Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2Si2O5(OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces.
Clay minerals form in the presence of water and have been important to life, and many theories of abiogenesis involve them. They are important constituents of soils, and have been useful to humans since ancient times in agriculture and manufacturing.
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, Al2Si2O5(OH)4). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide.
Clays develop plasticity when wet but can be hardened through firing. Clay is the longest-known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been dated to around 14,000 BCE, and clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often baked into brick, as an essential part of its load-bearing structure. In agriculture, clay content is a major factor in determining land arability. Clay soils are generally less suitable for crops due to poor natural drainage; however, clay soils are more fertile, due to higher cation-exchange capacity.
Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.
Although its permeability and porosity is relatively low, siltstone is sometimes a tight gas reservoir rock, an unconventional reservoir for methane gas that requires hydraulic fracturing for economic gas production.
Kaolinite (/ˈkeɪ.ələˌnaɪt, -lɪ-/ KAY-ə-lə-nyte, -lih-; also called kaolin) is a clay mineral, with the chemical composition Al2Si2O5(OH)4. It is a layered silicate mineral, with one "tetrahedral" sheet of silicate tetrahedra (SiO4) linked to one "octahedral" sheet of aluminate octahedrons (AlO2(OH)4) through oxygen atoms on one side, and another such sheet through hydrogen bonds on the other side.
Kaolinite is a soft, earthy, usually white, mineral (dioctahedral phyllosilicate clay), produced by the chemical weathering of aluminium silicate minerals like feldspar. It has a low shrink–swell capacity and a low cation-exchange capacity (1–15 meq/100 g).
Cementation is a process where minerals bond grains of sediment together by growing around them. This means precipitation of ions carried in groundwater to form new crystalline material between sedimentary grains. The new pore-filling minerals form "bridges" between original sediment grains, thereby binding them together. In this way, sand becomes sandstone, and gravel becomes conglomerate or breccia.
Cementation occurs as part of the diagenesis or lithification of sediments and occurs primarily below the water table regardless of sedimentary grain sizes present. Large volumes of pore water must pass through sediment pores for new mineral cements to crystallize and so millions of years are generally required to complete the cementation process. Common mineral cements include calcite, quartz, and silica phases like cristobalite, iron oxides, and clay minerals; other mineral cements also occur.
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g., kaolin, Al2Si2O5(OH)4) and tiny fragments (silt-sized particles) of other minerals, especially quartz and calcite. Shale is characterized by its tendency to split into thin layers (laminae) less than one centimeter in thickness. This property is called fissility. Shale is the most common sedimentary rock.
The term shale is sometimes applied more broadly, as essentially a synonym for mudrock, rather than in the narrower sense of clay-rich fissile mudrock.
Diatomaceous earth (/ˌdaɪ.ətəˈmeɪʃəs/ DY-ə-tə-MAY-shəs), also known as diatomite (/daɪˈætəmaɪt/ dy-AT-ə-myte), celite, or kieselguhr, is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3 mm to less than 1 μm, but typically 10 to 200 μm. Depending on the granularity, this powder can have an abrasive feel, similar to pumice powder, and has a low density as a result of its high porosity. The typical chemical composition of oven-dried diatomaceous earth is 80–90% silica, with 2–4% alumina (attributed mostly to clay minerals), and 0.5–2% iron oxide.
Diatomaceous earth consists of the fossilized remains of diatoms, a type of hard-shelled microalgae, that have accumulated over millions of years. It is used as a filtration aid, mild abrasive in products including metal polishes and toothpaste, mechanical insecticide, absorbent for liquids, matting agent for coatings, reinforcing filler in plastics and rubber, anti-block in plastic films, porous support for chemical catalysts, cat litter, activator in coagulation studies, a stabilizing component of dynamite, a thermal insulator, and a soil for potted plants and trees as in the art of bonsai. It is also used in gas chromatography packed columns made with glass or metal as stationary phase.
Tonstein (from the German "Ton", meaning clay, plus "Stein", meaning stone) is a hard, compact sedimentary rock that is composed mainly of kaolinite or, less commonly, other clay minerals such as montmorillonite and illite. The clays often are cemented by iron oxide minerals, carbonaceous matter, or chlorite. Tonsteins form from volcanic ash deposited in swamps.Tonsteins occur as distinctive, thin, and laterally extensive layers in coal seams throughout the world. They are often used as key beds to correlate the strata in which they are found. The regional persistence of tonsteins and relict phenocrysts indicate that they formed as the result of the diagenetic alteration of volcanic ash falls in an acidic (low pH) and low-salinity environment, consistent with a freshwater swamp. In contrast, the alteration of a volcanic ashfall deposit in a marine environment typically produces a bentonite layer.
The induration of tonsteins is in contrast to kaolin claystones that can be mined for kaolin clay, such as the ball clays found at Bovey Tracey which formed by the erosion of a nearby kaolinised granite. These deposits are generally softer, white, and plastic.