Vanadium in the context of Oxidation

Corundum is a crystalline form of aluminium oxide (Al₂O₃) typically containing traces of iron, titanium, vanadium, and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange.

The name "corundum" is derived from the Tamil-Dravidian word kurundam (ruby-sapphire) (appearing in Sanskrit as kuruvinda).

Nitrogen fixation is a chemical process by which molecular dinitrogen (N
₂) is converted into ammonia (NH
₃). It occurs both biologically and abiologically in chemical industries. Biological nitrogen fixation or diazotrophy is catalyzed by enzymes called nitrogenases. These enzyme complexes are encoded by the Nif genes (or Nif homologs) and contain iron, often with a second metal (usually molybdenum, but sometimes vanadium).

Some nitrogen-fixing bacteria have symbiotic relationships with plants, especially legumes, mosses and aquatic ferns such as Azolla. Looser non-symbiotic relationships between diazotrophs and plants are often referred to as associative, as seen in nitrogen fixation on rice roots. Nitrogen fixation occurs between some termites and fungi. It occurs naturally in the air by means of NO_x production by lightning.

A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group (gold, copper, lead, aluminium, mercury, silver) and the platinum group (platinum, iridium, osmium, palladium, rhodium, ruthenium). Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.

Only gold, silver, copper and the platinum group occur native in large amounts. Over geological time scales, very few metals can resist natural weathering processes like oxidation, so mainly the less reactive metals such as gold and platinum are found as native metals. The others usually occur as isolated pockets where a natural chemical process reduces a common compound or ore of the metal, leaving the pure metal behind as small flakes or inclusions.

Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide (α-Al₂O₃) with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name sapphire is derived from the Latin word sapphirus, itself from the Greek word sappheiros (σάπφειρος), which referred to lapis lazuli. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called rubies rather than sapphires. Pink-colored corundum may be classified either as ruby or sapphire depending on the locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires – 9 on the Mohs scale (the third-hardest mineral, after diamond at 10 and moissanite at 9.5) – sapphires are also used in some non-ornamental applications, such as infrared optical components, high-durability windows, wristwatch crystals and movement bearings, and very thin electronic wafers, which are used as the insulating substrates of special-purpose solid-state electronics such as integrated circuits and GaN-based blue LEDs. It occurs in association with ruby, zircon, biotite, muscovite, calcite, dravite and quartz.

The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)₂O₆, where X represents ions of calcium (Ca), sodium (Na), iron (Fe(II)) or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron (Fe(II) or Fe(III)). Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.

The name pyroxene is derived from the Ancient Greek words for 'fire' (πυρ, pur) and 'stranger' (ξένος, xénos). Pyroxenes were so named due to their presence in volcanic lavas, where they are sometimes found as crystals embedded in volcanic glass; it was assumed they were impurities in the glass, hence the name meaning "fire stranger". However, they are simply early-forming minerals that crystallized before the lava erupted.

Emerald is a gemstone and a variety of the mineral beryl (Be₃Al₂(SiO₃)₆) colored green by trace amounts of chromium or sometimes vanadium. Beryl has a hardness of 7.5–8 on the Mohs scale. Most emeralds have many inclusions, so their toughness (resistance to breakage) is classified as generally poor. Emerald is a cyclosilicate. It occurs mainly in association with quartz, muscovite, albite, schorl, microcline, fluorite, smoky quartz and elbaite.

Carbon steel (US) or Non-alloy steel (Europe) is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states:

• no minimum content is specified or required for chromium, cobalt, molybdenum, nickel, niobium, titanium, tungsten, vanadium, zirconium, or any other element to be added to obtain a desired alloying effect;
• the specified minimum for copper does not exceed 0.40%;
• or the specified maximum for any of the following elements does not exceed: manganese 1.65%; silicon 0.60%; and copper 0.60%.

As the carbon content percentage rises, steel has the ability to become harder and stronger through heat treating; however, it becomes less ductile. Regardless of the heat treatment, a higher carbon content reduces weldability. In carbon steels, the higher carbon content lowers the melting point.

Heavy fuel oil (HFO) is a fuel oil of a tar-like consistency. Also known as bunker fuel, or residual fuel oil, HFO is the residual mixture leftover from the distillation and cracking of crude oil in oil refineries. Generally, it has a boiling temperature between 350 and 500 °C and a significantly increased viscosity compared to diesel. As it is created through the extraction of more valuable components of its petroleum precursor, HFO contains various undesirable compounds and elements, which includes aromatics, sulfur, nitrogen, vanadium, and others. These non-hydrocarbon contaminants significantly increase toxic gas and particulate emissions upon combustion, such as sulfur dioxide, carbon monoxide, and nitrogen oxides.

