Single crystal in the context of "Solid"

⭐ In the context of solids, how does the degree of atomic kinetic energy relate to their response to thermal expansion?

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⭐ Core Definition: Single crystal


In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no grain boundaries. The absence of the defects associated with grain boundaries can give monocrystals unique properties, particularly mechanical, optical and electrical, which can also be anisotropic, depending on the type of crystallographic structure. These properties, in addition to making some gems precious, are industrially used in technological applications, especially in optics and electronics.

Because entropic effects favor the presence of some imperfections in the microstructure of solids, such as impurities, inhomogeneous strain and crystallographic defects such as dislocations, perfect single crystals of meaningful size are exceedingly rare in nature. The necessary laboratory conditions often add to the cost of production. On the other hand, imperfect single crystals can reach enormous sizes in nature: several mineral species such as beryl, gypsum and feldspars are known to have produced crystals several meters across.

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👉 Single crystal in the context of Solid

Solid is a state of matter in which atoms are closely packed and are difficult to move past each other. Solids resist compression, expansion, or external forces that would alter its shape, with the degree of resistance being dependent upon the specific material under consideration. Solids also always possess the least amount of kinetic energy per atom/molecule relative to other phases or, equivalently stated, solids are formed when matter in the liquid / gas phase is cooled below a certain temperature. This temperature is called the melting point of the substance and is an intrinsic property; i.e. independent of how much of the matter there is. The vast majority of substances, when in the solid state, can be arranged in one of a few ubiquitous structures.

Solids are characterized by structural rigidity and resistance to applied external forces and pressure. Unlike liquids, solids do not flow to take on the shape of their container, nor do they expand to fill the entire available volume like a gas. Much like the other three fundamental phases, solids also expand when heated, the thermal energy put into increasing the distance and reducing the potential energy between atoms. However, solids do this to a much lesser extent. When heated to their melting point or sublimation point, solids melt into a liquid or sublimate directly into a gas, respectively. For solids that directly sublimate into a gas, the melting point is replaced by the sublimation point. As a rule of thumb, melting will occur if the subjected pressure is higher than the substance's triple point pressure, and sublimation will occur otherwise. Melting and melting points refer exclusively to transitions between solids and liquids. Melting occurs across a great extent of temperatures, ranging from 0.10 K for helium-3 under 30 bars (3 MPa) of pressure, to around 4,100 K at 1 atm for the composite refractory material hafnium carbonitride.

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Single crystal in the context of Crystal

A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification.

The word crystal derives from the Ancient Greek word κρύσταλλος (krustallos), meaning both "ice" and "rock crystal", from κρύος (kruos), "icy cold, frost".

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Single crystal in the context of Crystalline silicon

Crystalline silicon or (c-Si) is the crystalline forms of silicon, either polycrystalline silicon (poly-Si, consisting of small crystals), or monocrystalline silicon (mono-Si, a continuous crystal). Crystalline silicon is the dominant semiconducting material used in photovoltaic technology for the production of solar cells. These cells are assembled into solar panels as part of a photovoltaic system to generate solar power from sunlight.

In electronics, crystalline silicon is typically the monocrystalline form of silicon, and is used for producing microchips. This silicon contains much lower impurity levels than those required for solar cells. Production of semiconductor grade silicon involves a chemical purification to produce hyper-pure polysilicon, followed by a recrystallization process to grow monocrystalline silicon. The cylindrical boules are then cut into wafers for further processing.

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Single crystal in the context of Hydrothermal synthesis

Hydrothermal synthesis includes the various techniques of synthesizing substances from high-temperature aqueous solutions at high pressures; also termed "hydrothermal method". The term "hydrothermal" is of geologic origin. Geochemists and mineralogists have studied hydrothermal phase equilibria since the beginning of the twentieth century. George W. Morey at the Carnegie Institution and later, Percy W. Bridgman at Harvard University did much of the work to lay the foundations necessary to containment of reactive media in the temperature and pressure range where most of the hydrothermal work is conducted. In the broadest definition, a process is considered hydrothermal if it involves water temperatures above 100 °C (212 °F) and pressures above 1 atm.

In the context of material science, hydrothermal synthesis focuses on the production of single crystal. Under high temperature > (300 °C) and pressure (> 100 atm), ordinarily insoluble minerals become soluble in water. The crystal growth is performed in an apparatus consisting of a steel pressure vessel called an autoclave, in which the reactant ("nutrient") is supplied along with water. A temperature gradient is maintained between the opposite ends of the growth chamber. At the hotter end the nutrient solute dissolves, while at the cooler end it is deposited on a seed crystal, growing the desired crystal.

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Single crystal in the context of Boule (crystal)

A boule is a single-crystal ingot produced by synthetic means.

A boule of silicon is the starting material for most of the integrated circuits used today. In the semiconductor industry synthetic boules can be made by a number of methods, such as the Bridgman technique and the Czochralski process, which result in a cylindrical rod of material.

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Single crystal in the context of Seed crystal

A seed crystal is a small piece of single crystal or polycrystal material from which a large crystal of typically the same material is grown in a laboratory. Used to replicate material, the use of seed crystal to promote growth avoids the otherwise slow randomness of natural crystal growth, and allows manufacture on a scale suitable for industry.

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