Atomic absorption in the context of Elemental analysis


Atomic absorption in the context of Elemental analysis

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⭐ Core Definition: Atomic absorption

Atomic absorption spectroscopy (AAS) is an elemental analysis method for determining the concentration of metals in a given sample.

The principle of AAS relies on the vaporization of metals within a sample when introduced to a flame. Every ground state metal absorbs light radiation (and excites) at a different wavelength. This uniqueness allows each metallic element to have its own absorption spectrum that corresponds to its identity. The total absorbed radiation at a specific wavelength by an element in the sample is proportional to the density of atoms of the element. The quantification of this relationship is used to determine the concentration of specific metals in the sample.

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Atomic absorption in the context of Petrography

Petrography is a branch of petrology that focuses on detailed descriptions of rocks. Someone who studies petrography is called a petrographer. The mineral content and the textural relationships within the rock are described in detail. The classification of rocks is based on the information acquired during the petrographic analysis. Petrographic descriptions start with the field notes at the outcrop and include macroscopic description of hand-sized specimens. The most important petrographer's tool is the petrographic microscope. The detailed analysis of minerals by optical mineralogy in thin section and the micro-texture and structure are critical to understanding the origin of the rock.

Electron microprobe or atom probe tomography analysis of individual grains as well as whole rock chemical analysis by atomic absorption, X-ray fluorescence, and laser-induced breakdown spectroscopy are used in a modern petrographic lab. Individual mineral grains from a rock sample may also be analyzed by X-ray diffraction when optical means are insufficient. Analysis of microscopic fluid inclusions within mineral grains with a heating stage on a petrographic microscope provides clues to the temperature and pressure conditions existent during the mineral formation.

View the full Wikipedia page for Petrography
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