Electrical charge in the context of Polyatomic anion

An ion (/ˈaɪ.ɒn, -ən/) is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons.

A cation is a positively charged ion with fewer electrons than protons (e.g. K (potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl (chloride ion) and OH (hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed monatomic ions, atomic ions or simple ions, while ions consisting of two or more atoms are termed polyatomic ions or molecular ions.

In mathematics, the concept of a measure is a generalization and formalization of geometrical measures (length, area, volume) and other common notions, such as magnitude, mass, and probability of events. These seemingly distinct concepts have many similarities and can often be treated together in a single mathematical context. Measures are foundational in probability theory, integration theory, and can be generalized to assume negative values, as with electrical charge. Far-reaching generalizations (such as spectral measures and projection-valued measures) of measure are widely used in quantum physics and physics in general.

The intuition behind this concept dates back to Ancient Greece, when Archimedes tried to calculate the area of a circle. But it was not until the late 19th and early 20th centuries that measure theory became a branch of mathematics. The foundations of modern measure theory were laid in the works of Émile Borel, Henri Lebesgue, Nikolai Luzin, Johann Radon, Constantin Carathéodory, and Maurice Fréchet, among others. According to Thomas W. Hawkins Jr., "It was primarily through the theory of multiple integrals and, in particular the work of Camille Jordan that the importance of the notion of measurability was first recognized."

A polyatomic ion (also known as a molecular ion) is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that usually has a net charge that is not zero, or in special case of zwitterion where spatially separated charges where the net charge may be variable depending on acidity conditions. The term molecule may or may not be used to refer to a polyatomic ion, depending on the definition used. The prefix poly- carries the meaning "many" in Greek, but even ions of two atoms are commonly described as polyatomic. There may be more than one atom in the structure that has non-zero charge, therefore the net charge of the structure may have a cationic (positive) or anionic nature depending on those atomic details.

In older literature, a polyatomic ion may instead be referred to as a radical (or less commonly, as a radical group). In contemporary usage, the term radical refers to various free radicals, which are species that have an unpaired electron and need not be charged.

In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms are fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero. Beside nearly-pure ionic bonding, many covalent bonds exhibit a strong ionicity, making oxidation state a useful predictor of charge.

The oxidation state of an atom does not represent the "real" charge on that atom, or any other actual atomic property. This is particularly true of high oxidation states, where the ionization energy required to produce a multiply positive ion is far greater than the energies available in chemical reactions. Additionally, the oxidation states of atoms in a given compound may vary depending on the choice of electronegativity scale used in their calculation. Thus, the oxidation state of an atom in a compound is purely a formalism. It is nevertheless important in understanding the nomenclature conventions of inorganic compounds. Also, several observations regarding chemical reactions may be explained at a basic level in terms of oxidation states.

Spacecraft charging is a physical phenomenon where spacecraft accumulate electrical charge while operating in space environments. This effect occurs due to interactions between the spacecraft and the surrounding plasma environment, solar radiation, and cosmic rays.

The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. The SI unit for electric dipole moment is the coulomb-metre (C⋅m). The debye (D) is another unit of measurement used in atomic physics and chemistry.

Theoretically, an electric dipole is defined by the first-order term of the multipole expansion; it consists of two equal and opposite charges that are infinitesimally close together, although real dipoles have separated charge.
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Atmospheric electricity describes the electrical charges in the Earth's atmosphere (or that of another planet). The movement of charge between the Earth's surface, the atmosphere, and the ionosphere is known as the global atmospheric electrical circuit. Atmospheric electricity is an interdisciplinary topic with a long history, involving concepts from electrostatics, atmospheric physics, meteorology and Earth science.

Thunderstorms act as a giant battery in the atmosphere, charging up the electrosphere to about 400,000 volts with respect to the surface. This sets up an electric field throughout the atmosphere, which decreases with increase in altitude. Atmospheric ions created by cosmic rays and natural radioactivity move in the electric field, so a very small current flows through the atmosphere, even away from thunderstorms. Near the surface of the Earth, the magnitude of the field is on average around 100 V/m, oriented such that it drives positive charges down.

The farad (symbol: F) is the unit of electrical capacitance, the ability of a body to store an electrical charge, in the International System of Units (SI), equivalent to 1 coulomb per volt (C/V). It is named after the English physicist Michael Faraday (1791–1867). In SI base units 1 F = 1 kg⋅m⋅s⋅A.