Sky brightness refers to the visual perception of the sky and how it scatters and diffuses light. The fact that the sky is not completely dark at night is easily visible. If light sources (e.g. the Moon and light pollution) were removed from the night sky, only direct starlight would be visible.
The sky's brightness varies greatly over the day, and the primary cause differs as well. During daytime, when the Sun is above the horizon, the direct scattering of sunlight is the overwhelmingly dominant source of light. During twilight (the duration after sunset or before sunrise until or since, respectively, the full darkness of night), the situation is more complicated, and a further differentiation is required.