Dissolution (chemistry) in the context of "Solvent"

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⭐ Core Definition: Dissolution (chemistry)

Solvations describes the interaction of a solvent with dissolved molecules. Both ionized and uncharged molecules interact strongly with a solvent, and the strength and nature of this interaction influence many properties of the solute, including solubility, reactivity, and color, as well as influencing the properties of the solvent such as its viscosity and density. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. The surrounded solute particles then move away from the solid solute and out into the solution. Ions are surrounded by a concentric shell of solvent. Solvation is the process of reorganizing solvent and solute molecules into solvation complexes and involves bond formation, hydrogen bonding, and van der Waals forces. Solvation of a solute by water is called hydration.

Solubility of solid compounds depends on a competition between lattice energy and solvation, including entropy effects related to changes in the solvent structure.

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Dissolution (chemistry) in the context of Hydrophobe

In chemistry, hydrophobicity is the chemical property of a molecule (called a hydrophobe) that is seemingly repelled from a mass of water. In contrast, hydrophiles are attracted to water.

Hydrophobic molecules tend to be nonpolar and, thus, prefer other neutral molecules and nonpolar solvents. Because water molecules are polar, hydrophobes do not dissolve well among them. Hydrophobic molecules in water often cluster together, forming micelles. Water on hydrophobic surfaces will exhibit a high contact angle.

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Dissolution (chemistry) in the context of Oxygen saturation

Oxygen saturation (symbol SO2) is a relative measure of the concentration of oxygen that is dissolved or carried in a given medium as a proportion of the maximal concentration that can be dissolved in that medium at the given temperature. It can be measured with a dissolved oxygen probe such as an oxygen sensor or an optode in liquid media, usually water. The standard unit of oxygen saturation is percent (%).

Oxygen saturation can be measured regionally and noninvasively. Arterial oxygen saturation (SaO2) is commonly measured using pulse oximetry. Tissue saturation at peripheral scale can be measured using NIRS. This technique can be applied on both muscle and brain.

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Dissolution (chemistry) in the context of Subsidence

Subsidence is a general term for downward vertical movement of the Earth's surface, which can be caused by both natural processes and human activities. Subsidence involves little or no horizontal movement, which distinguishes it from slope movement.

Processes that lead to subsidence include dissolution of underlying carbonate rock by groundwater; gradual compaction of sediments; withdrawal of fluid lava from beneath a solidified crust of rock; mining; pumping of subsurface fluids, such as groundwater or petroleum; or warping of the Earth's crust by tectonic forces. Subsidence resulting from tectonic deformation of the crust is known as tectonic subsidence and can create accommodation for sediments to accumulate and eventually lithify into sedimentary rock.

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Dissolution (chemistry) in the context of Hydrophile

A hydrophile is a molecule or other molecular entity that is attracted to water molecules and tends to be dissolved by water.

In contrast, hydrophobes are not attracted to water and may seem to be repelled by it. Hygroscopics are attracted to water, but are not dissolved by water.

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Dissolution (chemistry) in the context of Adsorption

Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the adsorbate on the surface of the adsorbent. This process differs from absorption, in which a fluid (the absorbate) is dissolved by or permeates a liquid or solid (the absorbent). While adsorption does often precede absorption, which involves the transfer of the absorbate into the volume of the absorbent material, alternatively, adsorption is distinctly a surface phenomenon, wherein the adsorbate does not penetrate through the material surface and into the bulk of the adsorbent. The term sorption encompasses both adsorption and absorption, and desorption is the reverse of sorption.

Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in the material. However, atoms on the surface of the adsorbent are not wholly surrounded by other adsorbent atoms and therefore can attract adsorbates. The exact nature of the bonding depends on the details of the species involved, but the adsorption process is generally classified as physisorption (characteristic of weak van der Waals forces) or chemisorption (characteristic of covalent bonding). It may also occur due to electrostatic attraction. The nature of the adsorption can affect the structure of the adsorbed species. For example, polymer physisorption from solution can result in squashed structures on a surface.

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Dissolution (chemistry) in the context of Miscibility

Miscibility (/ˌmɪsɪˈbɪlɪti/) is the property of two substances to mix in all proportions (that is, to fully dissolve in each other at any concentration), forming a homogeneous mixture (a solution). Such substances are said to be miscible (etymologically equivalent to the common term "mixable"). The term is most often applied to liquids, but also applies to solids and gases. An example in liquids is the miscibility of water and ethanol as they mix in all proportions.

By contrast, substances are said to be immiscible if the mixture does not form a solution for certain proportions. For one example, oil is not soluble in water, so these two solvents are immiscible. As another example, butanone (methyl ethyl ketone) is immiscible in water: it is soluble in water up to about 275 grams per liter, but will separate into two phases beyond that.

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Dissolution (chemistry) in the context of Starch gelatinization

Starch gelatinization is a process of breaking down of intermolecular bonds of starch molecules in the presence of water and heat, allowing the hydrogen bonding sites (the hydroxyl hydrogen and oxygen) to engage more water. This irreversibly dissolves the starch granule in water. Water acts as a plasticizer.

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Dissolution (chemistry) in the context of Bentonite

Bentonite (/ˈbɛntənt/ BEN-tə-nyte) is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-montmorillonite.

Bentonite usually forms from the weathering of volcanic ash in seawater, or by hydrothermal circulation through the porosity of volcanic ash beds, which converts (devitrification) the volcanic glass (obsidian, a volcanic glass with a chemical composition equivalent to rhyolite) present in the ash into clay minerals. In the mineral alteration process, a large fraction (up to 40–50 wt.%) of amorphous silica is dissolved and leached away, leaving the bentonite deposit in place. Bentonite beds are white or pale blue or green (traces of reduced Fe
) in fresh exposures, turning to a cream color and then yellow, red, or brown (traces of oxidized Fe
) as the exposure is weathered further.

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