Spontaneous emission in the context of "Jaynes–Cummings model"

Vacuum energy is an underlying background energy that exists in space throughout the entire universe. The vacuum energy is a special case of zero-point energy that relates to the quantum vacuum.

The effects of vacuum energy can be experimentally observed in various phenomena such as spontaneous emission, the Casimir effect, and the Lamb shift, and are thought to influence the behavior of the Universe on cosmological scales. Using the upper limit of the cosmological constant, the vacuum energy of free space has been estimated to be 10 joules (10 ergs), or ~5 GeV per cubic meter. However, in quantum electrodynamics, consistency with the principle of Lorentz covariance and with the magnitude of the Planck constant suggests a much larger value of 10 joules per cubic meter. This huge discrepancy is known as the cosmological constant problem or, colloquially, the "vacuum catastrophe."

Electron excitation is the transfer of a bound electron to a more energetic, but still bound state. This can be done by photoexcitation (PE), where the electron absorbs a photon and gains all its energy. Or it is achieved through collisional excitation (CE), where the electron receives energy from a collision with another, energetic electron. Within a semiconductor crystal lattice, thermal excitation is a process where lattice vibrations provide enough energy to transfer electrons to a higher energy band such as a more energetic sublevel or energy level. When an excited electron falls back to a state of lower energy, it undergoes electron relaxation (deexcitation). This is accompanied by the emission of a photon (radiative relaxation/spontaneous emission) or by a transfer of energy to another particle. The energy released is equal to the difference in energy levels between the electron energy states.

Excited states in nuclear, atomic, and molecule systems have distinct energy values, allowing external energy to be absorbed in the appropriate proportions.

Stimulated emission is the process by which an incoming photon of a specific frequency can interact with an excited atomic electron (or other excited molecular state), causing it to drop to a lower energy level. The liberated energy transfers to the electromagnetic field, creating a new photon with a frequency, polarization, and direction of travel that are all identical to the photons of the incident wave. This is in contrast to spontaneous emission, which occurs at a characteristic rate for each of the atoms/oscillators in the upper energy state regardless of the external electromagnetic field.

According to the American Physical Society, the first person to correctly predict the phenomenon of stimulated emission was Albert Einstein in a series of papers starting in 1916, culminating in what is now called the Einstein B Coefficient. Einstein's work became the theoretical foundation of the maser and the laser. The process is identical in form to atomic absorption in which the energy of an absorbed photon causes an identical but opposite atomic transition: from the lower level to a higher energy level. In normal media at thermal equilibrium, absorption exceeds stimulated emission because there are more electrons in the lower energy states than in the higher energy states. However, when a population inversion is present, the rate of stimulated emission exceeds that of absorption, and a net optical amplification can be achieved. Such a gain medium, along with an optical resonator, is at the heart of a laser or maser.Lacking a feedback mechanism, laser amplifiers and superluminescent sources also function on the basis of stimulated emission.

Luminescence is a spontaneous emission of radiation from an electronically or vibrationally excited species not in thermal equilibrium with its environment.  A luminescent object emits cold light in contrast to incandescence, where an object only emits light after heating. Generally, the emission of light is due to the movement of electrons between different energy levels within an atom after excitation by external factors. However, the exact mechanism of light emission in vibrationally excited species is unknown.

The dials, hands, scales, and signs of aviation and navigational instruments and markings are often coated with luminescent materials in a process known as luminising.

In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to an increase in energy level above a chosen starting point, usually the ground state, but sometimes an already excited state. The temperature of a group of particles is indicative of the level of excitation (with the notable exception of systems that exhibit negative temperature).

The lifetime of a system in an excited state is usually short: spontaneous or induced emission of a quantum of energy (such as a photon or a phonon) usually occurs shortly after the system is promoted to the excited state, returning the system to a state with lower energy (a less excited state or the ground state). This return to a lower energy level is known as de-excitation and is the inverse of excitation.