Ferberite is the iron endmember of the manganese–iron wolframite solid solution series. The manganese endmember is hübnerite. Ferberite is a black monoclinic mineral composed of iron(II) tungstate, FeWO4.
Ferberite and hübnerite often contain both divalent cations of iron and manganese, with wolframite as the intermediate species for which the solid solution series is named.
Wolframite is an iron, manganese, and tungstate mineral with a chemical formula of (Fe,Mn)WO4 that is the intermediate mineral between ferberite (Fe rich) and hübnerite (Mn rich). Along with scheelite, the wolframite series are the most important tungsten ore minerals. Wolframite is found in quartz veins and pegmatites associated with granitic intrusives. Associated minerals include cassiterite, scheelite, bismuth, quartz, pyrite, galena, sphalerite, and arsenopyrite.
This mineral was historically found in Europe in Bohemia, Saxony, and in the UK in Devon and Cornwall. China reportedly has the world's largest supply of tungsten ore with about 60%. Other producers are Spain, Canada, Portugal, Russia, Australia, Thailand, South Korea, Rwanda, Bolivia, the United States, and the Democratic Republic of the Congo.
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