Binding energy in the context of "Chemisorption"

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⭐ Core Definition: Binding energy

In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly used in condensed matter physics, atomic physics, and chemistry, whereas in nuclear physics the term separation energy is used. A bound system is typically at a lower energy level than its unbound constituents. According to relativity theory, a ΔE decrease in the total energy of a system is accompanied by a decrease Δm in the total mass, where Δmc = ΔE.

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👉 Binding energy in the context of Chemisorption

Chemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like corrosion, and subtler effects associated with heterogeneous catalysis, where the catalyst and reactants are in different phases. The strong interaction between the adsorbate and the substrate surface creates new types of electronic bonds.

In contrast with chemisorption is physisorption, which leaves the chemical species of the adsorbate and surface intact. It is conventionally accepted that the energetic threshold separating the binding energy of "physisorption" from that of "chemisorption" is about 0.5 eV per adsorbed species.

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Binding energy in the context of Atomic number

The atomic number or nuclear charge number (symbol Z) of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (np) or the number of protons found in the nucleus of every atom of that element. The atomic number can be used to uniquely identify ordinary chemical elements. In an ordinary uncharged atom, the atomic number is also equal to the number of electrons.

For an ordinary atom which contains protons, neutrons and electrons, the sum of the atomic number Z and the neutron number N gives the atom's atomic mass number A. Since protons and neutrons have approximately the same mass (and the mass of the electrons is negligible for many purposes) and the mass defect of the nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in daltons (making a quantity called the "relative isotopic mass"), is within 1% of the whole number A.

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Binding energy in the context of Magic number (physics)

In nuclear physics, a magic number is a number of nucleons (either protons or neutrons, separately) such that they are arranged into complete shells within the atomic nucleus. As a result, atomic nuclei with a "magic" number of protons or neutrons are much more stable than other nuclei. The seven most widely recognized magic numbers as of 2019 are 2, 8, 20, 28, 50, 82, and 126.

For protons, this corresponds to the elements helium, oxygen, calcium, nickel, tin, lead, and the hypothetical unbihexium, although 126 is so far only known to be a magic number for neutrons. Atomic nuclei consisting of such a magic number of nucleons have a higher average binding energy per nucleon than one would expect based upon predictions such as the semi-empirical mass formula and are hence more stable against nuclear decay.

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Binding energy in the context of Hadron

In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong nuclear force. Pronounced /ˈhædrɒn/ , the name is derived from Ancient Greek ἁδρός (hadrós) 'stout, thick'. They are analogous to molecules, which are held together by the electric force. Most of the mass of ordinary matter comes from two hadrons: the proton and the neutron, while most of the mass of the protons and neutrons is in turn due to the binding energy of their constituent quarks, due to the strong force.

Hadrons are categorized into two broad families: baryons, made of an odd number of quarks (usually three), and mesons, made of an even number of quarks (usually two: one quark and one antiquark). Protons and neutrons (which make the majority of the mass of an atom) are examples of baryons; pions are an example of a meson. A tetraquark state (an exotic meson), named the Z(4430), was discovered in 2007 by the Belle Collaboration and confirmed as a resonance in 2014 by the LHCb collaboration. Two pentaquark states (exotic baryons), named P
c
(4380)
and P
c
(4450)
, were discovered in 2015 by the LHCb collaboration. There are several other "Exotic" hadron candidates and other colour-singlet quark combinations that may also exist.

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Binding energy in the context of Desorption

Desorption is the physical process where adsorbed atoms or molecules are released from a surface into the surrounding vacuum or fluid. This occurs when a molecule gains enough energy to overcome the activation barrier and the binding energy that keep it attached to the surface.

Desorption is the reverse of the process of adsorption, which differs from absorption in that adsorption refers to substances bound to the surface, rather than being absorbed into the bulk.

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Binding energy in the context of Nuclear chain reaction

In nuclear physics, a nuclear chain reaction occurs when one single nuclear reaction causes an average of one or more subsequent nuclear reactions, thus leading to the possibility of a self-propagating series or "positive feedback loop" of these reactions. The specific nuclear reaction may be the fission of heavy isotopes (e.g., uranium-235, U). A nuclear chain reaction releases several million times more energy per reaction than any chemical reaction.

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Binding energy in the context of Semi-empirical mass formula

In nuclear physics, the semi-empirical mass formula (SEMF; sometimes also called the Weizsäcker formula, Bethe–Weizsäcker formula, or Bethe–Weizsäcker mass formula to distinguish it from the Bethe–Weizsäcker process) is used to approximate the mass of an atomic nucleus from its number of protons and neutrons. As the name suggests, it is based partly on theory and partly on empirical measurements. The formula represents the liquid-drop model proposed by George Gamow, which can account for most of the terms in the formula and gives rough estimates for the values of the coefficients. It was first formulated in 1935 by German physicist Carl Friedrich von Weizsäcker, and although refinements have been made to the coefficients over the years, the structure of the formula remains the same today.

The formula gives a good approximation for atomic masses and thereby other effects. However, it fails to explain the existence of lines of greater binding energy at certain numbers of protons and neutrons. These numbers, known as magic numbers, are the foundation of the nuclear shell model.

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Binding energy in the context of Nuclear shell model

In nuclear physics, atomic physics, and nuclear chemistry, the nuclear shell model utilizes the Pauli exclusion principle to model the structure of atomic nuclei in terms of energy levels. The first shell model was proposed by Dmitri Ivanenko (together with E. Gapon) in 1932. The model was developed in 1949 following independent work by several physicists, most notably Maria Goeppert Mayer and J. Hans D. Jensen, who received the 1963 Nobel Prize in Physics for their contributions to this model, and Eugene Wigner, who received the Nobel Prize alongside them for his earlier foundational work on atomic nuclei.

The nuclear shell model is partly analogous to the atomic shell model, which describes the arrangement of electrons in an atom, in that a filled shell results in better stability. When adding nucleons (protons and neutrons) to a nucleus, there are certain points where the binding energy of the next nucleon is significantly less than the last one. This observation that there are specific magic quantum numbers of nucleons (2, 8, 20, 28, 50, 82, and 126) that are more tightly bound than the following higher number is the origin of the shell model.

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