Arsenic in the context of El Tatio

The Bronze Age is an archaeological and anthropological term defining a phase in the development of material culture among ancient societies in Asia, the Near East and Europe. An ancient civilisation is deemed to be part of the Bronze Age if it either produced bronze by smelting its own copper and alloying it with tin, arsenic, or other metals, or traded other items for bronze from producing areas elsewhere. The Bronze Age is the middle principal period of the three-age system, following the Stone Age and preceding the Iron Age. Conceived as a global era, the Bronze Age follows the Neolithic ("New Stone") period, with a transition period between the two known as the Chalcolithic ("copper-Stone") Age. These technical developments took place at different times in different places, and therefore each region's history is framed by a different chronological system.

Bronze Age cultures were the first to develop writing. According to archaeological evidence, cultures in Mesopotamia, which used cuneiform script, and Egypt, which used hieroglyphs, developed the earliest practical writing systems. In the archaeology of the Americas, a five-period system is conventionally used instead, which does not include a Bronze Age, though some cultures there did smelt copper and bronze. No evidence of metalworking has been found on the Australian continent prior to the establishment of European settlements in 1788.

Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloids (such as arsenic or silicon). These additions produce a range of alloys some of which are harder than copper alone or have other useful properties, such as strength, ductility, or machinability.

The archaeological period during which bronze was the hardest metal in widespread use is known as the Bronze Age. The beginning of the Bronze Age in western Eurasia is conventionally dated to the mid-4th millennium BCE (~3500 BCE), and to the early 2nd millennium BCE in China; elsewhere it gradually spread across regions. The Bronze Age was followed by the Iron Age, which started about 1300 BCE and reached most of Eurasia by about 500 BCE, although bronze continued to be much more widely used than it is in modern times.

Orpiment, also known as yellow arsenic blende, is a deep-colored, orange-yellow arsenic sulfide mineral with formula As
₂S
₃. It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and may be formed through sublimation.

Orpiment takes its name from the Latin auripigmentum (aurum, "gold" + pigmentum, "pigment"), due to its deep-yellow color. Orpiment once was widely used in artworks, medicine, and other applications. Because of its toxicity and instability, its usage has declined.

Cobalt is a chemical element; it has symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, somewhat brittle, gray metal.

Cobalt-based blue pigments (cobalt blue) have been used since antiquity for jewelry and paints, and to impart a distinctive blue tint to glass. The color was long thought to be due to the metal bismuth. Miners had long used the name kobold ore (German for goblin ore) for some of the blue pigment-producing minerals. They were so named because they were poor in known metals and gave off poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), which was ultimately named for the kobold.

In chemistry, homonuclear molecules, or elemental molecules, or homonuclear species, are molecules composed of only one element. Homonuclear molecules may consist of various numbers of atoms. The size of the molecule an element can form depends on the element's properties, and some elements form molecules of more than one size. The most familiar homonuclear molecules are diatomic molecules, which consist of two atoms, although not all diatomic molecules are homonuclear. Homonuclear diatomic molecules include hydrogen (H₂), oxygen (O₂), nitrogen (N₂) and all of the halogens. Ozone (O₃) is a common triatomic homonuclear molecule. Homonuclear tetratomic molecules include arsenic (As₄) and phosphorus (P₄).

Allotropes are different chemical forms of the same element (not containing any other element). In that sense, allotropes are all homonuclear. Many elements have multiple allotropic forms. In addition to the most common form of gaseous oxygen, O₂, and ozone, there are other allotropes of oxygen. Sulfur forms several allotropes containing different numbers of sulfur atoms, including diatomic, triatomic, hexatomic and octatomic (S₂, S₃, S₆, S₈) forms, though the first three are rare. The element carbon is known to have a number of homonuclear molecules, including diamond and graphite.

Bioleaching is the extraction or liberation of metals from their ores through the use of living organisms. Bioleaching is one of several applications within biohydrometallurgy and several methods are used to treat ores or concentrates containing copper, zinc, lead, arsenic, antimony, nickel, molybdenum, gold, silver, and cobalt.

Bioleaching falls into two broad categories. The first, is the use of microorganisms to oxidize refractory minerals to release valuable metals such and gold and silver. Most commonly the minerals that are the target of oxidization are pyrite and arsenopyrite.

Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known.

Bismuth was formerly understood to be the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was found to be very slightly radioactive. The metal's only primordial isotope, bismuth-209, undergoes alpha decay with a half-life roughly a billion times longer than the estimated age of the universe.

