A liquid crystal phase is thermotropic if its order parameter is determined by temperature. At high temperatures, liquid crystals become an isotropic liquid and at low temperatures, they tend to glassify. In a thermotropic crystal, those phase transitions occur only at temperature extremes; the phase is insensitive to concentration.
Most thermotropic liquid crystals are composed of rod-like molecules, and admit nematic, smectic, or cholesterolic phases.
Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal can flow like a liquid, but its molecules may be oriented in a common direction as in a solid. There are many types of LC phases, which can be distinguished by their optical properties (such as textures). The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations. An LC material may not always be in an LC state of matter (just as water may be ice or water vapour).
Liquid crystals can be divided into three main types: thermotropic, lyotropic, and metallotropic. Thermotropic and lyotropic liquid crystals consist mostly of organic molecules, although a few minerals are also known. Thermotropic LCs exhibit a phase transition into the LC phase as temperature changes. Lyotropic LCs exhibit phase transitions as a function of both temperature and concentration of molecules in a solvent (typically water). Metallotropic LCs are composed of both organic and inorganic molecules; their LC transition additionally depends on the inorganic-organic composition ratio.
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