In geometry, an improper rotation (also called rotation-reflection, rotoreflection, rotary reflection, or rotoinversion) is an isometry in Euclidean space that is a combination of a rotation about an axis and a reflection in a plane perpendicular to that axis. Reflection and inversion are each a special case of improper rotation. Any improper rotation is an affine transformation and, in cases that keep the coordinate origin fixed, a linear transformation.It is used as a symmetry operation in the context of geometric symmetry, molecular symmetry and crystallography, where an object that is unchanged by a combination of rotation and reflection is said to have improper rotation symmetry.
It is important to note the distinction between rotary reflection and rotary inversion symmetry operations and their associated symmetry elements. Rotary reflections are generally used to describe the symmetry of individual molecules and are defined as a 360°/n rotation about an n-fold rotation axis followed by a reflection over a mirror plane perpendicular to the n-fold rotation axis. Rotoinversions are generally used to describe the symmetry of crystals and are defined as a 360°/n rotation about an n-fold rotation axis followed by an inversion through the origin. Although rotary reflection operations have a rotoinversion analogue and vice versa, rotoreflections and rotoinversions of the same order need not be identical. For example, a 6-fold rotoinversion axis and its associated with symmetry operations are distinct from those resulting from a 6-fold reflection axis.