Heat capacity in the context of Joule


Heat capacity in the context of Joule

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⭐ Core Definition: Heat capacity

Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat that must be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). It quantifies the ability of a material or system to store thermal energy.

Heat capacity is an extensive property. The corresponding intensive property is the specific heat capacity, found by dividing the heat capacity of an object by its mass. Dividing the heat capacity by the amount of substance in moles yields its molar heat capacity. The volumetric heat capacity measures the heat capacity per volume. In architecture and civil engineering, the heat capacity of a building is often referred to as its thermal mass.

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Heat capacity in the context of Salinity

Salinity (/səˈlɪnɪti/) is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal to ).

Salinity is an important factor in determining many aspects of the chemistry of natural waters and of biological processes within it, and is a thermodynamic state variable that, along with temperature and pressure, governs physical characteristics like the density and heat capacity of the water. These in turn are important for understanding ocean currents and heat exchange with the atmosphere.

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Heat capacity in the context of Heat engine

A heat engine is a system that transfers thermal energy to do mechanical or electrical work. While originally conceived in the context of mechanical energy, the concept of the heat engine has been applied to various other kinds of energy, particularly electrical, since at least the late 19th century. The heat engine does this by bringing a working substance from a higher state temperature to a lower state temperature. A heat source generates thermal energy that brings the working substance to the higher temperature state. The working substance generates work in the working body of the engine while transferring heat to the colder sink until it reaches a lower temperature state. During this process some of the thermal energy is converted into work by exploiting the properties of the working substance. The working substance can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings and is not converted to work. Also, some energy is unusable because of friction and drag.

In general, an engine is any machine that converts energy to mechanical work. Heat engines distinguish themselves from other types of engines by the fact that their efficiency is fundamentally limited by Carnot's theorem of thermodynamics. Although this efficiency limitation can be a drawback, an advantage of heat engines is that most forms of energy can be easily converted to heat by processes like exothermic reactions (such as combustion), nuclear fission, absorption of light or energetic particles, friction, dissipation and resistance. Since the heat source that supplies thermal energy to the engine can thus be powered by virtually any kind of energy, heat engines cover a wide range of applications.

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Heat capacity in the context of Sea breeze

A sea breeze or onshore breeze is a wind that blows in the afternoon from a large body of water toward or onto a landmass. By contrast, a land breeze or offshore breeze is a wind that blows in the night from a landmass toward or onto a large body of water. Sea breezes and land breezes are both important factors in coastal regions' prevailing winds.

Sea breeze and land breeze develop due to differences in air pressure created by the differing heat capacities of water and dry land. As such, sea breezes and land breezes are more localised than prevailing winds. Since land heats up much faster than water under solar radiation, a sea breeze is a common occurrence along coasts after sunrise. On the other hand, dry land also cools faster than water without solar radiation, so the wind instead flows from the land towards the sea when the sea breeze dissipates after sunset.

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Heat capacity in the context of Statistical mechanics

In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. Sometimes called statistical physics or statistical thermodynamics, its applications include many problems in a wide variety of fields such as biology, neuroscience, computer science, information theory and sociology. Its main purpose is to clarify the properties of matter in aggregate, in terms of physical laws governing atomic motion.

Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions.

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Heat capacity in the context of Properties of water

Water (H2O) is a polar inorganic compound that is at room temperature a tasteless and odorless liquid, which is nearly colorless apart from an inherent hint of blue. It is by far the most studied chemical compound and is described as the "universal solvent" and the "solvent of life". It is the most abundant substance on the surface of Earth and the only common substance to exist as a solid, liquid, and gas on Earth's surface. It is also the third most abundant molecule in the universe (behind molecular hydrogen and carbon monoxide).

Water molecules form hydrogen bonds with each other and are strongly polar. This polarity allows it to dissociate ions in salts and bond to other polar substances such as alcohols and acids, thus dissolving them. Its hydrogen bonding causes its many unique properties, such as having a solid form less dense than its liquid form, a relatively high boiling point of 100 °C for its molar mass, and a high heat capacity.

