Heavy water in the context of "Gilbert N. Lewis"

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⭐ Core Definition: Heavy water

Heavy water (deuterium oxide,
H
2
O
, D
2
O
) is a form of water in which hydrogen atoms are all deuterium (
H
or D, also known as heavy hydrogen) rather than the common hydrogen-1 isotope (
H
, also called protium) that makes up most of the hydrogen in normal water. The presence of the heavier isotope gives the water different nuclear properties, and the increase in mass gives it slightly different physical and chemical properties when compared to normal water.

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👉 Heavy water in the context of Gilbert N. Lewis

Gilbert Newton Lewis ForMemRS (October 23 or October 25, 1875 – March 23, 1946) was an American physical chemist and a dean of the college of chemistry at University of California, Berkeley. Lewis was best known for his discovery of the covalent bond and his concept of electron pairs; his Lewis dot structures and other contributions to valence bond theory have shaped modern theories of chemical bonding. Lewis successfully contributed to chemical thermodynamics, photochemistry, and isotope separation, and is also known for his concept of acids and bases. Lewis also researched on relativity and quantum physics, and in 1926 he coined the term "photon" for the smallest unit of radiant energy.

G. N. Lewis was born in 1875 in Weymouth, Massachusetts. After receiving his PhD in chemistry from Harvard University and studying abroad in Germany and the Philippines, Lewis moved to California in 1912 to teach chemistry at the University of California, Berkeley, where he became the dean of the college of chemistry and spent the rest of his life. As a professor, he incorporated thermodynamic principles into the chemistry curriculum and reformed chemical thermodynamics in a mathematically rigorous manner accessible to ordinary chemists. He began measuring the free energy values related to several chemical processes, both organic and inorganic. In 1916, he also proposed his theory of bonding and added information about electrons in the periodic table of the chemical elements. In 1933, he started his research on isotope separation. Lewis worked with hydrogen and managed to purify a sample of heavy water. He then came up with his theory of acids and bases, and did work in photochemistry during the last years of his life.

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Heavy water in the context of German nuclear weapons program

Nazi Germany undertook several research programs relating to nuclear technology, including nuclear weapons and nuclear reactors, before and during World War II. These were variously called Uranverein (Uranium Society) or Uranprojekt (Uranium Project). The first effort started in April 1939, just months after the discovery of nuclear fission in Berlin in December 1938, but ended shortly ahead of the September 1939 German invasion of Poland, for which many German physicists were drafted into the Wehrmacht. A second effort under the administrative purview of the Wehrmacht's Heereswaffenamt began on September 1, 1939, the day of the invasion of Poland. The program eventually expanded into three main efforts: Uranmaschine (nuclear reactor) development, uranium and heavy water production, and uranium isotope separation. Eventually, the German military determined that nuclear fission would not contribute significantly to the war, and in January 1942 the Heereswaffenamt turned the program over to the Reich Research Council (Reichsforschungsrat) while continuing to fund the activity.

The program was split up among nine major institutes where the directors dominated research and set their own objectives. Subsequently, the number of scientists working on applied nuclear fission began to diminish as many researchers applied their talents to more pressing wartime demands. The most influential people in the Uranverein included Kurt Diebner, Abraham Esau, Walther Gerlach, and Erich Schumann. Schumann was one of the most powerful and influential physicists in Germany. Diebner, throughout the life of the nuclear weapon project, had more control over nuclear fission research than did Walther Bothe, Klaus Clusius, Otto Hahn, Paul Harteck, or Werner Heisenberg. Esau was appointed as Reichsmarschall Hermann Göring's plenipotentiary for nuclear physics research in December 1942, and was succeeded by Walther Gerlach after he resigned in December 1943.

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Heavy water in the context of Deuterium

Deuterium (hydrogen-2, symbol H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen; the other is protium, or hydrogen-1, H. The deuterium nucleus (deuteron) contains one proton and one neutron, whereas the far more common H has no neutrons.

The name deuterium comes from Greek deuteros, meaning "second". American chemist Harold Urey discovered deuterium in 1931. Urey and others produced samples of heavy water in which the H had been highly concentrated. The discovery of deuterium won Urey a Nobel Prize in 1934.

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Heavy water in the context of Natural uranium

Natural uranium (NU or Unat) is uranium with the same isotopic ratio as found in nature. It contains 0.711% uranium-235, 99.284% uranium-238, and a trace of uranium-234 by weight (0.0055%). Approximately 2.2% of its radioactivity comes from uranium-235, 48.6% from uranium-238, and 49.2% from uranium-234.

Natural uranium can be used to fuel both low- and high-power nuclear reactors. Historically, graphite-moderated reactors and heavy water-moderated reactors have been fueled with natural uranium in the pure metal (U) or uranium dioxide (UO2) ceramic forms. However, experimental fuelings with uranium trioxide (UO3) and triuranium octaoxide (U3O8) have shown promise.

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Heavy water in the context of Neutrino detector

A neutrino detector is a physics apparatus which is designed to study neutrinos.Because neutrinos only weakly interact with other particles of matter, neutrino detectors must be very large to detect a significant number of neutrinos. Neutrino detectors are often built underground, to isolate the detector from cosmic rays and other background radiation. The field of neutrino astronomy is still very much in its infancy – the only confirmed extraterrestrial sources as of 2018 are the Sun and the supernova 1987A in the nearby Large Magellanic Cloud. Another likely source (three standard deviations) is the blazar TXS 0506+056 about 3.7 billion light years away. Neutrino observatories will "give astronomers fresh eyes with which to study the universe".

Various detection methods have been used. Super Kamiokande is a large volume of water surrounded by phototubes that watch for the Cherenkov radiation emitted when an incoming neutrino creates an electron or muon in the water. The Sudbury Neutrino Observatory was similar, but used heavy water as the detecting medium. Other detectors have consisted of large volumes of chlorine or gallium which are periodically checked for excesses of argon or germanium, respectively, which are created by neutrinos interacting with the original substance. MINOS used a solid plastic scintillator watched by phototubes; Borexino uses a liquid pseudocumene scintillator also watched by phototubes; and the NOνA detector uses a liquid scintillator watched by avalanche photodiodes.

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Heavy water in the context of Neutron moderator

In nuclear engineering, a neutron moderator is a medium that reduces the speed of fast neutrons, ideally without capturing any, leaving them as thermal neutrons with only minimal (thermal) kinetic energy. These thermal neutrons are immensely more susceptible than fast neutrons to propagate a nuclear chain reaction of uranium-235 or other fissile isotope by colliding with their atomic nucleus.

Water (sometimes called "light water" in this context) is the most commonly used moderator (roughly 75% of the world's reactors). Solid graphite (20% of reactors) and heavy water (5% of reactors) are the main alternatives. Beryllium has also been used in some experimental types, and hydrocarbons have been suggested as another possibility.

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