In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas comes into a supercritical phase, and so cannot be liquefied by pressure alone. At the critical point, defined by a critical temperature Tc and a critical pressure pc, phase boundaries vanish. Other examples include the liquid–liquid critical points in mixtures, and the ferromagnet–paramagnet transition (Curie temperature) in the absence of an external magnetic field.
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👉 Critical point (thermodynamics) in the context of Liquid helium
Liquid helium is a physical state of helium at very low temperatures at standard atmospheric pressures. Liquid helium may show superfluidity.
At standard pressure, the chemical element helium exists in a liquid form only at the extremely low temperature of −269 °C (−452.20 °F; 4.15 K). Its boiling point and critical point depend on the isotope of helium present: the common isotope helium-4 or the rare isotope helium-3. These are the only two stable isotopes of helium. See the table below for the values of these physical quantities. The density of liquid helium-4 at its boiling point and a pressure of one atmosphere (101.3 kilopascals) is about 125 g/L (0.125 g/ml), or about one-eighth the density of liquid water.
In this Dossier
- ⭐ Core Definition: Critical point (thermodynamics)
- 👉 Critical point (thermodynamics) in the context of Liquid helium
- Critical point (thermodynamics) in the context of Giant planet
- Critical point (thermodynamics) in the context of Liquid hydrogen
- Critical point (thermodynamics) in the context of Supercritical drying
- Critical point (thermodynamics) in the context of Supercritical carbon dioxide
Critical point (thermodynamics) in the context of Giant planet
A giant planet is a diverse type of planet much larger than Earth. It is sometimes referred to as a jovian planet, with Jove being another name for the Roman god Jupiter. Giant planets are usually primarily composed of low-boiling point materials (volatiles), rather than rock or other solid matter, but mega-Earths do also exist. There are four such giant planets in the Solar System: Jupiter, Saturn, Uranus, and Neptune. Many extrasolar giant planets have been identified.
Giant planets are sometimes known as gas giants, but many astronomers now apply the term only to Jupiter and Saturn, classifying Uranus and Neptune, which have different compositions, as ice giants. Both names are potentially misleading; the Solar System's giant planets all consist primarily of fluids above their critical points, where distinct gas and liquid phases do not exist. Jupiter and Saturn are principally made of hydrogen and helium, whilst Uranus and Neptune consist of water, ammonia, and methane.
Critical point (thermodynamics) in the context of Liquid hydrogen
Liquid hydrogen (H2(l)) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form.
To exist as a liquid, H2 must be cooled below its critical point of 33 K. However, for it to be in a fully liquid state at atmospheric pressure, H2 needs to be cooled to 20.28 K (−252.87 °C; −423.17 °F). A common method of obtaining liquid hydrogen involves a compressor resembling a jet engine in both appearance and principle. Liquid hydrogen is typically used as a concentrated form of hydrogen storage. Storing it as liquid takes less space than storing it as a gas at normal temperature and pressure. However, the liquid density is very low compared to other common fuels. Once liquefied, it can be maintained as a liquid for some time in thermally insulated containers.
Critical point (thermodynamics) in the context of Supercritical drying
Supercritical drying, also known as critical point drying, is a process to remove liquid in a precise and controlled way. It is useful in the production of microelectromechanical systems (MEMS), the drying of spices, the production of aerogel, the decaffeination of coffee and in the preparation of biological specimens.
Critical point (thermodynamics) in the context of Supercritical carbon dioxide
Supercritical carbon dioxide (sCO
2) is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure.
Carbon dioxide usually behaves as a gas in air at standard temperature and pressure (STP), or as a solid called dry ice when cooled and/or pressurised sufficiently. If the temperature and pressure are both increased from STP to be at or above the critical point for carbon dioxide, it can adopt properties midway between a gas and a liquid. More specifically, it behaves as a supercritical fluid above its critical temperature (304.128 K, 30.9780 °C, 87.7604 °F) and critical pressure (7.3773 MPa, 72.808 atm, 1,070.0 psi, 73.773 bar), expanding to fill its container like a gas but with a density like that of a liquid.