Freezing in the context of Nucleating agents


Freezing in the context of Nucleating agents

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⭐ Core Definition: Freezing

Freezing is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point.

For most substances, the melting and freezing points are the same temperature; however, certain substances possess differing solid-liquid transition temperatures. For example, agar displays a hysteresis in its melting point and freezing point. It melts at 85 °C (185 °F) and solidifies from 32 to 40 °C (90 to 104 °F).

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Freezing in the context of Sea water

Seawater, or sea water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approximately 35 grams (1.2 oz) of dissolved salts (predominantly sodium (Na) and chloride (Cl) ions). The average density at the surface is 1.025 kg/L. Seawater is denser than both fresh water and pure water (density 1.0 kg/L at 4 °C (39 °F)) because the dissolved salts increase the mass by a larger proportion than the volume. The freezing point of seawater decreases as salt concentration increases. At typical salinity, it freezes at about −2 °C (28 °F). The coldest seawater still in the liquid state ever recorded was found in 2010, in a stream under an Antarctic glacier: the measured temperature was −2.6 °C (27.3 °F).

Seawater pH is typically limited to a range between 7.5 and 8.4. However, there is no universally accepted reference pH-scale for seawater and the difference between measurements based on different reference scales may be up to 0.14 units.

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Freezing in the context of Snow

Snow consists of individual ice crystals that grow while suspended in the atmosphere—usually within clouds—and then fall, accumulating on the ground where they undergo further changes. It consists of frozen crystalline water throughout its life cycle, starting when, under suitable conditions, the ice crystals form in the atmosphere, increase to millimeter size, precipitate and accumulate on surfaces, then metamorphose in place, and ultimately melt, slide, or sublimate away.

Snowstorms organize and develop by feeding on sources of atmospheric moisture and cold air. Snowflakes nucleate around particles in the atmosphere by attracting supercooled water droplets, which freeze in hexagonal-shaped crystals. Snowflakes take on a variety of shapes, basic among these are platelets, needles, columns, and rime. As snow accumulates into a snowpack, it may blow into drifts. Over time, accumulated snow metamorphoses, by sintering, sublimation, and freeze-thaw. Where the climate is cold enough for year-to-year accumulation, a glacier may form. Otherwise, snow typically melts seasonally, causing runoff into streams and rivers and recharging groundwater.

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Freezing in the context of Ice

Ice is water that is frozen into a solid state, typically forming at or below temperatures of 0 °C, 32 °F, or 273.15 K. It occurs naturally on Earth, on other planets, in Oort cloud objects, and as interstellar ice. As a naturally occurring crystalline inorganic solid with an ordered structure, ice is considered to be a mineral. Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaque bluish-white color.

Virtually all of the ice on Earth is of a hexagonal crystalline structure denoted as ice Ih (spoken as "ice one h"). Depending on temperature and pressure, at least nineteen phases (packing geometries) can exist. The most common phase transition to ice Ih occurs when liquid water is cooled below °C (273.15 K, 32 °F) at standard atmospheric pressure. When water is cooled rapidly (quenching), up to three types of amorphous ice can form. Interstellar ice is overwhelmingly low-density amorphous ice (LDA), which likely makes LDA ice the most abundant type in the universe. When cooled slowly, correlated proton tunneling occurs below −253.15 °C (20 K, −423.67 °F) giving rise to macroscopic quantum phenomena.

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Freezing in the context of Crystallization

Crystallization is a process that leads to solids with highly organized atoms or molecules, i.e. a crystal. The ordered nature of a crystalline solid can be contrasted with amorphous solids in which atoms or molecules lack regular organization. Crystallization can occur by various routes including precipitation from solution, freezing of a liquid, or deposition from a gas. Attributes of the resulting crystal can depend largely on factors such as temperature, air pressure, cooling rate, or solute concentration.

Crystallization occurs in two main phases. The first is nucleation, the appearance of a crystalline phase from either a supercooled liquid or a supersaturated solvent. The second step is known as crystal growth, which is the increase in the size of particles and leads to a crystal state. An important feature of this step is that loose particles form layers at the crystal's surface and lodge themselves into open inconsistencies such as pores, cracks, etc.

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Freezing in the context of Outgassing

Outgassing (sometimes called offgassing, particularly when in reference to indoor air quality) is the release of a gas that was dissolved, trapped, frozen, or absorbed in some material. Outgassing can include sublimation and evaporation (which are phase transitions of a substance into a gas), as well as desorption, seepage from cracks or internal volumes, and gaseous products of slow chemical reactions. Boiling is generally thought of as a separate phenomenon from outgassing because it consists of a phase transition of a liquid into a vapor of the same substance.

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Freezing in the context of Snowball Earth

The Snowball Earth is a geohistorical hypothesis that proposes that during one or more of Earth's icehouse climates, the planet's surface became nearly entirely frozen with no liquid oceanic or surface water exposed to the atmosphere. The most academically mentioned period of such a global ice age is believed to have occurred some time before 650 mya during the Cryogenian period, which included at least two large glacial periods, the Sturtian and Marinoan glaciations.

Proponents of the hypothesis argue that it best explains sedimentary deposits that are generally believed to be of glacial origin at tropical palaeolatitudes and other enigmatic features in the geological record. Opponents of the hypothesis contest the geological evidence for global glaciation and the geophysical feasibility of an ice- or slush-covered ocean, and they emphasize the difficulty of escaping an all-frozen condition. Several unanswered questions remain, including whether Earth was a full "snowball" or a "slushball" with a thin equatorial band of open (or seasonally open) water. The Snowball Earth episodes are proposed to have occurred before the sudden radiations of multicellular bioforms known as the Avalon and Cambrian explosions; the most recent Snowball episode may have triggered the evolution of multicellularity.

