Hydride in the context of Transition metal hydride


Hydride in the context of Transition metal hydride

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⭐ Core Definition: Hydride

In chemistry, a hydride is formally the anion of hydrogen (H), a hydrogen ion with two electrons. In modern usage, this is typically only used for ionic bonds, but it is sometimes (and has been more frequently in the past) applied to all compounds containing covalently bound H atoms. In this broad and potentially archaic sense, water (H2O) is a hydride of oxygen, ammonia is a hydride of nitrogen, etc. In covalent compounds, it implies hydrogen is attached to a less electronegative element. In such cases, the H centre has nucleophilic character, which contrasts with the protic character of acids. The hydride anion is very rarely observed.

Almost all of the elements up to Cf form binary compounds with hydrogen, the exceptions being He, Ne, Ar, Kr, Pm, Rn, Fr, and Ra. Exotic molecules such as positronium hydride have also been made.

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👉 Hydride in the context of Transition metal hydride

Transition metal hydrides are chemical compounds containing a transition metal bonded to hydrogen. Most transition metals form hydride complexes and some are significant in various catalytic and synthetic reactions. The term "hydride" is used loosely: some of them are acidic (e.g., H2Fe(CO)4), whereas some others are hydridic, having H-like character (e.g., ZnH2).

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Hydride in the context of Prebiotic atmosphere

The prebiotic atmosphere is the second atmosphere present on Earth before today's biotic, oxygen-rich third atmosphere, and after the first atmosphere (which was mainly water vapor and simple hydrides) of Earth's formation. The formation of the Earth, roughly 4.5 billion years ago, involved multiple collisions and coalescence of planetary embryos. This was followed by an over 100 million year period on Earth where a magma ocean was present, the atmosphere was mainly steam, and surface temperatures reached up to 8,000 K (14,000 °F). Earth's surface then cooled and the atmosphere stabilized, establishing the prebiotic atmosphere. The environmental conditions during this time period were quite different from today: the Sun was about 30% dimmer overall yet brighter at ultraviolet and x-ray wavelengths; there was a liquid ocean; it is unknown if there were continents but oceanic islands were likely; Earth's interior chemistry (and thus, volcanic activity) was different; there was a larger flux of impactors (e.g. comets and asteroids) hitting Earth's surface.

Studies have attempted to constrain the composition and nature of the prebiotic atmosphere by analyzing geochemical data and using theoretical models that include our knowledge of the early Earth environment. These studies indicate that the prebiotic atmosphere likely contained more CO2 than the modern Earth, had N2 within a factor of 2 of the modern levels, and had vanishingly low amounts of O2. The atmospheric chemistry is believed to have been "weakly reducing", where reduced gases like CH4, NH3, and H2 were present in small quantities. The composition of the prebiotic atmosphere was likely periodically altered by impactors, which may have temporarily caused the atmosphere to have been "strongly reduced".

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Hydride in the context of Hydron

In chemistry, the hydron, informally called proton, is the cationic form of atomic hydrogen, represented with the symbol H. The general term "hydron", endorsed by IUPAC, encompasses cations of hydrogen regardless of isotope: thus it refers collectively to protons (H) for the protium isotope, deuterons (H or D) for the deuterium isotope, and tritons (H or T) for the tritium isotope.

Unlike most other ions, the hydron consists only of a bare atomic nucleus. The negatively charged counterpart of the hydron is the hydride anion, H
.

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Hydride in the context of Lithium deuteride

Lithium hydride is an inorganic compound with the formula LiH. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not soluble but reactive with all protic organic solvents. It is soluble and nonreactive with certain molten salts such as lithium fluoride, lithium borohydride, and sodium hydride. With a molar mass of 7.95 g/mol, it is the lightest ionic compound.

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Hydride in the context of Plutonium

Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous.

Plutonium was first synthesized and isolated in late 1940 and early 1941, by deuteron bombardment of uranium-238 in the 1.5-metre (60 in) cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which then beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since uranium had been named after the planet Uranus and neptunium after the planet Neptune, element 94 was named after Pluto, which at the time was also considered a planet. Wartime secrecy prevented the University of California team from publishing its discovery until 1948.

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Hydride in the context of Binary compounds of hydrogen

Binary compounds of hydrogen are binary chemical compounds containing just hydrogen and one other chemical element. By convention all binary hydrogen compounds are called hydrides even when the hydrogen atom in it is not an anion. These hydrogen compounds can be grouped into several types.

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Hydride in the context of Siloxane

In organosilicon chemistry, a siloxane is an organic compound containing a functional group of two silicon atoms bound to an oxygen atom: Si−O−Si. The parent siloxanes include the oligomeric and polymeric hydrides with the formulae H[OSiH2]nOH and [OSiH2]n. Siloxanes also include branched compounds, the defining feature of which is that each pair of silicon centres is separated by one oxygen atom. The siloxane functional group forms the backbone of silicones [−R2Si−O−SiR2−]n, the premier example of which is polydimethylsiloxane (PDMS). The functional group R3SiO− (where the three Rs may be different) is called siloxy. Siloxanes are manmade and have many commercial and industrial applications because of the compounds’ hydrophobicity, low thermal conductivity, and high flexibility.

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Hydride in the context of Lactate dehydrogenase

Lactate dehydrogenase (LDH or LD) is an enzyme found in nearly all living cells. LDH catalyzes the conversion of pyruvate to lactate and back, as it converts NAD to NADH and back. A dehydrogenase is an enzyme that transfers a hydride from one molecule to another.

LDH exists in four distinct enzyme classes. This article is specifically about the NAD(P)-dependent L-lactate dehydrogenase. Other LDHs act on D-lactate and/or are dependent on cytochrome c: D-lactate dehydrogenase (cytochrome) and L-lactate dehydrogenase (cytochrome).

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Hydride in the context of Sodium hydride

Sodium hydride is the chemical compound with the empirical formula NaH. This alkali metal hydride is primarily used as a strong yet combustible base in organic synthesis. NaH is a saline (salt-like) hydride, composed of Na and H ions, in contrast to molecular hydrides such as borane, silane, germane, ammonia, and methane. It is an ionic material that is insoluble in all solvents (other than molten sodium metal), consistent with the fact that H ions do not exist in solution.

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Hydride in the context of Carbenes

In organic chemistry, a carbene is a molecule containing a neutral carbon atom with a valence of two and two unshared valence electrons. The general formula is R−:C−R' or R=C: where the R represents substituents or hydrogen atoms.

The term "carbene" may also refer to the specific compound :CH2, also called methylene, the parent hydride from which all other carbene compounds are formally derived.

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