Photochemical in the context of Nanometre

An atmosphere is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. The name originates from Ancient Greek ἀτμός (atmós) 'vapour, steam' and σφαῖρα (sphaîra) 'sphere'. An object acquires most of its atmosphere during its primordial epoch, either by accretion of matter or by outgassing of volatiles. The chemical interaction of the atmosphere with the solid surface can change its fundamental composition, as can photochemical interaction with the Sun. A planet retains an atmosphere for longer durations when the gravity is high and the temperature is low. The solar wind works to strip away a planet's outer atmosphere, although this process is slowed by a magnetosphere. The further a body is from the Sun, the lower the rate of atmospheric stripping.

Aside from Mercury, all Solar System planets have substantial atmospheres, as does the dwarf planet Pluto and the moon Titan. The high gravity and low temperature of Jupiter and the other gas giant planets allow them to retain massive atmospheres of mostly hydrogen and helium. Lower mass terrestrial planets orbit closer to the Sun, and so mainly retain higher density atmospheres made of carbon, nitrogen, and oxygen, with trace amounts of inert gas. Atmospheres have been detected around exoplanets such as HD 209458 b and Kepler-7b.

Heptacene is an organic compound and a polycyclic aromatic hydrocarbon and the seventh member of the acene or polyacene family of linear fused benzene rings. This compound has long been pursued by chemists because of its potential interest in electronic applications and was first synthesized but not cleanly isolated in 2006. Heptacene was finally fully characterized in bulk by researchers in Germany and the United States in 2017.

The final step is a photochemical decarbonylization with a 1,2-dione bridge extruded as carbon monoxide. In solution heptacene is not formed because it is very unstable being a reactive DA diene and quickly reacts with oxygen or forms dimers. When on the other hand the dione precursor is dissolved in a PMMA matrix first, heptacene can be studied by spectroscopy. Heptacene has been studied spectroscopically at cryogenic temperatures in a matrix. When dissolved in sulfuric acid the heptacene dication is reported to be stable at room-temperature for more than a year in absence of oxygen."[Isolated] solid heptacene has a half-life time of several weeks at room temperature."