Diopside in the context of "Orthopyroxene"

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⭐ Core Definition: Diopside

Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2
O
6
. It forms complete solid solution series with hedenbergite (FeCaSi
2
O
6
) and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

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Diopside in the context of Lapis lazuli

Lapis lazuli (UK: /ˌlæpɪs ˈlæz(j)ʊli, ˈlæʒʊ-, -ˌli/; US: /ˈlæz(j)əli, ˈlæʒə-, -ˌliˌ læˈzli/) is a deep-blue metamorphic rock used as a semi-precious stone that has been prized since antiquity for its intense color. Its name originates from the Persian word for the gem, lāžward, and serves as the root for the word for "blue" in several languages, including Spanish and Portuguese azul and English azure. Lapis lazuli is a rock composed primarily of the minerals lazurite, pyrite, diopside, and calcite. As early as the 7th millennium BC, lapis lazuli was mined in the Sar-i Sang mines, in Shortugai, and in other mines in Badakhshan province in modern northeast Afghanistan. Lapis lazuli artifacts, dated to 7570 BC, have been found at Bhirrana, which is the oldest site of Indus Valley Civilisation. Lapis was highly valued by the Indus Valley Civilisation (3300–1900 BC). Lapis beads have been found at Neolithic burials in Mehrgarh, the Caucasus, and as far away as Mauritania. It was used in the funeral mask of Tutankhamun (1341–1323 BC).

By the end of the Middle Ages, Europe began importing lapis lazuli to grind it into powder and make ultramarine pigment. Ultramarine was used by some of the most important artists of the Renaissance and Baroque, including Masaccio, Perugino, Titian and Vermeer; it was often reserved for the clothing of the central figures of their paintings, especially the Virgin Mary. Ultramarine has also been found in dental tartar of medieval nuns and scribes, perhaps as a result of licking their painting brushes while producing medieval texts and manuscripts.

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Diopside in the context of Pyroxene

The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents ions of calcium (Ca), sodium (Na), iron (Fe(II)) or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron (Fe(II) or Fe(III)). Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.

The name pyroxene is derived from the Ancient Greek words for 'fire' (πυρ, pur) and 'stranger' (ξένος, xénos). Pyroxenes were so named due to their presence in volcanic lavas, where they are sometimes found as crystals embedded in volcanic glass; it was assumed they were impurities in the glass, hence the name meaning "fire stranger". However, they are simply early-forming minerals that crystallized before the lava erupted.

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Diopside in the context of Circumstellar dust

Circumstellar dust is cosmic dust around a star. It can be in the form of a spherical shell or a disc, e.g. an accretion disk. Circumstellar dust can be responsible for significant extinction and is usually the source of an infrared excess for stars that have it. For some evolved stars on the asymptotic giant branch, the dust can be composed of silicate emissions. According to a study, it is still uncertain whether the dust is a result of crystalline silicate or polycyclic aromatic hydrocarbon. However, recent observations revealed that Vega-type stars display broad silicate emission. It is suggested that the circumstellar dust components can depend on the evolutionary stage of a star and is related to the changes in its physical conditions.

The study of the composition of this dust is dubbed astrominerology. The circumstellar dust around aging stars has been observed to include, "almost pure crystalline Mg-rich silicates (forsterite and clinoenstatite), amorphous silicates, diopside, spinel, oxides (corundum and Fe0.9Mg0.1O), and also carbon-rich solids such as: (hydrogenated) amorphous carbons, aromatic hydrocarbons and silicon carbide."

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