Ozone layer in the context of James Chappuis

Earth is the third planet from the Sun and the only astronomical object known to harbor life. This is enabled by Earth being an ocean world, the only one in the Solar System sustaining liquid surface water. Almost all of Earth's water is contained in its global ocean, covering 70.8% of Earth's crust. The remaining 29.2% of Earth's crust is land, most of which is located in the form of continental landmasses within Earth's land hemisphere. Most of Earth's land is at least somewhat humid and covered by vegetation, while large ice sheets at Earth's polar deserts retain more water than Earth's groundwater, lakes, rivers, and atmospheric water combined. Earth's crust consists of slowly moving tectonic plates, which interact to produce mountain ranges, volcanoes, and earthquakes. Earth has a liquid outer core that generates a magnetosphere capable of deflecting most of the destructive solar winds and cosmic radiation.

Earth has a dynamic atmosphere, which sustains Earth's surface conditions and protects it from most meteoroids and UV-light at entry. It is composed primarily of nitrogen and oxygen. Water vapor is widely present in the atmosphere, forming clouds that cover most of the planet. The water vapor acts as a greenhouse gas and, together with other greenhouse gases in the atmosphere, particularly carbon dioxide (CO₂), creates the conditions for both liquid surface water and water vapor to persist via the capturing of energy from the Sun's light. This process maintains the current average surface temperature of 14.76 °C (58.57 °F), at which water is liquid under normal atmospheric pressure. Differences in the amount of captured energy between geographic regions (as with the equatorial region receiving more sunlight than the polar regions) drive atmospheric and ocean currents, producing a global climate system with different climate regions, and a range of weather phenomena such as precipitation, allowing components such as carbon and nitrogen to cycle.

Ozone (/ˈoʊzoʊn/ ), also called trioxygen, is an inorganic molecule with the chemical formula O
₃. It is a pale-blue gas with a distinctively pungent odour. It is an allotrope of oxygen that is much less stable than the diatomic allotrope O
₂, breaking down in the lower atmosphere to O
₂ (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the atmosphere, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation.

Ozone's odour is reminiscent of chlorine, and detectable by many people at concentrations of as little as 0.1 ppm in air. Ozone's O₃ structure was determined in 1865. The molecule was later proven to have a bent structure and to be weakly diamagnetic. At standard temperature and pressure, ozone is a pale blue gas that condenses at cryogenic temperatures to a dark blue liquid and finally a violet-black solid. Ozone's instability with regard to more common dioxygen is such that both concentrated gas and liquid ozone may decompose explosively at elevated temperatures, physical shock, or fast warming to the boiling point. It is therefore used commercially only in low concentrations.

Paul Jozef Crutzen (Dutch pronunciation: [pʌul ˈjoːzəf ˈkrʏtsə(n)]; 3 December 1933 – 28 January 2021) was a Dutch meteorologist and atmospheric chemist. In 1995, he was awarded the Nobel Prize in Chemistry alongside Mario Molina and Frank Sherwood Rowland for their work on atmospheric chemistry and specifically for his efforts in studying the formation and decomposition of atmospheric ozone. In addition to studying the ozone layer and climate change, he popularized the term Anthropocene to describe a proposed new epoch in the Quaternary period when human actions have a drastic effect on the Earth. He was also amongst the first few scientists to introduce the idea of a nuclear winter to describe the potential climatic effects stemming from large-scale atmospheric pollution including smoke from forest fires, industrial exhausts, and other sources like oil fires.

He was a member of the Royal Swedish Academy of Sciences and an elected foreign member of the Royal Society in the United Kingdom.

Oxygen is a chemical element; it has the symbol O and its atomic number is 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and a potent oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is the most abundant element in Earth's crust, making up almost half of the Earth's crust in the form of various oxides such as water, carbon dioxide, iron oxides and silicates. It is also the third-most abundant element in the universe after hydrogen and helium.

