Lamella (materials) in the context of Spherulite (polymer physics)


Lamella (materials) in the context of Spherulite (polymer physics)

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⭐ Core Definition: Lamella (materials)

A lamella (pl.: lamellae) is a small plate or flake, from the Latin, and may also refer to collections of fine sheets of material held adjacent to one another in a gill-shaped structure, often with fluid in between though sometimes simply a set of "welded" plates. The term is used in biological contexts for thin membranes of plates of tissue. In the context of materials science, the microscopic structures in bone and nacre are called lamellae. Moreover, the term lamella is often used to describe crystal structure of some materials.

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👉 Lamella (materials) in the context of Spherulite (polymer physics)

In polymer physics, spherulites (from Greek sphaira = ball and lithos = stone) are spherical semicrystalline regions inside non-branched linear polymers. Their formation is associated with crystallization of polymers from the melt and is controlled by several parameters such as the number of nucleation sites, structure of the polymer molecules, cooling rate, etc. Depending on those parameters, spherulite diameter may vary in a wide range from a few micrometers to millimeters. Spherulites are composed of highly ordered lamellae, which result in higher density, hardness, but also brittleness when compared to disordered regions in a polymer. The lamellae are connected by amorphous regions which provide elasticity and impact resistance. Alignment of the polymer molecules within the lamellae results in birefringence producing a variety of colored patterns, including a Maltese cross, when spherulites are viewed between crossed polarizers in an optical microscope.

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Lamella (materials) in the context of Crystallization of polymers

Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation. Crystallization affects optical, mechanical, thermal and chemical properties of the polymer. The degree of crystallinity is estimated by different analytical methods and it typically ranges between 10 and 80%, with crystallized polymers often called "semi-crystalline". The properties of semi-crystalline polymers are determined not only by the degree of crystallinity, but also by the size and orientation of the molecular chains.

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Lamella (materials) in the context of Widmanstätten patterns

A Widmanstätten pattern /ˈvɪdmɑːnˌʃttɪn/ (VID-man-shtay-tin), also known as a Thomson structure, is a figure of long phases of nickeliron, found in the octahedrite shapes of iron meteorite crystals and some pallasites.

Iron meteorites are very often formed from a single crystal of iron-nickel alloy, or sometimes several large crystals that may be many meters in size, and often lack any discernible crystal boundary on the surface. Large crystals are scarce in metals, and in meteors they occur from extremely slow cooling from a molten state in the vacuum of space when the Solar System first formed. Once in the solid state, the slow cooling then allows the solid solution to precipitate a separate phase that grows within the crystal lattice, which forms at particular angles that are determined by the lattice. In meteors, these interstitial defects can grow large enough to fill the entire crystal with needle or ribbon-like structures easily visible to the naked eye, almost entirely consuming the original lattice. They consist of a fine interleaving of kamacite and taenite bands or ribbons called lamellae. Commonly, in gaps between the lamellae, a fine-grained mixture of kamacite and taenite called plessite can be found.

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