Quaternary ammonium in the context of Oilfield


Quaternary ammonium in the context of Oilfield

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⭐ Core Definition: Quaternary ammonium

In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure [NR4], where R is an alkyl group, an aryl group or organyl group. Unlike the ammonium ion (NH+4) and the primary, secondary, or tertiary ammonium cations, the quaternary ammonium cations are permanently charged, independent of the pH of their solution. Quaternary ammonium salts or quaternary ammonium compounds (called quaternary amines in oilfield parlance) are salts of quaternary ammonium cations. Polyquats are a variety of engineered polymer forms which provide multiple quat molecules within a larger molecule.

Quats are used in consumer applications including as antimicrobials (such as detergents and disinfectants), fabric softeners, and hair conditioners. As an antimicrobial, they are able to inactivate enveloped viruses (such as SARS-CoV-2). Quats tend to be gentler on surfaces than bleach-based disinfectants, and are generally fabric-safe.

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Quaternary ammonium in the context of Zwitterion

In chemistry, a zwitterion (/ˈtsvɪtərˌɔːn/ TSVIT-ər-EYE-awn; from German Zwitter [ˈtsvɪtɐ] 'hermaphrodite'), also called an inner salt or dipolar ion, is a molecule that contains an equal number of positively and negatively charged functional groups.(1,2-dipolar compounds, such as ylides, are sometimes excluded from the definition.)

Some zwitterions, such as amino acid zwitterions, are in chemical equilibrium with an uncharged "parent" molecule. Betaines are zwitterions that cannot isomerize to an all-neutral form, such as when the positive charge is located on a quaternary ammonium group. Similarly, a molecule containing a phosphonium group and a carboxylate group cannot isomerize.

View the full Wikipedia page for Zwitterion
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