Structural unit in the context of Copolymer


Structural unit in the context of Copolymer

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⭐ Core Definition: Structural unit

In polymer chemistry, a structural unit is a building block of a polymer chain. It is the result of a monomer which has been polymerized into a long chain.

There may be more than one structural unit in the repeat unit. When different monomers are polymerized, a copolymer is formed. It is a routine way of developing new properties for new materials.

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Structural unit in the context of Degree of polymerization

The degree of polymerization, or DP, is the number of monomeric units in a macromolecule or polymer or oligomer molecule.

For a homopolymer, there is only one type of monomeric unit and the number-average degree of polymerization is given by ,where is the number-average molecular weight and is the molecular weight of the monomer unit. The overlines indicate arithmetic mean values. For most industrial purposes, degrees of polymerization in the thousands or tens of thousands are desired. This number does not reflect the variation in molecule size of the polymer that typically occurs, it only represents the mean number of monomeric units.

View the full Wikipedia page for Degree of polymerization
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