Spectroscopy in the context of "Hipparcos Catalogue"

Quantum chemistry, also called molecular quantum mechanics, is a branch of physical chemistry focused on the application of quantum mechanics to chemical systems, particularly towards the quantum-mechanical calculation of electronic contributions to physical and chemical properties of molecules, materials, and solutions at the atomic level. These calculations include systematically applied approximations intended to make calculations computationally feasible while still capturing as much information about important contributions to the computed wave functions as well as to observable properties such as structures, spectra, and thermodynamic properties. Quantum chemistry is also concerned with the computation of quantum effects on molecular dynamics and chemical kinetics.

Chemists rely heavily on spectroscopy through which information regarding the quantization of energy on a molecular scale can be obtained. Common methods are infra-red (IR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, and scanning probe microscopy. Quantum chemistry may be applied to the prediction and verification of spectroscopic data as well as other experimental data.

The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances.

Interferometry is a technique which uses the interference of superimposed waves to extract information. Interferometry typically uses electromagnetic waves and is an important investigative technique in the fields of astronomy, fiber optics, engineering metrology, optical metrology, oceanography, seismology, spectroscopy (and its applications to chemistry), quantum mechanics, nuclear and particle physics, plasma physics, biomolecular interactions, surface profiling, microfluidics, mechanical stress/strain measurement, velocimetry, optometry, and making holograms.

Interferometers are devices that extract information from interference. They are widely used in science and industry for the measurement of microscopic displacements, refractive index changes and surface irregularities. In the case with most interferometers, light from a single source is split into two beams that travel in different optical paths, which are then combined again to produce interference; two incoherent sources can also be made to interfere under some circumstances. The resulting interference fringes give information about the difference in optical path lengths. In analytical science, interferometers are used to measure lengths and the shape of optical components with nanometer precision; they are the highest-precision length measuring instruments in existence. In Fourier transform spectroscopy they are used to analyze light containing features of absorption or emission associated with a substance or mixture. An astronomical interferometer consists of two or more separate telescopes that combine their signals, offering a resolution equivalent to that of a telescope of diameter equal to the largest separation between its individual elements.

Wolf–Rayet stars, often abbreviated as WR stars, are a rare heterogeneous set of stars with unusual spectra showing prominent broad emission lines of ionised helium and highly ionised nitrogen or carbon. The spectra indicate very high surface enhancement of heavy elements, depletion of hydrogen, and strong stellar winds. The surface temperatures of known Wolf–Rayet stars range from 20,000 K to around 210,000 K, hotter than almost all other kinds of stars. They were previously called W-type stars referring to their spectral classification.

Classic (or population I) Wolf–Rayet stars are evolved, massive stars that have completely lost their outer hydrogen and are fusing helium or heavier elements in the core. A subset of the population I WR stars show hydrogen lines in their spectra and are known as WNh stars; they are young extremely massive stars still fusing hydrogen at the core, with helium and nitrogen exposed at the surface by strong mixing and radiation-driven mass loss. A separate group of stars with WR spectra are the central stars of planetary nebulae (CSPNe), post-asymptotic giant branch stars that were similar to the Sun while on the main sequence, but have now ceased fusion and shed their atmospheres to reveal a bare carbon-oxygen core.

Astronomical spectroscopy is the study of astronomy using the techniques of spectroscopy to measure the spectrum of electromagnetic radiation, including visible light, ultraviolet, X-ray, infrared and radio waves that radiate from stars and other celestial objects. A stellar spectrum can reveal many properties of stars, such as their chemical composition, temperature, density, mass, distance and luminosity. Spectroscopy can show the velocity of motion towards or away from the observer by measuring the Doppler shift. Spectroscopy is also used to study the physical properties of many other types of celestial objects such as planets, nebulae, galaxies, and active galactic nuclei.

Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique based on re-orientation of atomic nuclei with non-zero nuclear spins in an external magnetic field. This re-orientation occurs with absorption of electromagnetic radiation in the radio frequency region from roughly 4 to 900 MHz, which depends on the isotopic nature of the nucleus and increases proportionally to the strength of the external magnetic field. Notably, the resonance frequency of each NMR-active nucleus depends on its chemical environment. As a result, NMR spectra provide information about individual functional groups present in the sample, as well as about connections between nearby nuclei in the same molecule. As the NMR spectra are unique or highly characteristic to individual compounds and functional groups, NMR spectroscopy is one of the most important methods to identify molecular structures, particularly of organic compounds.

The principle of NMR usually involves three sequential steps:

An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. The variable measured is most often the irradiance of the light but could also, for instance, be the polarization state. The independent variable is usually the wavelength of the light or a closely derived physical quantity, such as the corresponding wavenumber or the photon energy, in units of measurement such as centimeters, reciprocal centimeters, or electron volts, respectively.

A spectrometer is used in spectroscopy for producing spectral lines and measuring their wavelengths and intensities. Spectrometers may operate over a wide range of non-optical wavelengths, from gamma rays and X-rays into the far infrared. If the instrument is designed to measure the spectrum on an absolute scale rather than a relative one, then it is typically called a spectrophotometer. The majority of spectrophotometers are used in spectral regions near the visible spectrum.

A binary star or binary star system is a system of two stars that are gravitationally bound to and in orbit around each other. Binary stars in the night sky that are seen as a single object to the naked eye are often resolved as separate stars using a telescope, in which case they are called visual binaries. Many visual binaries have long orbital periods of several centuries or millennia and therefore have orbits which are uncertain or poorly known. They may also be detected by indirect techniques, such as spectroscopy (spectroscopic binaries) or astrometry (astrometric binaries). If a binary star happens to orbit in a plane along our line of sight, its components will eclipse and transit each other; these pairs are called eclipsing binaries, or, together with other binaries that change brightness as they orbit, photometric binaries.

If components in binary star systems are close enough, they can gravitationally distort each other's outer stellar atmospheres. In some cases, these close binary systems can exchange mass, which may bring their evolution to stages that single stars cannot attain. Examples of binaries are Sirius and Cygnus X-1 (Cygnus X-1 being a well-known black hole). Binary stars are also common as the nuclei of many planetary nebulae, and are the progenitors of both novae and type Ia supernovae.

Georges-Antoine-Pons Rayet (12 December 1839 – 14 June 1906) was a French astronomer.

He was born in Bordeaux, France. He began working at the Paris Observatory in 1863. He worked on meteorology in addition to astronomy. He specialized in what was then the new field of spectroscopy.

In spectroscopy, spectral flux density is the quantity that describes the rate at which energy is transferred by electromagnetic radiation through a real or virtual surface, per unit surface area and per unit wavelength (or, equivalently, per unit frequency). It is a radiometric rather than a photometric measure. In SI units it is measured in W m, although it can be more practical to use W m nm (1 W m nm = 1 GW m = 1 W mm) or W m μm (1 W m μm = 1 MW m), and respectively by W·m·Hz, Jansky or solar flux units. The terms irradiance, radiant exitance, radiant emittance, and radiosity are closely related to spectral flux density.

The terms used to describe spectral flux density vary between fields, sometimes including adjectives such as "electromagnetic" or "radiative", and sometimes dropping the word "density". Applications include:

XMM-Newton, also known as the High Throughput X-ray Spectroscopy Mission and the X-ray Multi-Mirror Mission, is an X-ray space observatory launched by the European Space Agency in December 1999 on an Ariane 5 rocket. It is the second cornerstone mission of ESA's Horizon 2000 programme. Named after physicist and astronomer Sir Isaac Newton, the spacecraft is tasked with investigating interstellar X-ray sources, performing narrow- and broad-range spectroscopy, and performing the first simultaneous imaging of objects in both X-ray and optical (visible and ultraviolet) wavelengths.

Initially funded for two years, with a ten-year design life, the spacecraft remains in good health and has received repeated mission extensions, most recently in March 2023 and is scheduled to operate until the end of 2026. ESA plans to succeed XMM-Newton with the Advanced Telescope for High Energy Astrophysics (ATHENA), the second large mission in the Cosmic Vision 2015–2025 plan, to be launched in 2035. XMM-Newton is similar to NASA's Chandra X-ray Observatory, also launched in 1999.

