The discovery of the neutron and its properties was central to the extraordinary developments in atomic physics in the first half of the 20th century. Early in the century, Ernest Rutherford used alpha particle scattering to discover that an atom has its mass and electric charge concentrated in a tiny nucleus. By 1920, isotopes of chemical elements had been discovered, the atomic masses had been determined to be approximately integer multiples of the mass of the hydrogen atom, and the atomic number had been identified as the charge on the nucleus. Throughout the 1920s, the nucleus was viewed as composed of combinations of protons and electrons, the two elementary particles known at the time, but that model presented several experimental and theoretical contradictions.
The essential nature of the atomic nucleus was established with the discovery of the neutron by James Chadwick in 1932 and the determination that it was a new elementary particle, distinct from the proton.