Solvation in the context of "Aqueous"

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⭐ Core Definition: Solvation

Solvations describes the interaction of a solvent with dissolved molecules. Both ionized and uncharged molecules interact strongly with a solvent, and the strength and nature of this interaction influence many properties of the solute, including solubility, reactivity, and color, as well as influencing the properties of the solvent such as its viscosity and density. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. The surrounded solute particles then move away from the solid solute and out into the solution. Ions are surrounded by a concentric shell of solvent. Solvation is the process of reorganizing solvent and solute molecules into solvation complexes and involves bond formation, hydrogen bonding, and van der Waals forces. Solvation of a solute by water is called hydration.

Solubility of solid compounds depends on a competition between lattice energy and solvation, including entropy effects related to changes in the solvent structure.

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Solvation in the context of Saline water

Saline water (more commonly known as salt water) is water that contains a high concentration of dissolved salts (mainly sodium chloride). On the United States Geological Survey (USGS) salinity scale, saline water is saltier than brackish water, but less salty than brine. The salt concentration is usually expressed in parts per thousand (permille, ‰) and parts per million (ppm). The USGS salinity scale defines three levels of saline water. The salt concentration in slightly saline water is 1,000 to 3,000 ppm (0.1–0.3%); in moderately saline water is 3,000 to 10,000 ppm (0.3–1%); and in highly saline water is 10,000 to 35,000 ppm (1–3.5%). Seawater has a salinity of roughly 35,000 ppm, equivalent to 35 grams of salt per one liter (or kilogram) of water. The saturation level is only nominally dependent on the temperature of the water. At 20 °C (68 °F) one liter of water can dissolve about 357 grams of salt, a concentration of 26.3 percent by weight (% w/w). At 100 °C (212 °F) (the boiling temperature of pure water), the amount of salt that can be dissolved in one liter of water increases to about 391 grams, a concentration of 28.1% w/w.

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Solvation in the context of Erosion

Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust and then transports it to another location where it is deposited. Erosion is distinct from weathering which involves no movement. Removal of rock or soil as clastic sediment is referred to as physical or mechanical erosion; this contrasts with chemical erosion, where soil or rock material is removed from an area by dissolution. Eroded sediment or solutes may be transported just a few millimetres, or for thousands of kilometres.

Agents of erosion include rainfall; bedrock wear in rivers; coastal erosion by the sea and waves; glacial plucking, abrasion, and scour; areal flooding; wind abrasion; groundwater processes; and mass movement processes in steep landscapes like landslides and debris flows. The rates at which such processes act control how fast a surface is eroded. Typically, physical erosion proceeds the fastest on steeply sloping surfaces, and rates may also be sensitive to some climatically controlled properties including amounts of water supplied (e.g., by rain), storminess, wind speed, wave fetch, or atmospheric temperature (especially for some ice-related processes). Feedbacks are also possible between rates of erosion and the amount of eroded material that is already carried by, for example, a river or glacier. The transport of eroded materials from their original location is followed by deposition, which is arrival and emplacement of material at a new location.

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Solvation in the context of Hydroxide

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical.The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group −OH of atoms is the hydroxy group.Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

Many inorganic substances which bear the word hydroxide in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups.

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Solvation in the context of Enthalpy

Enthalpy (/ˈɛnθəlpi/ ) is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by Earth's ambient atmosphere. The pressure–volume term expresses the work that was done against constant external pressure to establish the system's physical dimensions from to some final volume (as ), i.e. to make room for it by displacing its surroundings.The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; bond, lattice, solvation, and other chemical "energies" are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal energy, pressure, and volume, not on the path taken to achieve it.

In the International System of Units (SI), the unit of measurement for enthalpy is the joule. Other historical conventional units still in use include the calorie and the British thermal unit (BTU).

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