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Heat capacity in the context of Ludwig Boltzmann

Ludwig Eduard Boltzmann (/ˈbɔːltsˌmɑːn/ BAWLTS-mahn or /ˈbltsmən/ BOHLTS-muhn; German: [ˈluːtvɪç ˈeːduaʁt ˈbɔltsman]; 20 February 1844 – 5 September 1906) was an Austrian mathematician and theoretical physicist. His greatest achievements were the development of statistical mechanics and the statistical explanation of the second law of thermodynamics. In 1877 he provided the current definition of entropy, , where Ω is the number of microstates whose energy equals the system's energy, interpreted as a measure of the statistical disorder of a system. Max Planck named the constant kB the Boltzmann constant.

Statistical mechanics is one of the pillars of modern physics. It describes how macroscopic observations (such as temperature and pressure) are related to microscopic parameters that fluctuate around an average. It connects thermodynamic quantities (such as heat capacity) to microscopic behavior, whereas, in classical thermodynamics, the only available option would be to measure and tabulate such quantities for various materials.

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Heat capacity in the context of Boltzmann constant

The Boltzmann constant (kB or k) is the proportionality factor that relates the average relative thermal energy of particles in a gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin (K) and the molar gas constant, in Planck's law of black-body radiation and Boltzmann's entropy formula, and is used in calculating thermal noise in resistors. The Boltzmann constant has dimensions of energy divided by temperature, the same as entropy and heat capacity. It is named after the Austrian scientist Ludwig Boltzmann.

As part of the 2019 revision of the SI, the Boltzmann constant is one of the seven "defining constants" that have been defined so as to have exact finite decimal values in SI units. They are used in various combinations to define the seven SI base units. The Boltzmann constant is defined to be exactly 1.380649×10 joules per kelvin, with the effect of defining the SI unit kelvin.

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Heat capacity in the context of Calorimeter

A calorimeter is a device used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity. Differential scanning calorimeters, isothermal micro calorimeters, titration calorimeters and accelerated rate calorimeters are among the most common types. A simple calorimeter just consists of a thermometer attached to a metal container full of water suspended above a combustion chamber. It is one of the measurement devices used in the study of thermodynamics, chemistry, and biochemistry.

To find the enthalpy change per mole of a substance A in a reaction between two substances A and B, the substances are separately added to a calorimeter and the initial and final temperatures (before the reaction has started and after it has finished) are noted. Multiplying the temperature change by the mass and specific heat capacities of the substances gives a value for the energy given off or absorbed during the reaction. Dividing the energy change by how many moles of A were present gives its enthalpy change of reaction. where q is the amount of heat according to the change in temperature measured in joules and Cv is the heat capacity of the calorimeter which is a value associated with each individual apparatus in units of energy per temperature (joules/kelvin).

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Heat capacity in the context of Solar power tower

A solar power tower, also known as 'central tower' power plant or 'heliostat' power plant, is a type of solar furnace using a tower to receive focused sunlight. It uses an array of flat, movable mirrors (called heliostats) to focus the sun's rays upon a collector tower (the target). Concentrating Solar Power (CSP) systems are seen as one viable solution for renewable, pollution-free energy.

Early designs used these focused rays to heat water and used the resulting steam to power a turbine. Newer designs using liquid sodium have been demonstrated, and systems using molten salts (40% potassium nitrate, 60% sodium nitrate) as the working fluids are now in operation. These working fluids have high heat capacity, which can be used to store the energy before using it to boil water to drive turbines. Storing the heat energy for later recovery allows power to be generated continuously, while the sun is shining, and for several hours after the sun has set (or been clouded over).

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Heat capacity in the context of Thermochemical

Thermochemistry is the study of the heat energy which is associated with chemical reactions and/or phase changes such as melting and boiling. A reaction may release or absorb energy, and a phase change may do the same. Thermochemistry focuses on the energy exchange between a system and its surroundings in the form of heat. Thermochemistry is useful in predicting reactant and product quantities throughout the course of a given reaction. In combination with entropy determinations, it is also used to predict whether a reaction is spontaneous or non-spontaneous, favorable or unfavorable.

