Lanthanide contraction in the context of "Scandium group"

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👉 Lanthanide contraction in the context of Scandium group

Group 3 is the first group of transition metals in the periodic table. This group is closely related to the rare-earth elements. It contains the four elements scandium (Sc), yttrium (Y), lutetium (Lu), and lawrencium (Lr). The group is also called the scandium group or scandium family after its lightest member.

The chemistry of the group 3 elements is typical for early transition metals: they all essentially have only the group oxidation state of +3 as a major one, and like the preceding main-group metals are quite electropositive and have a less rich coordination chemistry. Due to the effects of the lanthanide contraction, yttrium and lutetium are very similar in properties. Yttrium and lutetium have essentially the chemistry of the heavy lanthanides, but scandium shows several differences due to its small size. This is a similar pattern to those of the early transition metal groups, where the lightest element is distinct from the very similar next two.

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Lanthanide contraction in the context of Lanthanide

A lanthanide (/ˈlænθənaɪd/) is any of the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. The IUPAC recommended standard name of this series is lanthanoid (/ˈlænθənɔɪd/).In the periodic table, they fill the 4f orbitals. Lutetium (element 71) is also sometimes considered a lanthanide, despite being a d-block element and a transition metal.

The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide. All but one of the lanthanides are f-block elements, corresponding to the filling of the 4f electron shell. Lutetium is a d-block element (thus also a transition metal), and on this basis its inclusion has been questioned; however, like its congeners scandium and yttrium in group 3, it behaves similarly to the other 14. The term rare-earth element or rare-earth metal is often used to include the stable group 3 elements Sc, Y, and Lu in addition to the 4f elements. All lanthanide elements form trivalent cations, Ln, whose chemistry is largely determined by the ionic radius, which decreases steadily from lanthanum (La) to lutetium (Lu).

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