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Freezing in the context of Snowstorm

A winter storm (also known as snow storm) is an event in which wind coincides with varieties of precipitation that only occur at freezing temperatures, such as snow, mixed snow and rain, or freezing rain. In temperate continental and subarctic climates, these storms are not necessarily restricted to the winter season, but may occur in the late autumn and early spring as well. A snowstorm with strong winds and low visibility is called a blizzard.

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Freezing in the context of Snowflake

A snowflake is a single ice crystal that is large enough to fall through the Earth's atmosphere as snow. Snow appears white in color despite being made of clear ice. This is because the many small crystal facets of the snowflakes scatter the sunlight between them.

Each flake begins by forming around a tiny particle, called its nucleus, accumulating water droplets, which freeze and slowly form a crystal. Complex shapes emerge as the flake moves through differing temperature and humidity zones in the atmosphere, and possibly combines with other snowflakes. Because of this, snowflakes tend to look very different from one another. However, they may be categorized in eight broad classifications and at least 80 individual variants. The main constituent shapes for ice crystals, from which combinations may occur, are needle, column, plate, and rime.

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Freezing in the context of Nucleation

In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) significantly below 0 °C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0 °C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay.

Nucleation is a common mechanism which generates first-order phase transitions, and it is the start of the process of forming a new thermodynamic phase. In contrast, new phases at continuous phase transitions start to form immediately.

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Freezing in the context of Freeze-thaw

Frost weathering is a collective term for several mechanical weathering processes induced by stresses created by the freezing of water into ice. The term serves as an umbrella term for a variety of processes, such as frost shattering, frost wedging, and cryofracturing. The process may act on a wide range of spatial and temporal scales, from minutes to years and from dislodging mineral grains to fracturing boulders. It is most pronounced in high-altitude and high-latitude areas and is especially associated with alpine, periglacial, subpolar maritime, and polar climates, but may occur anywhere at sub-freezing temperatures (between −3 and −8 °C (27 and 18 °F)) if water is present.

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Freezing in the context of Frost

Frost is a layer of ice on a solid surface, which forms from water vapor that deposits onto a freezing surface. Frost forms when the air contains more water vapor than it can normally hold at a specific temperature. The process is similar to the formation of dew, except it occurs below the freezing point of water typically without crossing through a liquid state.

Air always contains a certain amount of water vapor, depending on temperature. Warmer air can hold more than colder air. When the atmosphere contains more water than it can hold at a specific temperature, its relative humidity rises above 100% becoming supersaturated, and the excess water vapor is forced to deposit onto any nearby surface, forming seed crystals. The temperature at which it will form is called the dew point, and depends on the humidity of air. When the temperature of the air drops below its dew point, excess water vapor is forced out of solution, resulting in a phase change directly from water vapor (a gas) to ice (a solid). As more water molecules are added to the seeds, crystal growth occurs, forming ice crystals. Crystals may vary in size and shape, from an even layer of numerous microscopic-seeds to fewer but much larger crystals, ranging from long dendritic crystals (tree-like) growing across a surface, acicular crystals (needle-like) growing outward from the surface, snowflake-shaped crystals, or even large, knifelike blades of ice covering an object, which depends on many factors such as temperature, air pressure, air motion and turbulence, surface roughness and wettability, and the level of supersaturation. For example, water vapor adsorbs to glass very well, so automobile windows will often frost before the paint, and large hoar-frost crystals can grow very rapidly when the air is very cold, calm, and heavily saturated, such as during an ice fog.

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Freezing in the context of Toaster Strudel

Toaster Strudel is the brand name of a toaster pastry, prepared by heating the frozen pastries in a toaster and then spreading the included icing packet on top. The brand is historically notable for being stored frozen, due to innovations in 1980s food manufacturing processes.

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Freezing in the context of Enthalpy of fusion

In thermodynamics, the enthalpy of fusion, also known as latent heat of fusion or heat of fusion, of a substance is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure.

The enthalpy of fusion is the amount of energy required to convert one mole of solid into liquid. For example, when melting 1 kg of ice (at 0 °C under a wide range of pressures), 333.55 kJ of energy is absorbed with no temperature change. The heat of solidification (when a substance changes from liquid to solid) is equal in magnitude and opposite in sign.

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Freezing in the context of Frozen food

Freezing food preserves it from the time it is prepared to the time it is eaten. Since early times, farmers, fishermen, and trappers have preserved grains and produce in unheated buildings during the winter season. Freezing food slows decomposition by turning residual moisture into ice, inhibiting the growth of most bacterial species. In the food commodity industry, there are two processes: mechanical and cryogenic (or flash freezing). The freezing kinetics is important to preserve the food quality and texture. Quicker freezing generates smaller ice crystals and maintains cellular structure. Cryogenic freezing is the quickest freezing technology available due to the ultra low liquid nitrogen temperature −196 °C (−320 °F).

Preserving food in domestic kitchens during modern times is achieved using household freezers. Accepted advice to householders was to freeze food on the day of purchase. An initiative by a supermarket group in 2012 (backed by the United Kingdom's Waste & Resources Action Programme) promotes the freezing of food "as soon as possible up to the product's 'use by' date". The Food Standards Agency was reported as supporting the change, provided the food had been stored correctly up to that time.

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