At standard temperature and pressure, two oxygen atoms will bind covalently to form dioxygen, a colorless and odorless diatomic gas with the chemical formula O
₂. Dioxygen gas currently constitutes approximately 20.95% molar fraction of the Earth's atmosphere, though this has changed considerably over long periods of time in Earth's history. A much rarer triatomic allotrope of oxygen, ozone (O
₃), strongly absorbs the UVB and UVC wavelengths and forms a protective ozone layer at the lower stratosphere, which shields the biosphere from ionizing ultraviolet radiation. However, ozone present at the surface is a corrosive byproduct of smog and thus an air pollutant.

The stratosphere is the second-lowest layer of the atmosphere of Earth, located above the troposphere and below the mesosphere. Pronounced /ˈstrætəˌsfɪər, -toʊ-/, the name originates from from Ancient Greek στρωτός (strōtós) 'layer, stratum' and -sphere. The stratosphere is composed of stratified temperature zones, with the warmer layers of air located higher (closer to outer space) and the cooler layers lower (closer to the planetary surface of the Earth). The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet (UV) radiation by the ozone layer, where ozone is exothermically photolyzed into oxygen in a cyclical fashion. This temperature inversion is in contrast to the troposphere, where temperature decreases with altitude, and between the troposphere and stratosphere is the tropopause border that demarcates the beginning of the temperature inversion.

Near the equator, the lower edge of the stratosphere is as high as 20 km (66,000 ft; 12 mi), at mid-latitudes around 10 km (33,000 ft; 6.2 mi), and at the poles about 7 km (23,000 ft; 4.3 mi). Temperatures range from an average of −51 °C (−60 °F; 220 K) near the tropopause to an average of −15 °C (5.0 °F; 260 K) near the mesosphere. Stratospheric temperatures also vary within the stratosphere as the seasons change, reaching particularly low temperatures in the polar night (winter). Winds in the stratosphere can far exceed those in the troposphere, reaching near 60 m/s (220 km/h; 130 mph) in the Southern polar vortex.

Liquefied petroleum gas, also referred to as liquid petroleum gas (LPG or LP gas), is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, n-butane and isobutane. It can also contain some propylene, butylene, and isobutylene/isobutene.

LPG is used as a fuel gas in heating appliances, cooking equipment, and vehicles, and is used as an aerosol propellant and a refrigerant, replacing chlorofluorocarbons in an effort to reduce the damage it causes to the ozone layer. When specifically used as a vehicle fuel, it is often referred to as autogas or just as gas.

Ground-level ozone (O₃), also known as surface-level ozone and tropospheric ozone, is a trace gas in the troposphere (the lowest level of the Earth's atmosphere), with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas. Ozone is also an important constituent of the stratosphere, where the ozone layer (2 to 8 parts per million ozone) exists which is located between 10 and 50 kilometers above the Earth's surface. The troposphere extends from the ground up to a variable height of approximately 14 kilometers above sea level. Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere.

Ground-level or tropospheric ozone is created by chemical reactions between NOx gases (oxides of nitrogen produced by combustion) and volatile organic compounds (VOCs). The combination of these chemicals in the presence of sunlight form ozone. Its concentration increases as height above sea level increases, with a maximum concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although ground-level ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is a greenhouse gas, and as such contribute to global warming. It is the third most important greenhouse gas after CO₂ and CH₄, as indicated by estimates of its radiative forcing.

Mario José Molina-Pasquel Henríquez (19 March 1943 – 7 October 2020) was a Mexican physical chemist. He played a pivotal role in the discovery of the Antarctic ozone hole, and was a co-recipient of the 1995 Nobel Prize in Chemistry for his role in discovering the threat to the Earth's ozone layer from chlorofluorocarbon (CFC) gases. He was the first Mexican-born scientist to receive a Nobel Prize in Chemistry and the third Mexican-born person to receive a Nobel prize.

In his career, Molina held research and teaching positions at University of California, Irvine, California Institute of Technology, Massachusetts Institute of Technology, University of California, San Diego, and the Center for Atmospheric Sciences at the Scripps Institution of Oceanography. Molina was also Director of the Mario Molina Center for Energy and Environment in Mexico City. Molina was a climate policy advisor to the President of Mexico, Enrique Peña Nieto.

