Miller indices form a notation system in crystallography for lattice planes in crystal (Bravais) lattices.
In particular, a family of lattice planes of a given (direct) Bravais lattice is determined by three integers h, k, and ℓ, the Miller indices. They are written (hkℓ), and denote the family of (parallel) lattice planes (of the given Bravais lattice) orthogonal to
, where
are the basis or primitive translation vectors of the reciprocal lattice for the given Bravais lattice. (Note that the plane is not always orthogonal to the linear combination of direct or original lattice vectors
because the direct lattice vectors need not be mutually orthogonal.) This is based on the fact that a reciprocal lattice vector
(the vector indicating a reciprocal lattice point from the reciprocal lattice origin) is the wavevector of a plane wave in the Fourier series of a spatial function (e.g., electronic density function) which periodicity follows the original Bravais lattice, so wavefronts of the plane wave are coincident with parallel lattice planes of the original lattice. Since a measured scattering vector in X-ray crystallography,
with
as the outgoing (scattered from a crystal lattice) X-ray wavevector and
as the incoming (toward the crystal lattice) X-ray wavevector, is equal to a reciprocal lattice vector
as stated by the Laue equations, the measured scattered X-ray peak at each measured scattering vector
is marked by Miller indices.