Dehydrogenation in the context of Semiquinone


Dehydrogenation in the context of Semiquinone

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⭐ Core Definition: Dehydrogenation

In chemistry, dehydrogenation is a chemical reaction that involves the removal of hydrogen, usually from an organic molecule. It is the reverse of hydrogenation. Dehydrogenation is important, both as a useful reaction and a serious problem. At its simplest, it is a useful way of converting alkanes, which are relatively inert and thus low-valued, to olefins, which are reactive and thus more valuable. Alkenes are precursors to aldehydes (Rβˆ’CH=O), alcohols (Rβˆ’OH), polymers, and aromatics. As a problematic reaction, the fouling and inactivation of many catalysts arises via coking, which is the dehydrogenative polymerization of organic substrates.

Enzymes that catalyze dehydrogenation are called dehydrogenases.

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πŸ‘‰ Dehydrogenation in the context of Semiquinone

Semiquinones (or ubisemiquinones, if their origin is ubiquinone) are free radicals resulting from the removal of one hydrogen atom with its electron during the process of dehydrogenation of a hydroquinone, such as hydroquinone itself or catechol, to a quinone or alternatively the addition of a single hydrogen atom with its electron to a quinone. Semiquinones are highly unstable.

E.g. ubisemiquinone is the first of two stages in reducing the supplementary form of CoQ10 (ubiquinone) to its active form ubiquinol.

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Dehydrogenation in the context of Saturated and unsaturated compounds

A saturated compound is a chemical compound (or ion) that resists addition reactions, such as hydrogenation, oxidative addition, and the binding of a Lewis base. The term is used in many contexts and classes of chemical compounds. Overall, saturated compounds are less reactive than unsaturated compounds. Saturation is derived from the Latin word saturare, meaning 'to fill'. An unsaturated compound is also a chemical compound (or ion) that attracts reduction reactions, such as dehydrogenation and oxidative reduction.

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Dehydrogenation in the context of Synthetic membrane

An artificial membrane, or synthetic membrane, is a synthetically created membrane which is usually intended for separation purposes in laboratory or in industry. Synthetic membranes have been successfully used for small and large-scale industrial processes since the middle of the twentieth century. A wide variety of synthetic membranes is known. They can be produced from organic materials such as polymers and liquids, as well as inorganic materials. Most commercially utilized synthetic membranes in industry are made of polymeric structures. They can be classified based on their surface chemistry, bulk structure, morphology, and production method. The chemical and physical properties of synthetic membranes and separated particles as well as separation driving force define a particular membrane separation process. The most commonly used driving forces of a membrane process in industry are pressure and concentration gradient. The respective membrane process is therefore known as filtration. Synthetic membranes utilized in a separation process can be of different geometry and flow configurations. They can also be categorized based on their application and separation regime. The best known synthetic membrane separation processes include water purification, reverse osmosis, dehydrogenation of natural gas, removal of cell particles by microfiltration and ultrafiltration, removal of microorganisms from dairy products, and dialysis.

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