Smokeless powder in the context of Cannons

Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, charcoal (which is mostly carbon), and potassium nitrate (saltpeter). The sulfur and charcoal act as fuels, while the saltpeter is an oxidizer. Gunpowder has been widely used as a propellant in firearms, artillery, rocketry, and pyrotechnics, including use as a blasting agent for explosives in quarrying, mining, building pipelines, tunnels, and roads.

Gunpowder is classified as a low explosive because of its relatively slow decomposition rate, low ignition temperature and consequently low brisance (breaking/shattering). Low explosives deflagrate—burning at subsonic speeds—whereas high explosives detonate, producing a supersonic shockwave. Ignition of gunpowder packed behind a projectile generates enough pressure to force the shot from the muzzle at high speed, but usually not enough force to rupture the gun barrel. It thus makes a good propellant but is less suitable for shattering rock or fortifications with its low-yield explosive power. Nonetheless, it was widely used to fill fused artillery shells (and used in mining and civil engineering projects) until the second half of the 19th century, when the first high explosives were put into use.

A firearm is any type of gun that shoots projectiles using high explosive pressure generated from combustion (deflagration) of chemical propellant, most often black powder in antique firearms and smokeless powder in modern firearms. Small arms is a subset of light firearms that is designed to be readily carried and operated by an individual. The term "firearm" is however variably defined in both technically and legally in different countries (see legal definitions), and can be used colloquially (sometimes incorrectly) to refer to any type of guns.

The first firearms originated in 10th-century Song dynasty China (see gunpowder weapons in the Song dynasty), when bamboo tubes containing gunpowder and pellet projectiles were mounted on spears to make the portable fire lance, which was operable by a single person and was later used effectively as a shock weapon in the siege of De'an in 1132. In the 13th century, fire lance barrels were replaced with metal tubes and transformed into the metal-barreled hand cannon, and the technology gradually spread throughout Eurasia during the 14th century. Older firearms typically used black powder as a propellant, but modern firearms use smokeless powder or other explosive propellants. Most modern firearms (with the notable exception of smoothbore shotguns) have rifled barrels to impart a stabilizing spin to the bullet for improved external ballistics.

A cannon (plural either cannons or cannon) is a large-caliber gun classified as a type of artillery, which usually launches a projectile using explosive chemical propellant. Gunpowder ("black powder") was the primary propellant before the invention of smokeless powder during the late 19th century. Cannons vary in gauge, effective range, mobility, rate of fire, angle of fire and firepower; different forms of cannon combine and balance these attributes in varying degrees, depending on their intended use on the battlefield. A cannon is a type of heavy artillery weapon. The word cannon is derived from several languages, in which the original definition can usually be translated as tube, cane, or reed.

The earliest known depiction of cannons may have appeared in Song dynasty China as early as the 12th century; however, solid archaeological and documentary evidence of cannons do not appear until the 13th century. In 1288, Yuan dynasty troops are recorded to have used hand cannons in combat, and the earliest extant cannon bearing a date of production comes from the same period. By the end of the 14th century, cannons were widespread throughout Eurasia.

An antique firearm is a term used to describe a firearm that was designed and manufactured prior to the beginning of the 20th century. Although the exact definition of what constitutes an "antique firearm" varies between countries, the advent of smokeless powder or the start of the Boer War are often used as cut-off dates. Antique firearms are usually collected because of their historical interest and/or their monetary value.

An air gun or airgun is a gun that uses compressed air or other pressurized gases to fire projectiles, reminiscent of the principle behind the ancient blowgun. This is in contrast to a firearm, which shoots projectiles using pressure generated via combustion of a chemical propellant, most often black powder in antique firearms and smokeless powder in modern firearms.

Air guns come in both long gun (air rifle) and handgun (air pistol) forms. Both types typically propel metallic projectiles that are either diabolo-shaped pellets or spherical shots called BBs, although in recent years Minié ball-shaped cylindro-conoidal projectiles called slugs are gaining more popularity. Certain types of air guns (usually air rifles) may also launch fin-stabilized projectile such as darts (e.g., tranquilizer guns) or hollow-shaft arrows (so-called "airbows").

A cartridge, also known as a round, is a type of pre-assembled firearm ammunition packaging a projectile (bullet, shot, or slug), a propellant substance (smokeless powder, black powder substitute, or black powder) and an ignition device (primer or percussion cap) within a metallic, paper, or plastic case that is precisely made to fit within the barrel chamber of a breechloading gun, for convenient transportation and handling during shooting. Although in popular usage the term "bullet" is often used to refer to a complete cartridge, the correct usage only refers to the projectile.

Military and commercial producers continue to pursue the goal of caseless ammunition. Some artillery ammunition uses the same cartridge concept as found in small arms. In other cases, the artillery shell is separate from the propellant charge.

A harpoon cannon is a whaling implement developed in the late 19th century and most used in the 20th century. It would be mounted on the bow of a whale catcher, where it could be easily aimed with a wide field of view at the target. Powered by black powder and later, smokeless powder, it would generally fire a large steel harpoon, either solid steel (cold harpoon) or fitted with an exploding black powder, or later, penthrite (PETN) grenade.

Harpoon cannons are still used by whaling nations, but these are usually guns of a smaller caliber. The exception is Iceland, which hunts large whales regularly.

Nitroglycerin (NG) (alternative spelling nitroglycerine), also known as trinitroglycerol (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless or pale yellow, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is a nitrate ester rather than a nitro compound, but the traditional name is retained. Discovered in 1846 by Ascanio Sobrero, nitroglycerin has been used as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. It is combined with nitrocellulose to form double-based smokeless powder, used as a propellant in artillery and firearms since the 1880s.

As is the case for many other explosives, nitroglycerin becomes more and more prone to exploding (i.e., spontaneous decomposition) as the temperature is increased. Upon exposure to heat above 218 °C at sea-level atmospheric pressure, nitroglycerin becomes extremely unstable and tends to explode. When placed in vacuum, it has an autoignition temperature of 270 °C instead. With a melting point of 12.8 °C, the chemical is almost always encountered as a thick and viscous fluid, changing to a crystalline solid when frozen. Although the pure compound itself is colorless, in practice the presence of nitric oxide impurities left over during production tends to give it a slight yellowish tint.

The .308 Winchester is a smokeless powder rimless bottlenecked rifle cartridge widely used for hunting, target shooting, police, military, and personal protection applications globally. It is similar, but not identical, to the 7.62×51mm NATO cartridge.