Arsenical bronze is an alloy in which arsenic, as opposed to or in addition to tin or other constituent metals, is combined with copper to make bronze. The use of arsenic with copper, either as the secondary constituent or with another component such as tin, results in a stronger final product and better casting behavior.

Copper ore is often naturally contaminated with arsenic; hence, the term "arsenical bronze" when used in archaeology is typically only applied to alloys with an arsenic content higher than 1% by weight, in order to distinguish it from potentially accidental additions of arsenic.

The word metalloid comes from the Latin metallum ("metal") and the Greek oeidḗs ("resembling in form or appearance"). However, there is no standard definition of a metalloid and no complete agreement on which elements are metalloids. Despite the lack of specificity, the term remains in use in the literature.

The six commonly recognised metalloids are boron, silicon, germanium, arsenic, antimony and tellurium. Five elements are less frequently so classified: carbon, aluminium, selenium, polonium and astatine. On a standard periodic table, all eleven elements are in a diagonal region of the p-block extending from boron at the upper left to astatine at lower right. Some periodic tables include a dividing line between metals and nonmetals, and the metalloids may be found close to this line.

Copper extraction is the multi-stage process of obtaining copper from its ores. The conversion of copper ores consists of a series of physical, chemical, and electrochemical processes. Methods have evolved and vary with country depending on the ore source, local environmental regulations, and other factors. The copper smelters with the highest production capacity (metric tons of copper yearly) lie in China, Chile, India, Germany, Japan, Peru and Russia. China alone has over half of the world's production capacity and is also the world's largest consumer of refined copper.

Precious metals and sulfuric acid are often valuable by-products of copper refining. Arsenic is the main type of impurity found in copper concentrates to enter smelting facilities. There has been an increase in arsenic in copper concentrates over the years since shallow, low-arsenic copper deposits have been progressively depleted.

A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group (gold, copper, lead, aluminium, mercury, silver) and the platinum group (platinum, iridium, osmium, palladium, rhodium, ruthenium). Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.

Only gold, silver, copper and the platinum group occur native in large amounts. Over geological time scales, very few metals can resist natural weathering processes like oxidation, so mainly the less reactive metals such as gold and platinum are found as native metals. The others usually occur as isolated pockets where a natural chemical process reduces a common compound or ore of the metal, leaving the pure metal behind as small flakes or inclusions.

A pnictogen (/ˈ(p)nɪktədʒən/; from Ancient Greek πνίγω (pnígō) 'to choke' and -gen 'generator') is any of the chemical elements in group 15 of the periodic table. Group 15 is also known as the nitrogen group or nitrogen family. Group 15 consists of the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and moscovium (Mc).

The IUPAC has called it Group 15 since 1988. Before that, in America it was called Group VA, owing to a text by H. C. Deming and the Sargent-Welch Scientific Company, while in Europe it was called Group VB, which the IUPAC had recommended in 1970. (Pronounced "group five A" and "group five B"; "V" is the Roman numeral 5.) In semiconductor physics, it is still usually called Group V. The "five" ("V") in the historical names comes from the "pentavalency" of nitrogen, reflected by the stoichiometry of compounds such as N₂O₅. They have also been called the pentels.

Arsenic in the solid state can be found as gray, black, or yellow allotropes. These various forms feature diverse structural motifs, with yellow arsenic enabling the widest range of reactivity. In particular, reaction of yellow arsenic with main group and transition metal elements results in compounds with wide-ranging structural motifs, with butterfly, sandwich and realgar-type moieties featuring most prominently.

Mineral springs are naturally occurring springs that produce hard water, water that contains dissolved minerals. Salts, sulfur compounds, and gases are among the substances that can be dissolved in the spring water during its passage underground. In this they are unlike sweet springs, which produce soft water with no noticeable dissolved gasses. The dissolved minerals may alter the water's taste. Mineral water obtained from mineral springs, and the precipitated salts such as Epsom salt have long been important commercial products.

Some mineral springs may contain significant amounts of harmful dissolved minerals, such as arsenic, and should not be drunk. Sulfur springs smell of rotten eggs due to hydrogen sulfide (H₂S), which is hazardous and sometimes deadly. It is a gas, and it usually enters the body when it is breathed in. The quantities ingested in drinking water are much lower and are not considered likely to cause harm, but few studies on long-term, low-level exposure have been done, as of 2003.