Degrees of freedom (physics and chemistry) in the context of "Gauge theory"

A plastic crystal is a crystal composed of weakly interacting molecules that possess some orientational or conformational degree of freedom. The name plastic crystal refers to the mechanical softness of such phases: they resemble waxes and are easily deformed. If the internal degree of freedom is molecular rotation, the name rotor phase or rotatory phase is also used. Typical examples are the modifications Methane I and Ethane I.

In addition to the conventional molecular plastic crystals, there are also emerging ionic plastic crystals, particularly organic ionic plastic crystals (OIPCs) and protic organic ionic plastic crystals (POIPCs). POIPCs are solid protic organic salts formed by proton transfer from a Brønsted acid to a Brønsted base and in essence are protic ionic liquids in the molten state, have found to be promising solid-state proton conductors for high temperature proton-exchange membrane fuel cells. Examples include 1,2,4-triazolium perfluorobutanesulfonate and imidazolium methanesulfonate.

In classical statistical mechanics, the equipartition theorem relates the temperature of a system to its average energies. The equipartition theorem is also known as the law of equipartition, equipartition of energy, or simply equipartition. The original idea of equipartition was that, in thermal equilibrium, energy is shared equally among all of its various forms; for example, the average kinetic energy per degree of freedom in translational motion of a molecule should equal that in rotational motion.

The equipartition theorem makes quantitative predictions. Like the virial theorem, it gives the total average kinetic and potential energies for a system at a given temperature, from which the system's heat capacity can be computed. However, equipartition also gives the average values of individual components of the energy, such as the kinetic energy of a particular particle or the potential energy of a single spring. For example, it predicts that every atom in a monatomic ideal gas has an average kinetic energy of ⁠3/2⁠k_BT in thermal equilibrium, where k_B is the Boltzmann constant and T is the (thermodynamic) temperature. More generally, equipartition can be applied to any classical system in thermal equilibrium, no matter how complicated. It can be used to derive the ideal gas law, and the Dulong–Petit law for the specific heat capacities of solids. The equipartition theorem can also be used to predict the properties of stars, even white dwarfs and neutron stars, since it holds even when relativistic effects are considered.

In physics, an effective field theory is a type of approximation, or effective theory, for an underlying physical theory, such as a quantum field theory or a statistical mechanics model. An effective field theory includes the appropriate degrees of freedom to describe physical phenomena occurring at a chosen length scale or energy scale, while ignoring substructure and degrees of freedom at shorter distances (or, equivalently, at higher energies). Intuitively, one averages over the behavior of the underlying theory at shorter length scales to derive what is hoped to be a simplified model at longer length scales. Effective field theories typically work best when there is a large separation between length scale of interest and the length scale of the underlying dynamics. Effective field theories have found use in particle physics, statistical mechanics, condensed matter physics, general relativity, and hydrodynamics. They simplify calculations, and allow treatment of dissipation and radiation effects.

Conformal symmetry is a property of spacetime that ensures angles remain unchanged even when distances are altered. If you stretch, compress, or otherwise distort spacetime, the local angular relationships between lines or curves stay the same. This idea extends the familiar Poincaré group —which accounts for rotations, translations, and boosts—into the more comprehensive conformal group.

Conformal symmetry encompasses special conformal transformations and dilations. In three spatial plus one time dimensions, conformal symmetry has 15 degrees of freedom: ten for the Poincaré group, four for special conformal transformations, and one for a dilation.

Lagrangian field theory is a formalism in classical field theory. It is the field-theoretic analogue of Lagrangian mechanics. Lagrangian mechanics is used to analyze the motion of a system of discrete particles each with a finite number of degrees of freedom. Lagrangian field theory applies to continua and fields, which have an infinite number of degrees of freedom.

One motivation for the development of the Lagrangian formalism on fields, and more generally, for classical field theory, is to provide a clear mathematical foundation for quantum field theory, which is infamously beset by formal difficulties that make it unacceptable as a mathematical theory. The Lagrangians presented here are identical to their quantum equivalents, but, in treating the fields as classical fields, instead of being quantized, one can provide definitions and obtain solutions with properties compatible with the conventional formal approach to the mathematics of partial differential equations. This enables the formulation of solutions on spaces with well-characterized properties, such as Sobolev spaces. It enables various theorems to be provided, ranging from proofs of existence to the uniform convergence of formal series to the general settings of potential theory. In addition, insight and clarity is obtained by generalizations to Riemannian manifolds and fiber bundles, allowing the geometric structure to be clearly discerned and disentangled from the corresponding equations of motion. A clearer view of the geometric structure has in turn allowed highly abstract theorems from geometry to be used to gain insight, ranging from the Chern–Gauss–Bonnet theorem and the Riemann–Roch theorem to the Atiyah–Singer index theorem and Chern–Simons theory.