Relativistic quantum chemistry in the context of "Lanthanide"

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⭐ Core Definition: Relativistic quantum chemistry

Relativistic quantum chemistry combines relativistic mechanics with quantum chemistry to calculate elemental properties and structure, especially for the heavier elements of the periodic table. A prominent example is an explanation for the color of gold: due to relativistic effects, it is not silvery like most other metals.

The term relativistic effects was developed in light of the history of quantum mechanics. Initially, quantum mechanics was developed without considering the theory of relativity. Relativistic effects are those discrepancies between values calculated by models that consider relativity and those that do not. Relativistic effects are important for heavier elements with high atomic numbers, such as lanthanides and actinides.

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Relativistic quantum chemistry in the context of Relativistic speed

Relativistic speed refers to speed at which relativistic effects become significant to the desired accuracy of measurement of the phenomenon being observed. Relativistic effects are those discrepancies between values calculated by models considering and not considering relativity. Related words are velocity, rapidity, and celerity which is proper velocity. Speed is a scalar, being the magnitude of the velocity vector which in relativity is the four-velocity and in three-dimension Euclidean space a three-velocity. Speed is empirically measured as average speed, although current devices in common use can estimate speed over very small intervals and closely approximate instantaneous speed. Non-relativistic discrepancies include cosine error which occurs in speed detection devices when only one scalar component of the three-velocity is measured and the Doppler effect which may affect observations of wavelength and frequency.

Relativistic effects are highly non-linear and for everyday purposes are insignificant because the Newtonian model closely approximates the relativity model. In special relativity the Lorentz factor is a measure of time dilation, length contraction and the relativistic mass increase of a moving object.

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Relativistic quantum chemistry in the context of Oganesson

Oganesson is a synthetic chemical element; it has symbol Og and atomic number 118. It was first synthesized in 2002 at the Joint Institute for Nuclear Research (JINR) in Dubna, near Moscow, Russia, by a joint team of Russian and American scientists. In December 2015, it was recognized as one of four new elements by the Joint Working Party of the international scientific bodies IUPAC and IUPAP. It was formally named on 28 November 2016. The name honors the nuclear physicist Yuri Oganessian, who played a leading role in the discovery of the heaviest elements in the periodic table.

Oganesson has the highest atomic number and highest atomic mass of all known elements. On the periodic table of the elements it is a p-block element, a member of group 18, and the last member of period 7. Its only known isotope, oganesson-294, is highly radioactive, with a half-life of 0.7 ms and, as of 2025, only five atoms have been successfully produced. This has so far prevented any experimental studies of its chemistry. Because of relativistic effects, theoretical studies predict that it would be a solid at room temperature, and significantly reactive, unlike the other members of group 18 (the noble gases).

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