Wave function in the context of "Fourier analysis"

Quantum chemistry, also called molecular quantum mechanics, is a branch of physical chemistry focused on the application of quantum mechanics to chemical systems, particularly towards the quantum-mechanical calculation of electronic contributions to physical and chemical properties of molecules, materials, and solutions at the atomic level. These calculations include systematically applied approximations intended to make calculations computationally feasible while still capturing as much information about important contributions to the computed wave functions as well as to observable properties such as structures, spectra, and thermodynamic properties. Quantum chemistry is also concerned with the computation of quantum effects on molecular dynamics and chemical kinetics.

Chemists rely heavily on spectroscopy through which information regarding the quantization of energy on a molecular scale can be obtained. Common methods are infra-red (IR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, and scanning probe microscopy. Quantum chemistry may be applied to the prediction and verification of spectroscopic data as well as other experimental data.

Quantum mechanics is the fundamental physical theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. It is the foundation of all quantum physics, which includes quantum chemistry, quantum biology, quantum field theory, quantum technology, and quantum information science.

Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales.

The spin–statistics theorem proves that the observed relationship between the intrinsic spin of a particle (angular momentum not due to the orbital motion) and the quantum particle statistics of collections of such particles is a consequence of the mathematics of quantum mechanics.

According to the theorem, the many-body wave function for elementary particles with integer spin (bosons) is symmetric under the exchange of any two particles, whereas for particles with half-integer spin (fermions), the wave function is antisymmetric under such an exchange. A consequence of the theorem is that non-interacting particles with integer spin obey Bose–Einstein statistics, while those with half-integer spin obey Fermi–Dirac statistics.

Erwin Rudolf Josef Alexander Schrödinger (/ˈʃroʊdɪŋər/ SHROH-ding-er, German: [ˈʃʁøːdɪŋɐ] ; 12 August 1887 – 4 January 1961), sometimes written as Schroedinger or Schrodinger, was an Austrian–Irish theoretical physicist who developed fundamental results in quantum theory. In particular, he is recognized for devising the Schrödinger equation, an equation that provides a way to calculate the wave function of a system and how it changes dynamically in time. He coined the term "quantum entanglement" in 1935.

In addition, Schrödinger wrote many works on various aspects of physics: statistical mechanics and thermodynamics, physics of dielectrics, color theory, electrodynamics, general relativity, and cosmology, and he made several attempts to construct a unified field theory. In his book, What Is Life?, Schrödinger addressed the problems of genetics, looking at the phenomenon of life from the point of view of physics. He also paid great attention to the philosophical aspects of science, ancient, and oriental philosophical concepts, ethics, and religion. He also wrote on philosophy and theoretical biology. In popular culture, he is best known for his "Schrödinger's cat" thought experiment.

Fourier optics is the study of classical optics using Fourier transforms (FTs), in which the waveform being considered is regarded as made up of a combination, or superposition, of plane waves. It has some parallels to the Huygens–Fresnel principle, in which the wavefront is regarded as being made up of a combination of spherical wavefronts (also called phasefronts) whose sum is the wavefront being studied. A key difference is that Fourier optics considers the plane waves to be natural modes of the propagation medium, as opposed to Huygens–Fresnel, where the spherical waves originate in the physical medium.

A curved phasefront may be synthesized from an infinite number of these "natural modes" i.e., from plane wave phasefronts oriented in different directions in space. When an expanding spherical wave is far from its sources, it is locally tangent to a planar phase front (a single plane wave out of the infinite spectrum), which is transverse to the radial direction of propagation. In this case, a Fraunhofer diffraction pattern is created, which emanates from a single spherical wave phase center. In the near field, no single well-defined spherical wave phase center exists, so the wavefront isn't locally tangent to a spherical ball. In this case, a Fresnel diffraction pattern would be created, which emanates from an extended source, consisting of a distribution of (physically identifiable) spherical wave sources in space. In the near field, a full spectrum of plane waves is necessary to represent the Fresnel near-field wave, even locally. A "wide" wave moving forward (like an expanding ocean wave coming toward the shore) can be regarded as an infinite number of "plane wave modes", all of which could (when they collide with something such as a rock in the way) scatter independently of one other. These mathematical simplifications and calculations are the realm of Fourier analysis and synthesis – together, they can describe what happens when light passes through various slits, lenses or mirrors that are curved one way or the other, or is fully or partially reflected.

In solid-state physics, the electronic band structure (or simply band structure) of a solid describes the range of energy levels that electrons may have within it, as well as the ranges of energy that they may not have (called band gaps or forbidden bands).

Band theory derives these bands and band gaps by examining the allowed quantum mechanical wave functions for an electron in a large, periodic lattice of atoms or molecules. Band theory has been successfully used to explain many physical properties of solids, such as electrical resistivity and optical absorption, and forms the foundation of the understanding of all solid-state devices (transistors, solar cells, etc.).