Strontium titanate in the context of Strontium


Strontium titanate in the context of Strontium

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⭐ Core Definition: Strontium titanate

Strontium titanate is an oxide of strontium and titanium with the chemical formula SrTiO3. At room temperature, it is a centrosymmetric paraelectric material with a perovskite structure. At low temperatures it approaches a ferroelectric phase transition with a very large dielectric constant ~10 but remains paraelectric down to the lowest temperatures measured as a result of quantum fluctuations, making it a quantum paraelectric. It was long thought to be a wholly artificial material, until 1982 when its natural counterpart—discovered in Siberia and named tausonite—was recognised by the IMA. Tausonite remains an extremely rare mineral in nature, occurring as very tiny crystals. Its most important application has been in its synthesized form wherein it is occasionally encountered as a diamond simulant, in precision optics, in varistors, and in advanced ceramics.

The name tausonite was given in honour of Lev Vladimirovich Tauson (1917–1989), a Russian geochemist. Disused trade names for the synthetic product include strontium mesotitanate, Diagem, and Marvelite. This product is currently being marketed for its use in jewelry under the name Fabulite. Other than its type locality of the Murun Massif in the Sakha Republic, natural tausonite is also found in Cerro Sarambi, Concepción department, Paraguay; and along the Kotaki River of Honshū, Japan.

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Strontium titanate in the context of Crystallography

Crystallography is the branch of science devoted to the study of molecular and crystalline structure and properties. The word crystallography is derived from the Ancient Greek word κρύσταλλος (krústallos; "clear ice, rock-crystal"), and γράφειν (gráphein; "to write"). In July 2012, the United Nations recognised the importance of the science of crystallography by proclaiming 2014 the International Year of Crystallography.

Crystallography is a broad topic, and many of its subareas, such as X-ray crystallography, are themselves important scientific topics. Crystallography ranges from the fundamentals of crystal structure to the mathematics of crystal geometry, including those that are not periodic or quasicrystals. At the atomic scale it can involve the use of X-ray diffraction to produce experimental data that the tools of X-ray crystallography can convert into detailed positions of atoms, and sometimes electron density. At larger scales it includes experimental tools such as orientational imaging to examine the relative orientations at the grain boundary in materials. Crystallography plays a key role in many areas of biology, chemistry, and physics, as well as in emerging developments in these fields.

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Strontium titanate in the context of Diamond simulant

A diamond simulant, diamond imitation or imitation diamond is an object or material with gemological characteristics similar to those of a diamond. Simulants are distinct from synthetic diamonds, which are actual diamonds exhibiting the same material properties as natural diamonds. Enhanced diamonds are also excluded from this definition. A diamond simulant may be artificial, natural, or in some cases a combination thereof. While their material properties depart markedly from those of diamond, simulants have certain desired characteristics—such as dispersion and hardness—which lend themselves to imitation. Trained gemologists with appropriate equipment are able to distinguish natural and synthetic diamonds from all diamond simulants, primarily by visual inspection.

The most common diamond simulants are high-leaded glass (i.e., rhinestones) and cubic zirconia (CZ), both artificial materials. A number of other artificial materials, such as strontium titanate and synthetic rutile have been developed since the mid-1950s, but these are no longer in common use. Introduced at the end of the 20th century, the lab-grown product moissanite has gained popularity as an alternative to diamond. The high price of gem-grade diamonds, as well as significant ethical concerns of the diamond trade, have created a large demand for diamond simulants.

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