Zeeman effect in the context of Rubidium

In atomic physics, a magnetic quantum number is a quantum number used to distinguish quantum states of an electron or other particle according to its angular momentum along a given axis in space. The orbital magnetic quantum number (m_l or m) distinguishes the orbitals available within a given subshell of an atom. It specifies the component of the orbital angular momentum that lies along a given axis, conventionally called the z-axis, so it describes the orientation of the orbital in space. The spin magnetic quantum number m_s specifies the z-axis component of the spin angular momentum for a particle having spin quantum number s. For an electron, s is 1⁄2, and m_s is either +1⁄2 or −1⁄2, often called "spin-up" and "spin-down", or α and β. The term magnetic in the name refers to the magnetic dipole moment associated with each type of angular momentum, so states having different magnetic quantum numbers shift in energy in a magnetic field according to the Zeeman effect.

The four quantum numbers conventionally used to describe the quantum state of an electron in an atom are the principal quantum number n, the azimuthal (orbital) quantum number ${\displaystyle \ell }$, and the magnetic quantum numbers m_l and m_s. Electrons in a given subshell of an atom (such as s, p, d, or f) are defined by values of ${\displaystyle \ell }$ (0, 1, 2, or 3). The orbital magnetic quantum number takes integer values in the range from ${\displaystyle -\ell }$ to ${\displaystyle +\ell }$, including zero. Thus the s, p, d, and f subshells contain 1, 3, 5, and 7 orbitals each. Each of these orbitals can accommodate up to two electrons (with opposite spins), forming the basis of the periodic table.

Hendrik Antoon Lorentz (/ˈlɔːrənts, ˈloʊr-, ˈloʊrɛnts/ LAWR-uhnts, LOHR-, LOH-rents; Dutch: [ˈɦɛndrɪk ˈɑntoːn ˈloːrɛnts]; 18 July 1853 – 4 February 1928) was a Dutch theoretical physicist who shared the 1902 Nobel Prize in Physics with Pieter Zeeman for their discovery and theoretical explanation of the Zeeman effect. He derived the Lorentz transformation of the special theory of relativity, as well as the Lorentz force, which describes the force acting on a charged particle in an electromagnetic field. He was also responsible for the Lorentz oscillator model, a classical model used to describe the anomalous dispersion observed in dielectric materials when the driving frequency of the electric field was near the resonant frequency of the material, resulting in abnormal refractive indices.

Lorentz received many other honors and distinctions, including a term as Chairman of the International Committee on Intellectual Cooperation, the forerunner of UNESCO, from 1925 until his death in 1928.

In atomic, molecular, and optical physics, a magneto-optical trap (MOT) is an apparatus which uses laser cooling and a spatially varying magnetic field to create a trap which can produce samples of cold neutral atoms. Temperatures achieved in a MOT can be as low as several microkelvins, depending on the atomic species, which is two or three times below the photon-recoil limit. However, for atoms with an unresolved hyperfine structure, such as Li, the temperature achieved in a MOT will be higher than the Doppler cooling limit.

A MOT is formed from the intersection of the zero of a weak quadrupolar magnetic field and six circularly polarized red-detuned optical molasses beams. Counterpropagating beams have opposite handed polarization. As atoms travel away from the zero field at the center of the trap, the spatially varying Zeeman shift brings an atomic transition into resonance with the laser beams. The polarization of the beam propagating in the opposite direction of this atomic motion is chosen to drive this transition. The absorption of these photons gives rise to a scattering force that pushes the atoms back towards the center of the trap.

Pieter Zeeman (/ˈzeɪmɑːn/ ZAY-mahn; Dutch: [ˈzeːmɑn] ; 25 May 1865 – 9 October 1943) was a Dutch experimental physicist who shared the 1902 Nobel Prize in Physics with Hendrik Lorentz for their discovery and theoretical explanation of the Zeeman effect.