Vesuvius Observatory in the context of National Institute of Geophysics and Volcanology

Volcanic lightning is an electrical discharge caused by a volcanic eruption rather than from an ordinary thunderstorm. Volcanic lightning arises from colliding, fragmenting particles of volcanic ash (and sometimes ice), which generate static electricity within the volcanic plume, leading to the name dirty thunderstorm. Moist convection currents and ice formation also drive the eruption plume dynamics and can trigger volcanic lightning. Unlike ordinary thunderstorms, volcanic lightning can also occur when there are no ice crystals in the ash cloud.

The earliest recorded observations of volcanic lightning are from Pliny the Younger, describing the eruption of Mount Vesuvius in 79 AD, "There was a most intense darkness rendered more appalling by the fitful gleam of torches at intervals obscured by the transient blaze of lightning." The first studies of volcanic lightning were also conducted at Mount Vesuvius by Luigi Palmieri who observed the eruptions of 1858, 1861, 1868, and 1872 from the Vesuvius Observatory. These eruptions often included lightning activity.

The Phlegraean Fields (Italian: Campi Flegrei, Italian: [ˈkampi fleˈɡrɛi]; Neapolitan: Campe Flegree) is a large volcanic caldera west of Naples, Italy. The Neapolitan Yellow Tuff eruption (about 12ka BP) produced just 50 cubic kilometers. It is, however, one of relatively few volcanoes large enough to form a caldera. It is part of the Campanian volcanic arc, which includes Mount Vesuvius, about 9 km (6 miles) east of Naples. The Phlegraean Fields is monitored by the Vesuvius Observatory. Part of the city of Naples is built over it.The Phlegraean Fields' largest known eruptions have an estimated volcanic explosivity index (VEI) of 7. It is often called a supervolcano in popular media, although the accepted definition for that term is a volcano that has had an eruption with a VEI of 8, the highest level.

The area of the caldera consists of 24 craters and volcanic edifices. Most of them lie under the Gulf of Naples. There are effusive gaseous manifestations in the Solfatara crater, which was believed in ancient Rome to be the home of Vulcan, the god of fire. The area features bradyseismic phenomena, which are most evident at the Macellum of Pozzuoli, misidentified by 18th-century excavators as a temple of Serapis: bands of boreholes left by marine molluscs on marble columns show that the level of the site in relation to sea level has varied. Hydrothermal activity can still be observed at Lucrino, Agnano and the town of Pozzuoli.