Marie Paul Auguste Charles Fabry ForMemRS (French: [maʁi pɔl oɡyst ʃaʁl fabʁi]; 11 June 1867 – 11 December 1945) was a French physicist working on optics. Together with Alfred Pérot he invented the Fabry–Pérot interferometer. He is also one of the co-discoverers of the ozone layer.

Henri Buisson (French: [ɑ̃ʁi bɥisɔ̃]; 1873–1944) was a French physicist. Buisson and Charles Fabry discovered the ozone layer in 1913.

Buisson was born on 15 July 1873 in Paris and died on 6 January 1944 in Marseille, at age 70.

The Dobson unit (DU) is a unit of measurement of the amount of a trace gas in a vertical column through the Earth's atmosphere. It originated by, and continues to be primarily used in respect to, the study of atmospheric ozone, whose total column amount, usually termed "total ozone", and sometimes "column abundance", is dominated by the high concentrations of ozone in the stratospheric ozone layer.

The Dobson unit is defined as the thickness (in units of 10 μm) of that layer of pure gas which would be formed by the total column amount at standard conditions for temperature and pressure (STP). This is sometimes referred to as a 'milli-atmo-centimeter'. A typical column amount of 300 DU of atmospheric ozone therefore would form a 3 mm layer of pure gas at the surface of the Earth if its temperature and pressure conformed to STP.

The blue hour (from French l'heure bleue; pronounced [lœʁ blø]) is the period of twilight (in the morning or evening, around the nautical stage) when the Sun is at a significant depth below the horizon. During this time, the remaining sunlight takes on a mostly blue shade. This shade differs from the colour of the sky on a clear day, which is caused by Rayleigh scattering.

The blue hour occurs when the Sun is far enough below the horizon so that the sunlight's blue wavelengths dominate due to the Chappuis absorption in the ozone layer. Since the term is colloquial, it lacks an official definition such as dawn, dusk, or the three stages of twilight. Rather, blue hour refers to the state of natural lighting that usually occurs around the nautical stage of the twilight period (at dawn or dusk).

Chappuis absorption (French: [ʃapɥi]) refers to the absorption of electromagnetic radiation by ozone, which is especially noticeable in the ozone layer, which absorbs a small part of sunlight in the visible portion of the electromagnetic spectrum. The Chappuis absorption bands occur at wavelengths between 400 and 650 nm. Within this range are two absorption maxima of similar height at 575 and 603 nm.

Compared to the absorption of ultraviolet light by the ozone layer, known as the Hartley and Huggins absorptions, Chappuis absorption is distinctly weaker. Along with Rayleigh scattering, it contributes to the blue color of the sky, and is noticeable when the light has to travel a long path through the Earth's atmosphere. For this reason, Chappuis absorption only has a significant effect on the color of the sky at dawn and dusk, during the so-called blue hour. It is named after the French chemist James Chappuis (1854–1934), who discovered this effect.

The ozone–oxygen cycle is the process by which ozone is continually regenerated in Earth's stratosphere, converting ultraviolet radiation (UV) into heat. In 1930 Sydney Chapman resolved the chemistry involved. The process is commonly called the Chapman cycle by atmospheric scientists.

Most of the ozone production occurs in the tropical upper stratosphere and mesosphere. The total mass of ozone produced per day over the globe is about 400 million metric tons. The global mass of ozone is relatively constant at about 3 billion metric tons, meaning the Sun produces about 12% of the ozone layer each day.

Aura (EOS CH-1) is a multi-national NASA scientific research satellite in orbit around the Earth, studying the Earth's ozone layer, air quality and climate. It is the third major component of the Earth Observing System (EOS) following on Terra (launched 1999) and Aqua (launched 2002). Aura follows on from the Upper Atmosphere Research Satellite (UARS). Aura is a joint mission between NASA, the Netherlands, Finland, and the U.K. The Aura spacecraft is healthy and is expected to operate until at least 2028, possibly beyond.

The name "Aura" comes from the Latin word for air. The satellite was launched from Vandenberg Air Force Base on July 15, 2004, aboard a Delta II 7920-10L rocket.