Piezoelectric effect in the context of "Lord Kelvin"

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⭐ Core Definition: Piezoelectric effect

Piezoelectricity (/ˌpz-, ˌpts-, pˌz-/, US: /piˌz-, piˌts-/) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress.

The piezoelectric effect results from the linear electromechanical interaction between the mechanical and electrical states in crystalline materials with no inversion symmetry. The piezoelectric effect is a reversible process: materials exhibiting the piezoelectric effect also exhibit the reverse piezoelectric effect, the internal generation of a mechanical strain resulting from an applied electric field. For example, lead zirconate titanate crystals will generate measurable piezoelectricity when their static structure is deformed by about 0.1% of the original dimension. Conversely, those same crystals will change about 0.1% of their static dimension when an external electric field is applied. The inverse piezoelectric effect is used in the production of ultrasound waves.

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Piezoelectric effect in the context of Voltage

Voltage, also known as (electrical) potential difference, electric pressure, or electric tension, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to move a positive test charge from the first point to the second point. In the International System of Units (SI), the derived unit for voltage is the volt (V).

The voltage between points can be caused by the build-up of electric charge (e.g., a capacitor), and from an electromotive force (e.g., electromagnetic induction in a generator). On a macroscopic scale, a potential difference can be caused by electrochemical processes (e.g., cells and batteries), the pressure-induced piezoelectric effect, photovoltaic effect, and the thermoelectric effect. Since it is the difference in electric potential, it is a physical scalar quantity.

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Piezoelectric effect in the context of Centrosymmetry

In crystallography, a centrosymmetric point group contains an inversion center as one of its symmetry elements. In such a point group, for every point (x, y, z) in the unit cell there is an indistinguishable point (-x, -y, -z). Such point groups are also said to have inversion symmetry. Point reflection is a similar term used in geometry.Crystals with an inversion center cannot display certain properties, such as the piezoelectric effect and the frequency doubling effect (second-harmonic generation). In addition, in such crystals, one-photon absorption (OPA) and two-photon absorption (TPA) processes are mutually exclusive, i.e., they do not occur simultaneously, and provide complementary information.

The following space groups have inversion symmetry: the triclinic space group 2, the monoclinic 10-15, the orthorhombic 47-74, the tetragonal 83-88 and 123-142, the trigonal 147, 148 and 162-167, the hexagonal 175, 176 and 191-194, the cubic 200-206 and 221-230.

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