As the fuel is cheap, it is predominantly utilized for marine vessel propulsion in marine diesel engines due to its relatively low cost compared to cleaner fuel sources such as diesel fuel or distillates. The emission-heavy nature of the fuel also contributes to this method of usage; marine vessels, such as oil tankers and cruise ships, are generally distant from population centers, sailing in open seas and oceans for the majority of the time, minimizing the exposure of humans to harmful aerosols and gaseous emissions. Ships utilizing heavy fuel oil may switch to cleaner alternatives such as diesel when approaching land. The use and carrying of HFO in seafaring vessels presents several environmental concerns, such as accidental oil spills due to adverse weather or routine handling, which are common due to their universal and dominant usage in marine transportation.

The Bushveld Igneous Complex (BIC) is the largest layered igneous intrusion within the Earth's crust. It has been tilted and eroded forming the outcrops around what appears to be the edge of a great geological basin: the Transvaal Basin. It is approximately two billion years old and is divided into four limbs or lobes: northern, eastern, southern and western. It comprises the Rustenburg Layered suite, the Lebowa Granites and the Rooiberg Felsics, that are overlain by the Karoo sediments. The site was first publicised around 1897 by Gustaaf Molengraaff who found the native South African tribes residing in and around the area.

Located in South Africa, the BIC contains some of the richest ore deposits on Earth. It contains the world's largest reserves of platinum-group metals (PGMs) and platinum group elements (PGEs) — platinum, palladium, osmium, iridium, rhodium and ruthenium — along with vast quantities of iron, tin, chromium, titanium and vanadium. These are used in, but not limited to, jewellery, automobiles and electronics. Gabbro or norite is also quarried from parts of the complex and rendered into dimension stone. There have been more than 20 mine operations. There have been studies of potential uranium deposits. The complex is well known for its chromitite reef deposits, particularly the Merensky reef and the UG2 reef. It represents about 75 percent of the world's platinum and about 50 percent of the world's palladium resources. In this respect, the Bushveld complex is unique and one of the most economically significant mineral deposit complexes in the world.

In chemistry, a vanadate is an anionic coordination complex of vanadium. Often vanadate refers to oxoanions of vanadium, most of which exist in its highest oxidation state of +5. The complexes [V(CN)₆] and [V₂Cl₉] are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively.

A simple vanadate ion is the tetrahedral orthovanadate anion, VO3−4 (which is also called vanadate(V)), which is present in e.g. sodium orthovanadate and in solutions of V₂O₅ in strong base (pH > 13). Conventionally this ion is represented with a single double bond, however this is a resonance form as the ion is a regular tetrahedron with four equivalent oxygen atoms.

Tantalum is a chemical element; it has symbol Ta and atomic number 73. It is named after Tantalus, a figure in Greek mythology. Tantalum is a very hard, ductile, lustrous, blue-gray transition metal that is highly corrosion-resistant. It is part of the refractory metals group, which are widely used as components of strong high-melting-point alloys. It is a group 5 element, along with vanadium and niobium, and it always occurs in geologic sources together with the chemically similar niobium, mainly in the mineral groups tantalite, columbite, and coltan.

The chemical inertness and very high melting point of tantalum make it valuable for laboratory and industrial equipment such as reaction vessels and vacuum furnaces. It is used in tantalum capacitors for electronic equipment such as computers. It is being investigated for use as a material for high-quality superconducting resonators in quantum processors.

Andrés Manuel del Río y Fernández (10 November 1764 – 23 March 1849) was a Spanish-born Mexican scientist, naturalist and engineer who discovered compounds of vanadium in 1801. He proposed that the element be given the name panchromium, or later, erythronium, but his discovery was not credited at the time, and his names were not used.

Nils Gabriel Sefström (2 June 1787 – 30 November 1845) was a Swedish chemist and metallurgist. A protégé of Jöns Jakob Berzelius, he rediscovered the element vanadium in 1830 while investigating the brittleness of steel.

Vanadinite is a mineral belonging to the apatite group of phosphates, with the chemical formula Pb₅(VO₄)₃Cl. It is one of the main industrial ores of the metal vanadium and a minor source of lead. A dense, brittle mineral, it is usually found in the form of red hexagonal crystals. It is an uncommon mineral, formed by the oxidation of lead ore deposits such as galena. First discovered in 1801 in Mexico, vanadinite deposits have since been unearthed in South America, Europe, Africa, and North America.

Sir Henry Enfield Roscoe FRS (7 January 1833 – 18 December 1915) was a British chemist. He is particularly noted for early work on vanadium, photochemical studies, and his assistance in creating Oxo, in its earlier liquid form.