Devitrification is the process of crystallization in a formerly crystal-free (amorphous) glass. The term is derived from the Latin vitreus, meaning glassy and transparent.
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👉 Devitrification in the context of Bentonite
Bentonite (/ˈbɛntənaɪt/ BEN-tə-nyte) is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-montmorillonite.
Bentonite usually forms from the weathering of volcanic ash in seawater, or by hydrothermal circulation through the porosity of volcanic ash beds, which converts (devitrification) the volcanic glass (obsidian, a volcanic glass with a chemical composition equivalent to rhyolite) present in the ash into clay minerals. In the mineral alteration process, a large fraction (up to 40–50 wt.%) of amorphous silica is dissolved and leached away, leaving the bentonite deposit in place. Bentonite beds are white or pale blue or green (traces of reduced Fe
) in fresh exposures, turning to a cream color and then yellow, red, or brown (traces of oxidized Fe
) as the exposure is weathered further.
In this Dossier
Devitrification in the context of Clinoptilolite
Clinoptilolite is a natural zeolite composed of a microporous arrangement of silica and alumina tetrahedra. It has the complex formula (Na,K,Ca)
2–3Al
3(Al,Si)
2Si
13O
36•12H
2O. It forms as white, green to reddish tabular monoclinic tectosilicate crystals with a Mohs hardness of 3.5 to 4 and a specific gravity of 2.1 to 2.2. It commonly occurs as a devitrification product of volcanic glass shards in tuff and as vesicle fillings in basalts, andesites and rhyolites. It was described in 1969 from an occurrence in the Barstow Formation, San Bernardino County, California. Sodium levels in clinoptilolite are generally higher than potassium levels, as is the case with the San Bernardino Barstow Formation, but there are sources that are potassium-rich and have minimal sodium.
It forms a series with heulandite: