Polyisocyanurate (/ˌpɒlɪˌaɪsoʊsaɪˈænjʊəreɪt/), also referred to as PIR, polyol, or ISO, is a thermoset plastic typically produced as a foam and used as rigid thermal insulation. The starting materials are similar to those used in polyurethane (PUR) except that the proportion of methylene diphenyl diisocyanate (MDI) is higher and a polyester-derived polyol is used in the reaction instead of a polyether polyol. The resulting chemical structure is significantly different, with the isocyanate groups on the MDI trimerising to form isocyanurate groups which the polyols link together, giving a complex polymeric structure.
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Polyisocyanurate in the context of Radiant barrier
A radiant barrier is a type of building material that reflects thermal radiation and reduces heat transfer. Because thermal energy is also transferred by conduction and convection, in addition to radiation, radiant barriers are often supplemented with thermal insulation that slows down heat transfer by conduction or convection.
A radiant barrier reflects heat radiation (radiant heat), preventing transfer from one side of the barrier to another due to a reflective, low emittance surface. In building applications, this surface is typically a very thin, mirror-like aluminum foil. The foil may be coated for resistance to the elements or for abrasion resistance. The radiant barrier may be one or two sided. One sided radiant barrier may be attached to insulating materials, such as polyisocyanurate, rigid foam, bubble insulation, or oriented strand board (OSB). Reflective tape can be adhered to strips of radiant barrier to make it a contiguous vapor barrier or, alternatively, radiant barrier can be perforated for vapor transmittance.