Endothermic reactions absorb heat, while exothermic reactions release heat. Thermochemistry coalesces the concepts of thermodynamics with the concept of energy in the form of chemical bonds. The subject commonly includes calculations of such quantities as heat capacity, heat of combustion, heat of formation, enthalpy, entropy, and free energy.

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Heat capacity in the context of Thermal reservoir

A thermal reservoir, also thermal energy reservoir or thermal bath, is a thermodynamic system with a heat capacity so large that the temperature of the reservoir changes relatively little when a significant amount of heat is added or extracted. As a conceptual simplification, it effectively functions as an infinite pool of thermal energy at a given, constant temperature. Since it can act as an inertial source and sink of heat, it is often also referred to as a heat reservoir or heat bath.

Lakes, oceans and rivers often serve as thermal reservoirs in geophysical processes, such as the weather. In atmospheric science, large air masses in the atmosphere often function as thermal reservoirs.

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Heat capacity in the context of Specific heat capacity

In thermodynamics, the specific heat capacity (symbol c) of a substance is the amount of heat that must be added to one unit of mass of the substance in order to cause an increase of one unit in temperature. It is also referred to as massic heat capacity or as the specific heat. More formally it is the heat capacity of a sample of the substance divided by the mass of the sample. The SI unit of specific heat capacity is joule per kelvin per kilogram, J⋅kg⋅K. For example, the heat required to raise the temperature of 1 kg of water by 1 K is 4184 joules, so the specific heat capacity of water is 4184 J⋅kg⋅K.

Specific heat capacity often varies with temperature, and is different for each state of matter. Liquid water has one of the highest specific heat capacities among common substances, about 4184 J⋅kg⋅K at 20 °C; but that of ice, just below 0 °C, is only 2093 J⋅kg⋅K. The specific heat capacities of iron, granite, and hydrogen gas are about 449 J⋅kg⋅K, 790 J⋅kg⋅K, and 14300 J⋅kg⋅K, respectively. While the substance is undergoing a phase transition, such as melting or boiling, its specific heat capacity is technically undefined, because the heat goes into changing its state rather than raising its temperature.

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Heat capacity in the context of Molar heat capacity

The molar heat capacity of a chemical substance is the amount of energy that must be added, in the form of heat, to one mole of the substance in order to cause an increase of one unit in its temperature. Alternatively, it is the heat capacity of a sample of the substance divided by the amount of substance of the sample; or also the specific heat capacity of the substance times its molar mass. The SI unit of molar heat capacity is joule per kelvin per mole, J⋅K⋅mol.

Like the specific heat, the measured molar heat capacity of a substance, especially a gas, may be significantly higher when the sample is allowed to expand as it is heated (at constant pressure, or isobaric) than when it is heated in a closed vessel that prevents expansion (at constant volume, or isochoric). The ratio between the two, however, is the same heat capacity ratio obtained from the corresponding specific heat capacities.

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Heat capacity in the context of Volumetric heat capacity

The volumetric heat capacity of a material is the heat capacity of a sample of the substance divided by the volume of the sample. It is the amount of energy that must be added, in the form of heat, to one unit of volume of the material in order to cause an increase of one unit in its temperature. The SI unit of volumetric heat capacity is joule per kelvin per cubic meter, J⋅K⋅m.

The volumetric heat capacity can also be expressed as the specific heat capacity (heat capacity per unit of mass, in J⋅K⋅kg) times the density of the substance (in kg/L, or g/mL). It is defined to serve as an intensive property.

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Heat capacity in the context of Thermal mass

In building design, thermal mass is a property of the matter of a building that requires a flow of heat in order for it to change temperature.

Not all writers agree on what physical property of matter "thermal mass" describes. Most writers use it as a synonym for heat capacity, the ability of a body to store thermal energy. It is typically referred to by the symbol Cth, and its SI unit is J/K or J/°C (which are equivalent).

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