Surveyor 7 in the context of "Lunar horizon glow"

The atmosphere of the Moon is a very sparse layer of gases surrounding the Moon, consisting only of an exosphere. For most practical purposes, the Moon is considered to be surrounded by vacuum. The elevated presence of atomic and molecular particles in its vicinity compared to interplanetary medium, referred to as "lunar atmosphere" for scientific objectives, is negligible in comparison with the gaseous envelopes surrounding Earth and most planets of the Solar System, and comparable to their exospheres. The pressure of this small mass is around 3×10 atm (0.3 nPa), varying throughout the day, and has a total mass of less than 10 metric tonnes. Otherwise, the Moon is considered not to have an atmosphere because it cannot absorb measurable quantities of radiation, does not appear layered or self-circulating, and requires constant replenishment due to the high rate at which its gases are lost into space.

Roger Joseph Boscovich was the first modern astronomer to argue for the lack of atmosphere around the Moon in his De lunae atmosphaera (1753).