Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature. It is used to make most organofluorine compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material polytetrafluoroethylene (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers.
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👉 Hydrofluoric acid in the context of Carl Wilhelm Scheele
Carl Wilhelm Scheele (German: [ˈʃeːlə], Swedish: [ˈɧêːlɛ]; 9 December 1742 – 21 May 1786) was a German-Swedish pharmaceutical chemist.
Scheele discovered oxygen (although Joseph Priestley published his findings first), and identified the elements molybdenum, tungsten, barium, nitrogen, and chlorine, among others. Scheele discovered organic acids tartaric, oxalic, uric, lactic, and citric, as well as hydrofluoric, hydrocyanic, and arsenic acids. He preferred speaking German to Swedish his whole life, as German was commonly spoken among Swedish pharmacists.
In this Dossier
Hydrofluoric acid in the context of Etching (microfabrication)
Etching is used in microfabrication to chemically remove layers from the surface of a wafer during manufacturing. Etching is a critically important process module in fabrication, and every wafer undergoes many etching steps before it is complete.
For many etch steps, part of the wafer is protected from the etchant by a "masking" material which resists etching. In some cases, the masking material is a photoresist which has been patterned using photolithography. Other situations require a more durable mask, such as silicon nitride.
Hydrofluoric acid in the context of Laki
Laki (Icelandic pronunciation: [ˈlaːcɪ] ) or Lakagígar ([ˈlaːkaˌciːɣar̥], Craters of Laki) is a volcanic fissure in the western part of Vatnajökull National Park, Iceland, not far from the volcanic fissure of Eldgjá and the small village of Kirkjubæjarklaustur. The fissure is properly referred to as Lakagígar, while Laki is a mountain that the fissure bisects. Lakagígar is part of a volcanic system centered on the volcano Grímsvötn and including the volcano Þórðarhyrna. It lies between the glaciers of Mýrdalsjökull and Vatnajökull, in an area of fissures that run in a southwest to northeast direction.
The system erupted violently over an eight-month period between June 1783 and February 1784 from the Laki fissure and the adjoining volcano Grímsvötn. It poured out an estimated 42 billion tonnes or 14 km (18×10 cu yd) of basalt lava as well as clouds of poisonous hydrofluoric acid and sulfur dioxide compounds that contaminated the soil, leading to the death of over 50% of Iceland's livestock population, and the destruction of the vast majority of all crops. This led to a famine which then killed at least a fifth of the island's human population, although some have claimed a quarter.
Hydrofluoric acid in the context of Fluorapatite
Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various colors (green, brown, blue, yellow, violet, or colorless), the pure mineral is colorless, as expected for a material lacking transition metals. Along with hydroxylapatite, it can be a component of tooth enamel, especially in individuals who use fluoridated toothpaste, but for industrial use both minerals are mined in the form of phosphate rock, whose usual mineral composition is primarily fluorapatite but often with significant amounts of the other.
Fluorapatite crystallizes in a hexagonal crystal system. It is often combined as a solid solution with hydroxylapatite (Ca5(PO4)3OH or Ca10(PO4)6(OH)2) in biological matrices. Chlorapatite (Ca5(PO4)3Cl) is another related structure. Industrially, the mineral is an important source of both phosphoric and hydrofluoric acids.