Sedna (minor-planet designation: 90377 Sedna) is a dwarf planet in the outermost reaches of the Solar System, orbiting the Sun far beyond the orbit of Neptune. It was discovered in 2003, and is roughly 1,000 km in diameter. Spectroscopic analysis has revealed its surface to be a mixture of the solid ices of water, carbon dioxide, and ethane, along with sedimentary deposits of methane-derived, reddish-colored tholins, a chemical makeup similar to the surfaces of other trans-Neptunian objects. Sedna is not expected to have a substantial atmosphere. Within the range of uncertainty, it is tied with Ceres in the asteroid belt as the largest dwarf planet not known to have a moon. Owing to its lack of known moons, Sedna's mass and density remain unknown.

Sedna takes approximately 11,400 years to complete one orbit around the Sun. Its orbit is one of the widest known in the Solar System. Its aphelion is located 937 astronomical units (AU) away, about 19 times farther than that of Pluto. Sedna's orbit is also one of the most elliptical discovered, with an eccentricity of 0.85. As of February 2025, Sedna is 83.2 AU (12.4 billion km) from the Sun, 2.5 times as far away as Neptune.

In spectroscopy, hypsochromic shift (from Ancient Greek ὕψος (upsos) 'height' and χρῶμα (chrōma) 'color') is a change of spectral band position in the absorption, reflectance, transmittance, or emission spectrum of a molecule to a shorter wavelength (higher frequency). Because the blue color in the visible spectrum has a shorter wavelength than most other colors, this effect is also commonly called a blue shift. It should not be confused with a bathochromic shift, which is the opposite process – the molecule's spectra are changed to a longer wavelength (lower frequency).

Hypsochromic shifts can occur because of a change in environmental conditions. For example, a change in solvent polarity will result in solvatochromism. A series of structurally related molecules in a substitution series can also show a hypsochromic shift. Hypsochromic shift is a phenomenon seen in molecular spectra, not atomic spectra - it is thus more common to speak of the movement of the peaks in the spectrum rather than lines.

In spectroscopy, bathochromic shift (from Greek βαθύς (bathys) 'deep' and χρῶμα (chrōma) 'color'; hence less common alternate spelling "bathychromic") is a change of spectral band position in the absorption, reflectance, transmittance, or emission spectrum of a molecule to a longer wavelength (lower frequency). Because the red color in the visible spectrum has a longer wavelength than most other colors, the effect is also commonly called a red shift.

Hypsochromic shift is a change to shorter wavelength (higher frequency).

Psittacofulvin pigments, sometimes called psittacins, are responsible for the bright-red, orange, and yellow colors specific to parrots. In parrots, psittacofulvins are synthesized by a polyketide synthase enzyme that is expressed in growing feathers. They consist of linear polyenes terminated by an aldehyde group. There are five known psittacofulvin pigments - tetradecahexenal, hexadecaheptenal, octadecaoctenal and eicosanonenal, in addition to a fifth, currently-unidentified pigment found in the feathers of scarlet macaws. Colorful feathers with high levels of psittacofulvin resist feather-degrading Bacillus licheniformis better than white ones.

Both carotenoids and psittacofulvins have narrow-band absorbance spectra, reflecting pale yellow or red pigmentary colors, making them difficult to distinguish between using spectral measurements. However, there are differences between them when researched spectroscopically. The carotenoid and psittacofulvin yellows are very similar, but the red parrot pigment offers an advantage: it creates a more deep-red color when compared to astaxanthin, the pigment's counterpart in most other birds.

Absorption spectroscopy is spectroscopy that involves techniques that measure the absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.

Absorption spectroscopy is employed as an analytical chemistry tool to determine the presence of a particular substance in a sample and, in many cases, to quantify the amount of the substance present. Infrared and ultraviolet–visible spectroscopy are particularly common in analytical applications. Absorption spectroscopy is also employed in studies of molecular and atomic physics, astronomical spectroscopy and remote sensing.