Phosphine in the context of "Chemical purity"

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⭐ Core Definition: Phosphine

Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula PH3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P2H4). With traces of P2H4 present, PH3 is spontaneously flammable in air (pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure.

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Phosphine in the context of Jupiter

Jupiter is the fifth planet from the Sun and the largest in the Solar System. It is a gas giant with a mass nearly 2.5 times that of all the other planets in the Solar System combined and slightly less than one-thousandth the mass of the Sun. Its diameter is 11 times that of Earth and a tenth that of the Sun. Jupiter orbits the Sun at a distance of 5.20 AU (778.5 Gm), with an orbital period of 11.86 years. It is the third-brightest natural object in the Earth's night sky, after the Moon and Venus, and has been observed since prehistoric times. Its name derives from that of Jupiter, the chief deity of ancient Roman religion.

Jupiter was the first of the Sun's planets to form, and its inward migration during the primordial phase of the Solar System affected much of the formation history of the other planets. Jupiter's atmosphere consists of 76% hydrogen and 24% helium by mass, with a denser interior. It contains traces of the elements carbon, oxygen, sulfur, neon, and compounds such as ammonia, water vapour, phosphine, hydrogen sulfide, and hydrocarbons. Jupiter's helium abundance is 80% of the Sun's, similar to Saturn's composition.

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Phosphine in the context of Volatile (astrogeology)

Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances.

On planet Earth, the term 'volatiles' often refers to the volatile components of magma. In astrogeology volatiles are investigated in the crust or atmosphere of a planet or moon. Volatiles include hydrogen, nitrogen, oxygen, water, ammonia, methane, carbon dioxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide, phosphine, halogens, noble gases and others.

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Phosphine in the context of Phosphorus cycle

The phosphorus cycle is the biogeochemical cycle that involves the movement of phosphorus through the lithosphere, hydrosphere, and biosphere. Unlike many other biogeochemical cycles, the atmosphere does not play a significant role in the movement of phosphorus, because phosphorus and phosphorus-based materials do not enter the gaseous phase readily, as the main source of gaseous phosphorus, phosphine, is only produced in isolated and specific conditions. Therefore, the phosphorus cycle is primarily examined studying the movement of orthophosphate (PO3−4), the form of phosphorus that is most commonly seen in the environment, through terrestrial and aquatic ecosystems.

Living organisms require phosphorus, a vital component of DNA, RNA, ATP, etc., for their proper functioning. Phosphorus also enters in the composition of phospholipids present in cell membranes. Plants assimilate phosphorus as phosphate and incorporate it into organic compounds. In animals, inorganic phosphorus in the form of apatite (Ca5(PO4)3(OH,F)) is also a key component of bones, teeth (tooth enamel), etc. On the land, phosphorus gradually becomes less available to plants over thousands of years, since it is slowly lost in runoff. Low concentration of phosphorus in soils reduces plant growth and slows soil microbial growth, as shown in studies of soil microbial biomass. Soil microorganisms act as both sinks and sources of available phosphorus in the biogeochemical cycle. Short-term transformation of phosphorus is chemical, biological, or microbiological. In the long-term global cycle, however, the major transfer is driven by tectonic movement over geologic time and weathering of phosphate containing rock such as apatite. Furthermore, phosphorus tends to be a limiting nutrient in aquatic ecosystems. However, as phosphorus enters aquatic ecosystems, it has the possibility to lead to over-production in the form of eutrophication, which can happen in both freshwater and saltwater environments.

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Phosphine in the context of Organoiron chemistry

Organoiron chemistry is the chemistry of iron compounds containing a carbon-to-iron chemical bond. Organoiron compounds are relevant in organic synthesis as reagents such as iron pentacarbonyl, diiron nonacarbonyl and disodium tetracarbonylferrate. Although iron is generally less active in many catalytic applications, it is less expensive and "greener" than other metals. Organoiron compounds feature a wide range of ligands that support the Fe-C bond; as with other organometals, these supporting ligands prominently include phosphines, carbon monoxide, and cyclopentadienyl, but hard ligands such as amines are employed as well.

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Phosphine in the context of Acetylene

Acetylene (systematic name: ethyne) is a chemical compound with the formula C2H2 and structure HC≡CH. It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure form and thus is usually handled as a solution. Pure acetylene is odorless, but commercial grades usually have a marked odor due to impurities such as divinyl sulfide and phosphine.

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