an organosulfur compound with the formula (CH3)2S=O. This colorless liquid is the sulfoxide most widely used commercially. It is an important polar aprotic solvent that dissolves both polar and nonpolar compounds and is miscible in a wide range of organic solvents as well as water. It has a relatively high boiling point. DMSO is metabolised to compounds that leave a garlic-like taste in the mouth after DMSO is absorbed by skin.

In terms of chemical structure, the molecule has idealized Cs symmetry. It has a trigonal pyramidal molecular geometry consistent with other three-coordinate S(IV) compounds, with a nonbonded electron pair on the approximately tetrahedral sulfur atom.

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Miscible in the context of Dichloromethane

Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula CH2Cl2. This colorless, volatile liquid with a chloroform-like, sweet odor is widely used as a solvent. Although it is not miscible with water, it is slightly polar and miscible with many organic solvents.

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Miscible in the context of Diethylene glycol

Diethylene glycol (DEG) is an organic compound with the formula (HOCH2CH2)2O. It is a colorless, practically odorless, and hygroscopic liquid with a sweetish taste. It is a four carbon dimer of ethylene glycol. It is miscible in water, alcohol, ether, acetone, and ethylene glycol. DEG is a widely used solvent. It can be a normal ingredient in various consumer products, and it can be a contaminant. DEG has also been misused to sweeten wine and beer, and to viscosify oral and topical pharmaceutical products. Its use has resulted in many epidemics of poisoning since the early 20th century.

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Miscible in the context of Separatory funnel

A separatory funnel, also known as a separation funnel, separating funnel, or colloquially sep funnel, is a piece of laboratory glassware used in liquid-liquid extractions to separate (partition) the components of a mixture into two immiscible solvent phases of different densities. Typically, one of the phases will be aqueous, and the other a lipophilic organic solvent such as ether, MTBE, dichloromethane, chloroform, or ethyl acetate. All of these solvents form a clear delineation between the two liquids. The more dense liquid, typically the aqueous phase unless the organic phase is halogenated, sinks to the bottom of the funnel and can be drained out through a valve away from the less dense liquid, which remains in the separatory funnel.

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Miscible in the context of Propylene glycol

Propylene glycol (IUPAC name: propane-1,2-diol) is a viscous, colorless liquid. It is almost odorless and has a faintly sweet taste. Its chemical formula is CH3CH(OH)CH2OH. As it contains two alcohol groups, it is classified as a diol. An aliphatic diol may also be called a glycol. It is miscible with a broad range of solvents, including water, acetone, and chloroform. In general, glycols are non-irritating and have very low volatility.

For certain uses as a food additive, propylene glycol is considered as GRAS by the US Food and Drug Administration, and is approved for food manufacturing. In the European Union, it has E-number E1520 for food applications. For cosmetics and pharmacology, the number is E490. Propylene glycol is also present in propylene glycol alginate, which is known as E405.

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Miscible in the context of Coalescence (chemistry)

In chemistry, coalescence is a process in which two phase domains of the same composition come together and form a larger phase domain. In other words, the process by which two or more separate masses of miscible substancesseem to "pull" each other together should they make the slightest contact.

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Miscible in the context of Decantation

Decantation is a process for the separation of mixtures of immiscible liquids or of a liquid and a solid mixture such as a suspension. The layer closer to the top of the container—the less dense of the two liquids, or the liquid from which the precipitate or sediment has settled out—is poured off, leaving denser liquid or the solid behind. The process typically is unable to remove all of the top layer, meaning the separation is incomplete or at least one of the two separated components is still contaminated by the other one.

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Miscible in the context of Glycerine

Glycerol (/ˈɡlɪsərɒl/) is a sugar alcohol with chemical formula C3H5(OH)3. It has three carbon atoms and as many hydroxyl groups. It is a colorless, odorless, sweet-tasting, viscous liquid at Standard Ambient Temperature and Pressure (SATP). Because of its three hydroxyl groups, glycerol is miscible with water and is hygroscopic in nature.

The glycerol backbone is found in lipids known as glycerides, where one or more of the hydroxyl groups are esterified with fatty acids. The most abundant of glycerides are triglycerides (found in animal fats and vegetable oils), it is where glycerol is most commonly found in nature. It is also widely used as a sweetener in the food industry and as a humectant in pharmaceutical formulations.

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Miscible in the context of Tetrahydrofuran

Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH2)4O. The compound is classified as heterocyclic compound, specifically a cyclic ether. It is a colorless, water-miscible organic liquid with low viscosity. It is mainly used as a precursor to polymers. Being polar and having a wide liquid range, THF is a versatile solvent. It is an isomer of another solvent, butanone.

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