In chemistry, congeners are chemical substances "related to each other by origin, structure, or function".
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👉 Congener (chemistry) in the context of Cadmium
Cadmium is a chemical element; it has symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of its compounds, and like mercury, it has a lower melting point than the transition metals in groups 3 through 11. Cadmium and its congeners in group 12 are often not considered transition metals, in that they do not have partly filled d or f electron shells in the elemental or common oxidation states. The average concentration of cadmium in Earth's crust is between 0.1 and 0.5 parts per million (ppm). It was discovered in 1817 simultaneously by Stromeyer and Hermann, both in Germany, as an impurity in zinc carbonate.
Cadmium occurs as a minor component in most zinc ores and is a byproduct of zinc production. It was used for a long time in the 1900s as a corrosion-resistant plating on steel, and cadmium compounds are used as red, orange, and yellow pigments, to color glass, and to stabilize plastic. Cadmium's use is generally decreasing because it is toxic, and nickel–cadmium batteries have been replaced with nickel–metal hydride and lithium-ion batteries. Because it is a neutron poison, cadmium is also used as a component of control rods in nuclear fission reactors. One of its few new uses is in cadmium telluride solar panels.
In this Dossier
Congener (chemistry) in the context of Palladium
Palladium is a chemical element; it has the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1802 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas (formally 2 Pallas), which was thought to be a planet at the time, which was itself named after the epithet of the Greek goddess Athena, acquired by her when she slew Pallas. Palladium, platinum, rhodium, ruthenium, iridium and osmium form together a group of elements referred to as the platinum group metals. They have similar chemical properties, but palladium has the lowest melting point and is the least dense of them.
More than half the supply of palladium and its congener platinum is used in catalytic converters, which convert as much as 90% of the harmful gases in automobile exhaust (hydrocarbons, carbon monoxide, and nitrogen dioxide) into nontoxic substances (nitrogen, carbon dioxide and water vapor). Palladium is also used in electronics, dentistry, medicine, hydrogen purification, chemical applications, electrochemical sensors, electrosynthesis, groundwater treatment, and jewellery. Palladium is a key component of fuel cells, in which hydrogen and oxygen react to produce electricity, heat, and water.
Congener (chemistry) in the context of Lanthanide
A lanthanide (/ˈlænθənaɪd/) is any of the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. The IUPAC recommended standard name of this series is lanthanoid (/ˈlænθənɔɪd/).In the periodic table, they fill the 4f orbitals. Lutetium (element 71) is also sometimes considered a lanthanide, despite being a d-block element and a transition metal.
The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide. All but one of the lanthanides are f-block elements, corresponding to the filling of the 4f electron shell. Lutetium is a d-block element (thus also a transition metal), and on this basis its inclusion has been questioned; however, like its congeners scandium and yttrium in group 3, it behaves similarly to the other 14. The term rare-earth element or rare-earth metal is often used to include the stable group 3 elements Sc, Y, and Lu in addition to the 4f elements. All lanthanide elements form trivalent cations, Ln, whose chemistry is largely determined by the ionic radius, which decreases steadily from lanthanum (La) to lutetium (Lu).