Orthonormal basis in the context of Coordinate frame

Rotation in mathematics is a concept originating in geometry. Any rotation is a motion of a certain space that preserves at least one point. It can describe, for example, the motion of a rigid body around a fixed point. Rotation can have a sign (as in the sign of an angle): a clockwise rotation is a negative magnitude so a counterclockwise turn has a positive magnitude.A rotation is different from other types of motions: translations, which have no fixed points, and (hyperplane) reflections, each of them having an entire (n − 1)-dimensional flat of fixed points in a n-dimensional space.

Mathematically, a rotation is a map. All rotations about a fixed point form a group under composition called the rotation group (of a particular space). But in mechanics and, more generally, in physics, this concept is frequently understood as a coordinate transformation (importantly, a transformation of an orthonormal basis), because for any motion of a body there is an inverse transformation which if applied to the frame of reference results in the body being at the same coordinates. For example, in two dimensions rotating a body clockwise about a point keeping the axes fixed is equivalent to rotating the axes counterclockwise about the same point while the body is kept fixed. These two types of rotation are called active and passive transformations.

In mathematics, particularly linear algebra, an orthogonal basis for an inner product space ${\displaystyle V}$ is a basis for ${\displaystyle V}$ whose vectors are mutually orthogonal. If the vectors of an orthogonal basis are normalized, the resulting basis is an orthonormal basis.

In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. The table of spherical harmonics contains a list of common spherical harmonics.

Since the spherical harmonics form a complete set of orthogonal functions and thus an orthonormal basis, certain functions defined on the surface of a sphere can be written as a sum of these spherical harmonics. This is similar to periodic functions defined on a circle that can be expressed as a sum of circular functions (sines and cosines) via Fourier series. Like the sines and cosines in Fourier series, the spherical harmonics may be organized by (spatial) angular frequency, as seen in the rows of functions in the illustration on the right. Further, spherical harmonics are basis functions for irreducible representations of SO(3), the group of rotations in three dimensions, and thus play a central role in the group theoretic discussion of SO(3).

In mathematics, a self-adjoint operator on a complex vector space ${\displaystyle V}$ with inner product ${\displaystyle \langle \cdot ,\cdot \rangle }$ is a linear map ${\displaystyle A}$ (from ${\displaystyle V}$ to itself) that is its own adjoint. That is, ${\displaystyle \langle Ax,y\rangle =\langle x,Ay\rangle }$ for all ${\displaystyle x,y\in V}$. If ${\displaystyle V}$ is finite-dimensional with a given orthonormal basis, this is equivalent to the condition that the matrix of ${\displaystyle A}$ is a Hermitian matrix, i.e., equal to its conjugate transpose ${\displaystyle A^{*}}$. By the finite-dimensional spectral theorem, ${\displaystyle V}$ has an orthonormal basis such that the matrix of ${\displaystyle A}$ relative to this basis is a diagonal matrix with entries in the real numbers. This article deals with applying generalizations of this concept to operators on Hilbert spaces of arbitrary dimension.

Self-adjoint operators are used in functional analysis and quantum mechanics. In quantum mechanics their importance lies in the Dirac–von Neumann formulation of quantum mechanics, in which physical observables such as position, momentum, angular momentum and spin are represented by self-adjoint operators on a Hilbert space. Of particular significance is the Hamiltonian operator ${\displaystyle {\hat {H}}}$ defined by